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    Process for producing thermoformed articles
    1.
    发明授权
    Process for producing thermoformed articles 有权
    生产热成型制品的方法

    公开(公告)号：US07855263B2

    公开(公告)日：2010-12-21

    申请号：US11883715

    申请日：2006-01-30

    申请人： Friederike Morhard ,  Gabriella Sartori ,  Alexander Fuchs ,  Claus Gabriel

    发明人： Friederike Morhard ,  Gabriella Sartori ,  Alexander Fuchs ,  Claus Gabriel

    IPC分类号： C08L23/10 ,  C08F10/04 ,  C08F10/14 ,  C08F110/04 ,  C08F110/06

    CPC分类号： B29C51/002 ,  B29K2023/12 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L23/142 ,  C08L2205/02 ,  C08L2666/06

    摘要： A process for obtaining thermoformed articles, comprising the following steps: a) forming a sheet comprising a propylene resin; b) thermoforming the sheet obtained in step a); wherein said propylene resin has the following characteristics: a) distribution of molecular weight Mw/Mn lower than 4; preferably lower than 3; b) 2,1 insertions measured with by 13C-NMR lower than 0.50%; preferably lower than 0.40%; c) eta* and the frequency ω meet the following relation for ω comprised between 0.1 ad 1: eta*>3700ω(−0 13) d) melt flow rate (MFR) (ISO 1133) lower than 5; preferably lower than 4; more preferably lower than 3; wherein the polypropylene resin comprises: (i) from 10 to 100% by weight of a propylene homopolymer or a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2═CHZ wherein Z is a linear or branched C2-C20 radical; and (ii) from 0 to 90% by weight of a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2═CHZ wherein Z is a linear or branched C2-C20 radical, said propylene copolymer having a content of ethylene or an alpha-olefin of formula CH2═CHZ different from the propylene copolymer (i).

    摘要翻译： 一种获得热成型制品的方法，包括以下步骤：a）形成包含丙烯树脂的片材; b）对在步骤a）中获得的片材进行热成型; 其中所述丙烯树脂具有以下特性：a）分子量Mw / Mn低于4的分布; 优选低于3; b）通过13 C-NMR测量的2,1次插入低于0.50％; 优选低于0.40％; c）eta *，频率ω满足以下关系：ω为0.1 ad 1：eta *>3700ω（-0 13）d）熔体流动速率（MFR）（ISO 1133）低于5; 优选低于4; 更优选低于3; 其中所述聚丙烯树脂包括：（i）10至100重量％的丙烯均聚物或含有0.1至10摩尔％的衍生单元的乙烯或式CH 2 = CHZ的α-烯烃的丙烯共聚物，其中Z 是直链或支链C2-C20基; 和（ii）0至90重量％的含有0.1至10摩尔％的乙烯或式CH 2 = CHZ的α-烯烃的衍生单元的丙烯共聚物，其中Z为直链或支链C 2 -C 20基团 所述丙烯共聚物具有不同于丙烯共聚物（i）的乙烯或式CH 2 = CHZ的α-烯烃的含量。

    Process for Producing Thermoformed Articles
    2.
    发明申请
    Process for Producing Thermoformed Articles 有权
    生产热成型制品的工艺

    公开(公告)号：US20090012239A1

    公开(公告)日：2009-01-08

    申请号：US11883715

    申请日：2006-01-30

    申请人： Friederike Morhard ,  Gabriella Sartori ,  Alexander Fuchs ,  Claus Gabriel

    发明人： Friederike Morhard ,  Gabriella Sartori ,  Alexander Fuchs ,  Claus Gabriel

    IPC分类号： C08L23/12

    CPC分类号： B29C51/002 ,  B29K2023/12 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L23/142 ,  C08L2205/02 ,  C08L2666/06

    摘要： A process for obtaining thermoformed articles, comprising the following steps: a) forming a sheet comprising a propylene resin; b) thermoforming the sheet obtained in step a); wherein said propylene resin has the following characteristics: a) distribution of molecular weight Mw/Mn lower than 4; preferably lower than 3; b) 2.1 insertions measured with by 13C-NMR lower than 0.50%; preferably lower than 0.40%; c) eta* and the frequency ω meet the following relation for ω comprised between 0.1 and 1: eta*>3700ω(−0 13) d) melt flow rate (MFR) (ISO 1133) lower than 5; preferably lower than 4; more preferably lower than 3; wherein the polypropylene resin comprises: (i) from 10 to 100% by weight of a propylene homopolymer or a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2═CHZ wherein Z is a linear or branched C2-C20 radical; and (ii) from 0 to 90% by weight of a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2═CHZ wherein Z is a linear or branched C2-C20 radical, said propylene copolymer having a content of ethylene or an alpha-olefin of formula CH2═CHZ different from the propylene copolymer (i).

    摘要翻译： 一种获得热成型制品的方法，包括以下步骤：a）形成包含丙烯树脂的片材; b）对在步骤a）中获得的片材进行热成型; 其中所述丙烯树脂具有以下特性：a）分子量Mw / Mn低于4的分布; 优选低于3; b）2.1用13 C-NMR测量的低于0.50％的插入; 优选低于0.40％; c）eta *，频率ωm满足以下关系：ω= 0.1和1：ηa> 3700m（-0.13）d）熔体流动速率（MFR）（ISO 1133）低于5; 优选低于4; 更优选低于3; 其中所述聚丙烯树脂包含：（i）10至100重量％的丙烯均聚物或含有0.1至10摩尔％的衍生单元的乙烯或式CH 2 -CHZ的α-烯烃的丙烯共聚物，其中Z 是直链或支链C2-C20基; 和（ii）0至90重量％的含有0.1至10摩尔％的乙烯或式CH2-CHZ的α-烯烃的衍生单元的丙烯共聚物，其中Z为直链或支链C 2 -C 20基团 所述丙烯共聚物具有不同于丙烯共聚物（i）的乙烯或式CH 2 -CHZ的α-烯烃的含量。

    Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency
    4.
    发明申请
    Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency 审中-公开
    丙烯共聚物组合物具有良好的低温冲击韧性和高透明度

    公开(公告)号：US20060167185A1

    公开(公告)日：2006-07-27

    申请号：US10517580

    申请日：2003-06-10

    申请人： Alexander Fuchs ,  Friederike Morhard

    发明人： Alexander Fuchs ,  Friederike Morhard

    IPC分类号： C08L23/04

    CPC分类号： C08L23/10 ,  C08L23/142 ,  C08L2205/02 ,  C08L2205/04 ,  C08L2205/22 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/06

    摘要： The present invention relates to a propylene copolymer composition comprising A) a propylene polymer containing from 0 to 10% by weight of olefins other than propylene and B) at least one propylene copolymer containing from 5 to 40% by weight of olefins other than propylene, where the propylene polymer A and the propylene copolymer B are present as separate phases and the propylene copolymer composition has a haze value of ≦30%, based on a path length of the propylene copolymer composition of 1 mm, and the brittle/tough transition temperature of the propylene copolymer composition is ≦−15° C.

    摘要翻译： 丙烯共聚物组合物本发明涉及丙烯共聚物组合物，其包含A）含有0-10重量％的除丙烯以外的烯烃的丙烯聚合物，和B）至少一种含有5-40重量％的除丙烯以外的烯烃的丙烯共聚物， 其中丙烯聚合物A和丙烯共聚物B作为分离相存在，丙烯共聚物组合物的雾度值<= 30％，基于丙烯共聚物组合物的路径长度为1mm，脆性/韧性转变 丙烯共聚物组合物的温度为<= -15℃

    Process for polymerizaing 1-hexene or higher alpha-olefins
    6.
    发明授权
    Process for polymerizaing 1-hexene or higher alpha-olefins 失效
    聚合1-己烯或更高级α-烯烃的方法

    公开(公告)号：US07977444B2

    公开(公告)日：2011-07-12

    申请号：US10592564

    申请日：2005-03-08

    申请人： Luigi Resconi ,  Eleonora Ciaccia ,  Friederike Morhard ,  Giampaolo Pellegatti

    发明人： Luigi Resconi ,  Eleonora Ciaccia ,  Friederike Morhard ,  Giampaolo Pellegatti

    IPC分类号： C08F4/6592 ,  C08F4/642 ,  C08F210/08 ,  C08F210/14

    CPC分类号： C08F210/14 ,  C08F4/65912 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/03 ,  C08F210/08

    摘要： A process for preparing a polymer containing derived units of one or more alpha olefins of formula CH2═CHW wherein W is a C3-C10 hydrocarbon radical and optionally from 0 to 81% by mol of derived units of propylene or 1-butene, comprising contacting under polymerization conditions one or more alpha olefins of formula CH2═CHW and optionally propylene or 1-butene in the presence of a catalyst system obtainable by contacting:a) a metallocene compound of formula (I) wherein M, X, L, T, R1, R2, R7 and R8 are described in the text; and (b) an alumoxane or a compound capable of forming an alkyl metallocene cation.

    摘要翻译： 一种制备含有一种或多种式CH 2 = CHW的α-烯烃的衍生单元的聚合物的方法，其中W是C 3 -C 10烃基和任选地0至81摩尔％的丙烯或1-丁烯的衍生单元，包括接触 在聚合条件下，在一种催化剂体系的存在下，通过使以下物质接触，得到一种或多种式CH 2 = CHW的α-烯烃和任选的丙烯或1-丁烯：a）式（I）的茂金属化合物，其中M，X，L，T， R1，R2，R7和R8在文中描述; 和（b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

    1-butene polymer and process for the preparation thereof
    7.
    发明授权
    1-butene polymer and process for the preparation thereof 有权
    1-丁烯聚合物及其制备方法

    公开(公告)号：US07534841B2

    公开(公告)日：2009-05-19

    申请号：US11665821

    申请日：2005-09-29

    申请人： Luigi Resconi ,  Maria Silvia Tonti ,  Friederike Morhard

    发明人： Luigi Resconi ,  Maria Silvia Tonti ,  Friederike Morhard

    IPC分类号： C08F4/64 ,  C08F4/76 ,  C08F210/08

    CPC分类号： C08F10/08 ,  C08F4/65912 ,  C08F110/08 ,  C08F210/08 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/17

    摘要： A 1-butene polymer optionally containing from 0 to 30% by mol of derived units of ethylene, propylene or alpha-olefin of formula CH2═CHZ, wherein Z is a C3-C20 linear or branched alkyl radical, having the following features: a) distribution of molecular weight (Mw/Mn) lower than 4; b) Melt flow rate (MFR) measured according to ISO 1133 (190° C., 2.16 kg); c) Intrinsic viscosity (IV) measured in tetrahydronaftalene (THN) at 135° C. lower than 0.8 dl/g; d) melting point higher than 100° C.; e) isotactic pentads (mmmm) measured with 13C-NMR operating at 100.61 MHz higher than 90%; f) 4,1 insertions not detectable at a C13-NMR operating at 100.61 MHz; and g) a yellowness index lower than 0.

    摘要翻译： 任选地含有0至30摩尔％的乙烯，丙烯或式CH 2 -CHZ的α-烯烃的衍生单元的1-丁烯聚合物，其中Z为C 3 -C 20直链或支链烷基，具有以下特征：a ）分子量（Mw / Mn）低于4的分布; b）根据ISO 1133（190℃，2.16kg）测量的熔体流动速率（MFR）; c）在135℃下在四氢萘甲酸（THN）中测得的特性粘度（IV）低于0.8dl / g; d）熔点高于100℃。 e）使用13 C-NMR测量的100.61MHz高于90％的全同立构五单元组（mmmm）; f）在100.61MHz的C 13-NMR下不能检测到4,1个插入; 和g）黄色指数低于0。

    Process for the Preparation of 1-Butene/Propylene Copolymers
    9.
    发明申请
    Process for the Preparation of 1-Butene/Propylene Copolymers 有权
    1-丁烯/丙烯共聚物的制备方法

    公开(公告)号：US20070299223A1

    公开(公告)日：2007-12-27

    申请号：US11667350

    申请日：2005-10-20

    申请人： Luigi Resconi ,  Simona Guidotti ,  Friederike Morhard ,  Anna Fait

    发明人： Luigi Resconi ,  Simona Guidotti ,  Friederike Morhard ,  Anna Fait

    IPC分类号： C08F210/08

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/06 ,  C08F210/08 ,  C08F210/10 ,  C08F2/06 ,  C08F2500/11 ,  C08F2500/03 ,  C08F2500/15 ,  C08F2500/17

    摘要： A solution polymerization process for obtaining isotactic, crystalline or crystallisable 1-butene/propylene polymers comprising contacting under polymerization conditions at a temperature ranging from 50° C. to 90° C. 1-butene and propylene in the presence of a catalyst system obtainable by contacting: a) at least one metallocene compound; b) an alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the polymerization medium consists of a mixture of 1-butene and propylene wherein the content of propylene in the liquid phase ranges from 1% to 60% by weight.

    摘要翻译： 用于获得全同立构，结晶或可结晶的1-丁烯/丙烯聚合物的溶液聚合方法，包括在聚合条件下在50℃至90℃的温度范围内接触1-丁烯和丙烯，所述催化剂体系可由 接触：a）至少一种茂金属化合物; b）铝氧烷或能够形成烷基茂金属阳离子的化合物; 和任选地c）有机铝化合物; 其中聚合介质由1-丁烯和丙烯的混合物组成，其中液相中丙烯的含量为1重量％至60重量％。