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    Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound
    3.
    发明授权
    Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound 失效
    一氧化碳与烯属不饱和化合物共聚的方法

    公开(公告)号：US5741939A

    公开(公告)日：1998-04-21

    申请号：US619868

    申请日：1996-03-21

    申请人： Frank Baardman ,  Arleen Marie Bradford ,  Jayne Jubb ,  Pieter Scheerman ,  Rudolf Jacobus Wijngaarden

    发明人： Frank Baardman ,  Arleen Marie Bradford ,  Jayne Jubb ,  Pieter Scheerman ,  Rudolf Jacobus Wijngaarden

    IPC分类号： B01J31/18 ,  B01J31/24 ,  C08G67/02 ,  C07C45/49

    CPC分类号： C08G67/02 ,  B01J31/2409 ,  B01J2531/80 ,  B01J31/1895

    摘要： A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound comprising contacting the monomers in the presence of a liquid diluent with a catalyst composition which is based on (a) a source of a Group VIII metal, (b) a bidentate ligand of the general formula R.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4 wherein M.sup.1 and M.sup.2 independently represent a phosphorus, arsenic or antimony atom, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent unsubstituted or substituted hydrocarbyl groups on the understanding that at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a polar substituted aryl group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and (c) a boron hydrocarbyl compound, with application of a stirring power transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.

    摘要翻译： 一种一氧化碳与烯属不饱和化合物共聚的方法，包括在液体稀释剂存在下使单体与催化剂组合物接触，所述催化剂组合物基于（a）Ⅷ族金属源，（b）二元配体 通式R1R2M1-R-M2R3R4其中M1和M2独立地表示磷，砷或锑原子，R1，R2，R3和R4独立地表示未取代或取代的烃基，其理解是R1，R2，R3和 R4表示极性取代的芳基，R表示桥中含有至少两个碳原子的二价桥连基团，和（c）硼烃基化合物，通过施加向聚合混合物中传递至少0.25kW / m3。

    Process for the preparation of copolymers
    5.
    发明授权
    Process for the preparation of copolymers 失效
    制备共聚物的方法

    公开(公告)号：US5750642A

    公开(公告)日：1998-05-12

    申请号：US801976

    申请日：1997-02-19

    申请人： Frank Baardman ,  Jayne Jubb

    发明人： Frank Baardman ,  Jayne Jubb

    IPC分类号： C08G67/02 ,  C08K5/49

    CPC分类号： C08G67/02

    摘要： A process for the preparation of copolymers of carbon monoxide with an olefinically unsaturated compound comprising copolymerizing the monomers in the presence of a catalyst composition based upon (a) a salt of a Group VIII metal, and (b) a cation which is selected from cationic oxidants and cations of the general formulae R.sub.n H.sub.4-n N.sup.+, R.sub.m H.sub.3-m C.sup.+ and R.sub.m H.sub.3-m O.sup.+, wherein n is 0, 1, 2, 3 or 4, m is 2 or 3, and R represents a hydrocarbyl group and/or two or three of R together with the atom carrying a positive charge represent a ring structure, on the understanding that when n is 3, at most two of R together with nitrogen represent a heterocyclic ring structure, and when n is 4, three of R together with nitrogen represent an aromatic heterocyclic ring structure.

    摘要翻译： 一种制备一氧化碳与烯属不饱和化合物的共聚物的方法，包括在催化剂组合物的存在下，基于（a）第Ⅷ族金属的盐和（b）选自阳离子 氧化剂和通式为RnH4-nN +，RmH3-mC +和RmH3-mO +的阳离子，其中n为0,1,2,3或4，m为2或3，R为烃基和/或两个或三个 的R原子与带正电荷的原子一起表示环结构，应当理解，当n为3时，R中最多两个与氮一起表示杂环结构，当n为4时，R中的三个与氮一起 表示芳族杂环结构。