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公开(公告)号：US6147022A
公开(公告)日：2000-11-14
申请号：US296533
申请日：1999-04-22
摘要： Process for regeneration of a catalytic moving bed in which the catalyst successively passes through at least one combustion zone A, at least one halogenation zone B, and at least one calcination zone C, whereby this process operates in a partial-regeneration-mode, the partially coked catalyst that is obtained from the last combustion zone passes into the halogenation zone in which the amount of halogen and the amount of oxygen are essentially zero--the valves of tubes (19) and (20) are then virtually closed--and the catalyst then passes through the calcination zone in which the amount of oxygen is essentially zero--the valve of tube (11) is then virtually closed.
摘要翻译： 催化移动床的再生方法，其中催化剂依次通过至少一个燃烧区A，至少一个卤化区B和至少一个煅烧区C，由此该过程以部分再生模式操作， 从最后一个燃烧区获得的部分焦化催化剂进入其中卤素的量和氧的量基本上为零的卤化区，然后管（19）和（20）的阀实际上是封闭的，催化剂 然后通过其中氧气量基本为零的煅烧区域 - 管（11）的阀然后被虚拟地关闭。
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2.发明申请Process and device for the production of aromatic compounds including a reduction of the catalyst 审中-公开用于生产芳族化合物的方法和装置，包括催化剂的还原公开(公告)号：US20050214176A1
公开(公告)日：2005-09-29
申请号：US10703546
申请日：2003-11-10
IPC分类号： B01J38/04 , C07B61/00 , C07C5/42 , C07C15/04 , C07C15/06 , C07C15/08 , C10G35/09 , C10G35/12 , C10G35/22 , B01J8/18
摘要： The invention relates to a process for the production of aromatic compounds from a hydrocarbon fraction with a catalyst that preferably circulates in a moving bed, a process that comprises at least the following successive stages that take place in at least one zone: treatment of the fraction in the presence of hydrogen and implementing at least one reaction for dehydrogenation of naphthenes; separation of the gas effluent that contains hydrogen, the liquid product and the catalyst; regeneration of the catalyst; reduction of the catalyst; and reintroduction of the catalyst for the treatment stage; recycling in the treatment stage of at least a portion of the gas effluent that contains the hydrogen that is called recycling gas; process in which the reduction stage is carried out in the presence of recycling gas that is introduced in an amount such that the amount of pure hydrogen that is provided is between 1-10 kg/kg of catalyst, whereby the effluent that is obtained from the reduction is then separated from the catalytic bed. The invention also pertains to the related device.
摘要翻译： 本发明涉及一种由具有优选在移动床中循环的催化剂的烃馏分生产芳族化合物的方法，该方法至少包括在至少一个区域中发生的以下连续阶段：处理馏分 在氢的存在下，并且实施至少一个用于环烷酸脱氢的反应; 分离含有氢气，液体产物和催化剂的气体流出物; 催化剂再生; 还原催化剂; 并重新引入用于治疗阶段的催化剂; 在处理阶段回收至少一部分含有称为再循环气体的氢气的气体流出物; 在再循环气体的存在下进行还原阶段的方法，该再循环气体的导入量使得提供的纯氢的量在1-10kg / kg的催化剂之间，由此得到的流出物 然后将还原与催化床分离。 本发明也涉及相关设备。
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3.发明授权Process and device for the production of aromatic compounds including a reduction of the catalyst 失效用于生产芳族化合物的方法和装置，包括催化剂的还原公开(公告)号：US06677494B2
公开(公告)日：2004-01-13
申请号：US09725931
申请日：2000-11-30
IPC分类号： C07C1502
摘要： The invention relates to a process for the production of aromatic compounds from a hydrocarbon fraction with a catalyst the preferably circulates in a moving bed. In the process, a hydrocarbon feedstock that is treated by a hydrogen-rich gas is transformed. In a particular embodiment, regenerative reforming is conducted, such as for production of BTX (butene, toluene, xylenes) with continuous regeneration of the catalyst. The invention also pertains to the related device for carrying out the process.
摘要翻译： 本发明涉及一种由具有催化剂的烃馏分制备芳族化合物的方法，优选在移动床中循环。 在此过程中，转化了由富氢气体处理的烃原料。 在一个具体的实施方案中，进行再生重整，例如用于生产BTX（丁烯，甲苯，二甲苯）并连续再生催化剂。 本发明还涉及用于执行该过程的相关设备。
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4.发明授权Process for the production of aromatic compounds in a moving bed including a reduction of the catalyst 有权在移动床中生产芳族化合物的方法，包括催化剂的还原公开(公告)号：US06660895B1
公开(公告)日：2003-12-09
申请号：US09725510
申请日：2000-11-30
IPC分类号： C07C1520
摘要： A moving bed process for producing aromatic compounds comprises at least a first step in which principally naphthene dehydrogenation is carried out in the presence of hydrogen in a mole ratio (H2)1/(HC), said step being followed by at least one subsequent step carried out at a mole ratio (H2)2/(HC)2, the process also comprising reducing the catalyst with hydrogen in a ratio (H2)red/(HC). In accordance with the invention, (H2)1/(HC)+(H2)red/(HC)≦(H2)2/(HC)2, (HC) representing the molar quantity of feed in the first step and (HC)2 that of the subsequent step, or (H2)1/(HC)+(H2)red/(HC)>(H2)2/HC2, but where (H2)1/(HC) is less than (H2)2/(HC)2. Particular application to reforming.
摘要翻译： 用于生产芳族化合物的移动床方法包括至少第一步骤，其中主要在氢气存在下以摩尔比（H 2）1 /（HC）进行环烷脱氢，所述步骤之后是至少一个后续步骤 以（H2）2 /（HC）2的摩尔比进行，该方法还包括以比例（H2）红/（HC）的氢还原催化剂。 根据本发明，代表第一步中进料摩尔量的（H2）1 /（HC）+（H2）红/（HC）=（H2）2 /（HC） （H2）1 /（HC）+（H2）红/（HC）>（H2）2 / HC2，但其中（H2）1 /（HC）小于（H2） ）2 /（HC）2。 具体应用于改革。
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