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    Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound
    3.
    发明授权
    Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound 失效
    一氧化碳与烯属不饱和化合物共聚的方法

    公开(公告)号：US5741939A

    公开(公告)日：1998-04-21

    申请号：US619868

    申请日：1996-03-21

    申请人： Frank Baardman ,  Arleen Marie Bradford ,  Jayne Jubb ,  Pieter Scheerman ,  Rudolf Jacobus Wijngaarden

    发明人： Frank Baardman ,  Arleen Marie Bradford ,  Jayne Jubb ,  Pieter Scheerman ,  Rudolf Jacobus Wijngaarden

    IPC分类号： B01J31/18 ,  B01J31/24 ,  C08G67/02 ,  C07C45/49

    CPC分类号： C08G67/02 ,  B01J31/2409 ,  B01J2531/80 ,  B01J31/1895

    摘要： A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound comprising contacting the monomers in the presence of a liquid diluent with a catalyst composition which is based on (a) a source of a Group VIII metal, (b) a bidentate ligand of the general formula R.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4 wherein M.sup.1 and M.sup.2 independently represent a phosphorus, arsenic or antimony atom, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent unsubstituted or substituted hydrocarbyl groups on the understanding that at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a polar substituted aryl group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and (c) a boron hydrocarbyl compound, with application of a stirring power transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.

    摘要翻译： 一种一氧化碳与烯属不饱和化合物共聚的方法，包括在液体稀释剂存在下使单体与催化剂组合物接触，所述催化剂组合物基于（a）Ⅷ族金属源，（b）二元配体 通式R1R2M1-R-M2R3R4其中M1和M2独立地表示磷，砷或锑原子，R1，R2，R3和R4独立地表示未取代或取代的烃基，其理解是R1，R2，R3和 R4表示极性取代的芳基，R表示桥中含有至少两个碳原子的二价桥连基团，和（c）硼烃基化合物，通过施加向聚合混合物中传递至少0.25kW / m3。

    Process for the preparation of a copolymer of carbon monoxide
    5.
    发明授权
    Process for the preparation of a copolymer of carbon monoxide 失效
    制备一氧化碳共聚物的方法

    公开(公告)号：US5747638A

    公开(公告)日：1998-05-05

    申请号：US813769

    申请日：1997-03-07

    申请人： Eit Drent ,  Frits Van Der Veer ,  Rudolf Jacobus Wijngaarden

    发明人： Eit Drent ,  Frits Van Der Veer ,  Rudolf Jacobus Wijngaarden

    IPC分类号： C08G67/00 ,  C08G67/02

    CPC分类号： C08G67/02

    摘要： A process for the copolymerization of carbon monoxide with ethene and optionally another olefinically unsaturated compound in which process the monomers are copolymerized in the presence of a liquid diluent and a catalyst composition which is based on (a) a Group VIII metal compound, (b) an anion of an acid which is obtainable by combining a Br.o slashed.nsted acid with a Lewis acid, and (c) an organic oxidant in a quantity of less than 30 moles per mole of Group VIII metal.

    摘要翻译： 一种一氧化碳与乙烯和任选的另一种烯属不饱和化合物共聚的方法，其中单体在液体稀释剂和基于（a）第Ⅷ族金属化合物的催化剂组合物存在下共聚合，（b） 可通过将Br + 526 nsted酸与路易斯酸结合得到的酸阴离子，和（c）每摩尔第Ⅷ族金属少于30摩尔量的有机氧化剂。

    Preparation of catalyst solution
    6.
    发明授权
    Preparation of catalyst solution 失效
    催化剂溶液的制备

    公开(公告)号：US5684123A

    公开(公告)日：1997-11-04

    申请号：US783964

    申请日：1997-01-15

    申请人： Frits Van Der Veer ,  Rudolf Jacobus Wijngaarden

    发明人： Frits Van Der Veer ,  Rudolf Jacobus Wijngaarden

    IPC分类号： B01J31/24 ,  C08F4/02 ,  C08F4/60 ,  C08F4/80 ,  C08G67/02 ,  B01J31/00 ,  C08K5/49

    CPC分类号： B01J31/2409 ,  B01J31/2404 ,  C08G67/02 ,  B01J2231/10 ,  B01J2531/824

    摘要： A process for the preparation of a solution of a catalyst system, suitable for use in a process for copolymerizing carbon monoxide and one or more ethylenically unsaturated compounds, which comprises (a) combining a palladium compound, a bisphosphine of the general formula R.sup.1 R.sup.2 P--R--PR.sup.3 R.sup.4 (I) wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents an aromatic hydrocarbyl group which is substituted with an alkoxy group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and a lower alcohol as solvent, and (b) admixing the obtained combination after a generation period G, during which a temperature T in the range of 0.degree.-70.degree. C. is maintained, with an acid having a pKa of less than 2, whereby the said generation period G is selected such that the value for G (in hours) and the temperature T in .degree.C.) are related as ##EQU1##

    摘要翻译： 一种制备适用于共聚一氧化碳和一种或多种烯属不饱和化合物的方法的催化剂体系溶液的方法，其包括（a）将钯化合物，通式为R1R2P-R的双膦 -PR 3 R 4（I）其中R 1，R 2，R 3和R 4各自独立地表示被烷氧基取代的芳族烃基，R表示桥中含有至少两个碳原子的二价桥连基团，低级醇为 溶剂，和（b）在保持了0〜70℃范围内的温度T与pKa小于2的酸的生成周期G之后将得到的组合物混合，由此所述代 选择周期G，使得G（小时）的值和DEGC中的温度T）与相关

    Process for the extraction of material from multi-phase systems
    7.
    发明授权
    Process for the extraction of material from multi-phase systems 失效
    从多相系统中提取材料的方法

    公开(公告)号：US6043299A

    公开(公告)日：2000-03-28

    申请号：US950683

    申请日：1997-10-15

    申请人： Rudolf Jacobus Wijngaarden ,  Ye-Mon Chen ,  David Karl Schisla

    发明人： Rudolf Jacobus Wijngaarden ,  Ye-Mon Chen ,  David Karl Schisla

    IPC分类号： B01D11/04 ,  C08F6/02 ,  C08F6/06 ,  B01D11/00

    CPC分类号： C08F6/02 ,  B01D11/0446 ,  C08F6/06

    摘要： A method for extracting and separating extractive components from fluids is provided. A first fluid and an extraction fluid are added to a vessel, thereby creating a two-phase two-layer system, wherein the first fluid and the extraction fluid are discrete and the two-phase system has a first fluid/extraction fluid interface. The two-phase system is then agitated, wherein the first fluid phase and the extraction fluid phase remain as substantially discrete layers. A means for communication between the first fluid and the extraction fluid is provided. The communication of the phases results in the extractive components being extracted from the first fluid into the extraction fluid. Agitation is stopped and the first fluid is recovered having reduced extractive components.

    摘要翻译： 提供了一种从流体中提取和分离提取组分的方法。 将第一流体和萃取流体加入到容器中，从而产生两相双层系统，其中第一流体和萃取流体是离散的，并且两相系统具有第一流体/萃取流体界面。 然后搅拌两相系统，其中第一流体相和萃取流体相保持基本上离散的层。 提供了用于第一流体和提取流体之间的连通的装置。 相的通信导致萃取组分从第一流体提取到萃取流体中。 停止搅拌，并回收具有降低的萃取组分的第一流体。

    Preparation of catalyst solution
    8.
    发明授权
    Preparation of catalyst solution 失效
    催化剂溶液的制备

    公开(公告)号：US5654250A

    公开(公告)日：1997-08-05

    申请号：US442521

    申请日：1995-05-16

    申请人： Frits Van Der Veer ,  Rudolf Jacobus Wijngaarden

    发明人： Frits Van Der Veer ,  Rudolf Jacobus Wijngaarden

    IPC分类号： B01J31/24 ,  C08F4/02 ,  C08F4/60 ,  C08F4/80 ,  C08G67/02 ,  B01J31/00 ,  B01J27/188

    CPC分类号： B01J31/2409 ,  B01J31/2404 ,  C08G67/02 ,  B01J2231/10 ,  B01J2531/824

    摘要： A process for the preparation of a solution of a catalyst system, suitable for use in a process for copolymerizing carbon monoxide and one or more ethylenically unsaturated compounds, which comprises (a) combining a palladium compound, a bisphosphine of the general formula R.sup.1 R.sup.2 P-R-PR.sup.3 R.sup.4 (I) wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents an aromatic hydrocarbyl group which is substituted with an alkoxy group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and a lower alcohol as solvent, and (b) admixing the obtained combination after a generation period G, during which a temperature T in the range of 0.degree.-70.degree. C. is maintained, with an acid having a pKa of less than 2, whereby the said generation period G is selected such that the value for G (in hours) and the temperature T (in .degree.C.) are related as ##EQU1##

    摘要翻译： 一种制备适用于共聚一氧化碳和一种或多种烯属不饱和化合物的方法的催化剂体系溶液的方法，其包括（a）将钯化合物，通式为R1R2P-R的双膦 -PR 3 R 4（I）其中R 1，R 2，R 3和R 4各自独立地表示被烷氧基取代的芳族烃基，R表示桥中含有至少两个碳原子的二价桥连基团，低级醇为 溶剂，和（b）在保持了0〜70℃范围内的温度T与pKa小于2的酸的生成周期G之后将得到的组合物混合，由此所述代 选择周期G，使得G（小时）和温度T（在DEGC中）的值与