Composition for prolonging the action of herbicides and herbicide
compositions with a prolonged action
    3.
    发明授权
    Composition for prolonging the action of herbicides and herbicide compositions with a prolonged action 失效
    用于延长作用的用于延长除草剂和除草剂组合物的作用的组合物

    公开(公告)号:US4695313A

    公开(公告)日:1987-09-22

    申请号:US744513

    申请日:1985-06-13

    CPC分类号: A01N25/22 A01N47/12

    摘要: The invention relates to compositions (extenders) useful for prolonging the action of herbicides containing thiolcarbamate derivatives as active ingredients as well as to herbicide compositions with a prolonged action containing thiolcarbamate derivatives as active ingredients and optionally an antidote which comprises a diaminomethane derivative of the general formula (III) ##STR1## wherein the R substituents stand independently from one another for C.sub.1-6 alkyl groups or for C.sub.2-4 alkenyl groups optionally substituted by a C.sub.1-4 alkyl group; and a process for prolonging the actin of herbicide compositions containing a thiolcarbamate derivative and optionally an antidote, which comprises applying the above mentioned composition in a quantity providing the prolonged action simultaneously with or after the application of the herbicide composition.

    摘要翻译: 本发明涉及用于延长含有硫代氨基甲酸酯衍生物作为活性成分的除草剂的作用的组合物(增量剂)以及含有硫代氨基甲酸酯衍生物作为活性成分的延长作用的除草剂组合物和任选的解毒剂,其包含通式 (III)其中R取代基彼此独立地为C 1-6烷基或任选被C 1-4烷基取代的C 2-4链烯基取代; 以及用于延长包含硫代氨基甲酸酯衍生物和任选的解毒剂的除草剂组合物的肌动蛋白的方法,其包括在施用除草剂组合物的同时施用上述组合物,其量提供延长的作用。

    Composition for prolonging the action of herbicides and herbicide
compositions with a prolonged action
    4.
    发明授权
    Composition for prolonging the action of herbicides and herbicide compositions with a prolonged action 失效
    用于延长作用的用于延长除草剂和除草剂组合物的作用的组合物

    公开(公告)号:US4695309A

    公开(公告)日:1987-09-22

    申请号:US840425

    申请日:1986-03-17

    CPC分类号: A01N25/22 A01N47/12

    摘要: The invention relates to compositions (extenders) useful for prolonging the action of herbicides containing thiolcarbamate derivatives as active ingredients as well as to herbicide compositions with a prolonged action containing thiolcarbamate derivatives as active ingredients and optionally an antidote which comprises a diaminomethane derivative of the general formula (III) ##STR1## wherein the R substituents stand independently from one another for C.sub.1-6 alkyl groups or for C.sub.2-4 alkenyl groups optionally substituted by a C.sub.1-4 aklyl group;and a process for prolonging the action of herbicide compositions containing a thiolcarbamate derivative and optionally an antidote, which comprises applying the above mentioned composition in a quantity providing the prolonged action simultaneously with or after the application of the herbicide composition.

    摘要翻译: 本发明涉及用于延长含有硫代氨基甲酸酯衍生物作为活性成分的除草剂的作用的组合物(增量剂)以及含有硫代氨基甲酸酯衍生物作为活性成分的延长作用的除草剂组合物和任选的解毒剂,其包含通式 (III)其中R取代基彼此独立地为C 1-6烷基或任选被C 1-4亚氨基取代的C 2-4烯基取代; 以及用于延长包含硫代氨基甲酸酯衍生物和任选的解毒剂的除草剂组合物的作用的方法,其包括在施用除草剂组合物的同时或之后施用上述组合物,其量提供延长的作用。

    Antidoted herbicide compositions and antidote compositions
    7.
    发明授权
    Antidoted herbicide compositions and antidote compositions 失效
    抗除草剂组合物和解毒剂组合物

    公开(公告)号:US5055125A

    公开(公告)日:1991-10-08

    申请号:US507314

    申请日:1990-04-10

    摘要: Herbicidal compositions comprising a substituted thiolcarbamate derivative corresponding to the formula (I) wherein R.sub.1, R.sub.2 and R.sub.3 are selected independently from alkyl groups having 1 to 4 carbon atoms and/or a chloroacetanilide derivative corresponding to the formula (II) wherein R.sub.4 and R.sub.5 are hydrogen or alkyl group having 1 to 4 carbon atoms, identical or different, R.sub.6 is an alkoxyalkyl group corresponding to the formula --R.sub.7 --O--R.sub.8 in which R.sub.7 and R.sub.8 are selected from alkyl groups having 1 to 4 carbon atoms and, as an antidote, a thiocarbamic acid derivative corresponding to the formula (III) wherein R.sub.9 and R.sub.10 independently from each other are alkyl or alkenyl group having 1 to 4 carbon atoms, or R.sub.9 and R.sub.10 taken together with one or two nitrogen atoms form a heterocyclic group, which may contain one oxygen atom or they form a soiro-heterocyclic or condensated ring, which can be substituted with alkyl groups having 1 to 4 carbon atoms or an aryl group, R.sub.11 is an alkyl or alkenyl group having 1 to 3 carbon atoms or a benzyl group containing one or 2 substituents, carboxy methylene, 1-methylene naphtyl, acetophenon-(2)-yl-, carb-(.alpha.)naphthoxy-methylene, N-methylene o-benzoic acid sulphimide, N-isopropyl-N-phenylacetamidyl, N,N-disubstituted-2-acetamidyl group containing alkyl, alkylene groups having 1 to 3 carbon atoms, alkoxyalkyl, phenyl or dialkyl phenyl group.

    摘要翻译: 包含对应于式(I)的取代的硫代氨基甲酸酯衍生物的除草组合物,其中R 1,R 2和R 3独立地选自具有1至4个碳原子的烷基和/或对应于式(II)的氯代乙酰苯胺衍生物,其中R 4和R 5是 氢或具有1〜4个碳原子的烷基相同或不同,R6是对应于式-R7-O-R8的烷氧基烷基,其中R 7和R 8选自具有1至4个碳原子的烷基,作为 解毒剂,对应于式(III)的氨基甲酸衍生物,其中R 9和R 10彼此独立地为具有1至4个碳原子的烷基或烯基,或者R 9和R 10与一个或两个氮原子一起形成杂环基, 其可以含有一个氧原子,或者它们形成可以被具有1至4个碳原子的烷基或芳基取代的单环或缩合的环,R 11是烷基或链烯基 具有1至3个碳原子的苄基或含有一个或两个取代基的苄基,羧基亚甲基,1-亚甲基萘基,苯乙酮 - (2) - 基 - ,碳 - (α)萘氧基 - 亚甲基,N-亚甲基邻苯甲酸 亚磺酰亚胺,N-异丙基-N-苯基乙酰胺基,含有N,N-二取代-2-乙酰氨基的烷基,具有1至3个碳原子的亚烷基,烷氧基烷基,苯基或二烷基苯基。

    Process for the preparation of substituted S-alkyl thio-carbamates
    8.
    发明授权
    Process for the preparation of substituted S-alkyl thio-carbamates 失效
    制备取代的S-烷基硫代 - 氨基甲酸酯的方法

    公开(公告)号:US3953427A

    公开(公告)日:1976-04-27

    申请号:US534096

    申请日:1974-12-18

    CPC分类号: C07D295/21

    摘要: The invention relates to a new and advantageous process for the preparation of substituted S-alkyl thiocarbamates having the general formula (I), ##EQU1## wherein R.sup.1 stands for a C.sub.1-4 alkyl group,R.sup.2 stands for a C.sub.1-4 alkyl or cyclohexyl group, orR.sup.1 and R.sup.2 may form together a C.sub.4-6 polymethylene group, andR.sup.3 stands for a C.sub.2-3 alkyl group.In accordance with the invention the substituted O-alkyl thiocarbamates of the general formula (II), ##EQU2## wherein R.sup.1, R.sup.2 and R.sup.3 each have the same meanings as defined above, are subjected to isomerization by heating them at a temperature of 130.degree. to 180.degree.C in the presence of dimethyl sulfate or diethyl sulfate to yield the appropriate S-alkyl esters.

    摘要翻译: 本发明涉及制备具有通式(I)的取代的S-烷基硫代氨基甲酸酯的新的和有利的方法,其中R 1代表C 1-4烷基,R 2表示 对于C 1-4烷基或环己基,或者R 1和R 2可以一起形成C 4-6多亚甲基,R 3代表C 2-3烷基。