Process for the preparation of polyolefins
    6.
    发明授权
    Process for the preparation of polyolefins 失效
    制备聚烯烃的方法

    公开(公告)号:US5672668A

    公开(公告)日:1997-09-30

    申请号:US107187

    申请日:1993-08-16

    摘要: A process for the preparation of an olefin polymer by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are a hydrogen atom or a hydrocarbon radical having 1 to 14 carbon atoms, or R.sup.a and R.sup.b, together with the atoms connecting them, can form a ring, at a temperature of from -60.degree. to 200.degree. C., at a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of a catalyst formed from a metallocene in the meso-form or a meso:rac mixture, with meso:rac>1:99, as transition-metal compound and a cocatalyst, wherein the metallocene is a compound of the formula I, ##STR1## in which M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are identical or different and are methyl or chlorine, R.sup.3 and R.sup.6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R.sup.4 and R.sup.5 are hydrogen or as defined for R.sup.3 and R.sup.6, or R.sup.4 forms an aliphatic or aromatic ring with R.sup.6, or adjacent radicals R.sup.4 form a ring of this type, and R.sup.7 is a ##STR2## radical, and m plus n is zero or 1.

    摘要翻译: 通过聚合或共聚式Ra-CH = CH-Rb的烯烃制备烯烃聚合物的方法,其中Ra和Rb相同或不同,并且是氢原子或具有1至14碳原子的烃基 原子或R a和R b与连接它们的原子一起在-60至200℃的温度下,在0.5至100巴的压力下,在溶液中,悬浮液中或在 在由外消旋混合物中内消旋金属茂或内消旋混合物形成的催化剂的存在下,作为过渡金属化合物和助催化剂,其中金属茂是化合物 其中M1是Zr或Hf,R1和R2是相同或不同的,是甲基或氯的式I,其中R 3和R 6相同或不同,是甲基,异丙基,苯基,乙基或三氟甲基 ,R 4和R 5是氢或如对R 3和R 6所定义,或者R 4与R 6或相邻的镭形成脂族或芳族环 ls R4形成这种类型的环,而R7是a