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1.发明授权
公开(公告)号：US4640832A
公开(公告)日：1987-02-03
申请号：US772395
申请日：1985-09-04
CPC分类号： C01B17/34 , C01P2006/80
摘要： There is described a process for the production of pure sodium polysulfides directly from the elements sodium and sulfur. For this purpose, the sodium and the sulfur under a protective gas and in a stoichiometrical ratio corresponding to the desired polysulfide are alternatingly dosed into a previously present melt of a polysulfide with vigorous stirring, the dosing being in portions such that upon introduction of the sodium the reaction mixture remains in the condition of a stirrable suspension and upon introduction of the sulfur this is completely reacted to a polysulfide of the desired or higher sulfur content.
摘要翻译： 描述了直接从元素钠和硫生产纯多硫化钠的方法。 为此，将保护气体下的钠和硫与化学计量比对应于所需的多硫化物交替计量到先前存在的多硫化物的熔体中，同时剧烈搅拌，该给药部分使得在引入钠 反应混合物保持在可搅拌悬浮液的状态，并且在引入硫时，其与所需或更高硫含量的多硫化物完全反应。
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2.发明授权
公开(公告)号：US5080881A
公开(公告)日：1992-01-14
申请号：US405864
申请日：1989-09-11
申请人： Friedrich Bittner , Walter Hinrichs , Herbert Hovestadt, deceased , Ludwig Lange , Erich Splett
发明人： Friedrich Bittner , Walter Hinrichs , Herbert Hovestadt, deceased , Ludwig Lange , Erich Splett
CPC分类号： C01B17/34 , B01J19/14 , B01J19/18 , B01J4/001 , B01J2219/00029 , B01J2219/0009 , B01J2219/00132 , B01J2219/00768 , C01P2006/80
摘要： Methods for the preparation of lower sodium polysulfides such as sodium disulfide from higher sodium polysulfides and sodium. To this end, either molten sodium polysulfide placed in a receiver is reacted with sodium in a stoichiometric ratio corresponding to the desired product under vigorous agitation and under protective gas or the higher polysulfide and the sodium are dosed into a polysulfide melt in a receiver under the same conditions either alternatively or simultaneously. In all instances, the dosing of the sodium is set so that the reaction mixture remains capable of being agitated and the agitation is continued until the desired product composition has been achieved.
摘要翻译： 从较高的多硫化钠和钠制备低级多硫化钠如二硫化钠的方法。 为此，放置在接收器中的熔融多硫化钠中的钠与化学计量比对应于所需产物在剧烈搅拌下并在保护气体下或在较高的多硫化物和钠在下面的接收器中加入多硫化物熔体 相同条件可选择或同时进行。 在所有情况下，将钠的配量设定为使得反应混合物保持能够搅拌并继续搅拌直到达到所需的产品组合物。
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3.发明授权Process for working up the filtration residue of crude sodium prepared by fusion electrolysis into a high-purity sodium alcholate 失效将通过熔融电解制备的粗制钠的过滤残渣加工成高纯度的乙酸钠的方法
公开(公告)号：US4857665A
公开(公告)日：1989-08-15
申请号：US144346
申请日：1988-01-15
CPC分类号： C07C29/70
摘要： A process for converting the filtration residue of crude sodium produced by fusion electrolysis into a sodium alcoholate with a low NaOH content. The residue first is intensively and continuously mixed for 2-5 hours at 300.degree.-600.degree. C. and then is added with stirring to the particular alcohol, possibly with heat added. The alcoholate solution so formed is filtered and the alcoholate may be obtained from the filtrate by distilling off the solvent.
摘要翻译： 将通过熔融电解产生的粗制钠的过滤残余物转化为低NaOH含量的醇钠的方法。 残余物首先在300-600℃下强烈连续混合2-5小时，然后在搅拌下加入特定的醇，可能加热。 将如此形成的醇化物溶液过滤，并通过蒸除溶剂从滤液中获得醇化物。
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4.发明授权Process for creating the flow properties to sodium-production filter residues 失效用于产生钠生产过滤残留物的流动性能的方法
公开(公告)号：US4767453A
公开(公告)日：1988-08-30
申请号：US144347
申请日：1988-01-15
CPC分类号： C22B26/10 , Y02P10/138 , Y02P10/212
摘要： A process is described for creating the flow properties to filtration residues from sodium production. These viscous-to-hard filter residues can be changed into a thin-fluid consistency by intensively agitating them under an inert gas for 2-6 hours at temperatures between 300.degree. and 600.degree. C.
摘要翻译： 描述了一种用于创建从钠生产过滤残余物的流动性质的方法。 通过在惰性气体下在300〜600℃的温度下将它们强烈搅拌2-6小时，可将这些粘稠硬过滤残渣变成薄流体稠度。
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公开(公告)号：US5075098A
公开(公告)日：1991-12-24
申请号：US510269
申请日：1990-04-19
申请人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
发明人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
IPC分类号： C01B17/22
CPC分类号： C01B17/22 , C01P2004/60 , C01P2006/80
摘要： A method of preparing sodium monosulfide by means of reacting a sodium polysulfide with sodium under protective gas, the sodium polysulfide is placed in a first stage in a finely distributed, solid state in a receiver, preheated to temperatures of 100.degree.-150.degree. C., liquid sodium is gradually added in the required amount to the material in the receiver under intensive mixing, whereby the temperature of the reaction mixture is maintained at 120.degree.-250.degree. C. and in a second stage the formed initial product is allowed to continue to react, or postreact under continuation of the mixing at 250.degree.-480.degree. C., until a Na.sub.2 S content of at least 95% by weight has been attained.
摘要翻译： 通过在保护气体下使多硫化钠与钠反应制备单硫化钠的方法，将多硫化钠置于接收器中以细分散的固态的第一阶段，预热至100-150℃的温度。 在密集混合下，将液态钠逐渐加入接收器中的物质，由此将反应混合物的温度保持在120-250℃，在第二阶段中使形成的初始产物继续 在250-480℃下继续混合反应或反应，直至达到至少95重量％的Na 2 S含量。
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公开(公告)号：US5039506A
公开(公告)日：1991-08-13
申请号：US510268
申请日：1990-04-19
申请人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
发明人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
IPC分类号： C01B17/22
CPC分类号： C01B17/22 , C01P2004/60 , C01P2006/80
摘要： In a method of preparing sodium monosulfide by means of reacting sodium and sulfur under protective gas, the entire sodium determined for reaction is placed in a receiver in a first stage, preheated to temperatures of 100.degree.-150.degree. C., sulfur is gradually added in the required amount of the material in the receiver under intensive mixing, whereby the temperature of the reaction mixture is maintained at 120.degree.-250.degree. C., and in a second stage the formed initial product is allowed to react under continuation of the mixing at 250.degree.-480.degree. C., until a Na.sub.2 S content of at least 95% by weight has been attained.
摘要翻译： 在保护气体中通过使钠和硫反应制备单硫化钠的方法中，将反应中确定的全部钠置于第一阶段的接收器中，预热至100-150℃，逐渐加入硫 在强化混合下在接收器中的所需量的材料，由此将反应混合物的温度保持在120-250℃，在第二阶段中，使形成的初始产物在混合物的继续下进行反应 在250-480℃下，直至达到至少95重量％的Na 2 S含量。
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公开(公告)号：US5039505A
公开(公告)日：1991-08-13
申请号：US510267
申请日：1990-04-19
申请人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
发明人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
IPC分类号： C01B17/22
CPC分类号： C01B17/22 , C01P2004/60 , C01P2006/80
摘要： A method of preparing sodium monosulfide by means of reacting sodium and sulfur under protective gas, wherein sodium monosulfide is placed in a first stage in a receiver in a finely distributed, solid state, the initial material is preheated to 120.degree.-150.degree. C. and sulfur and sodium are alternately added in the required amount ratio under intensive mixing, whereby the temperature of the reation mixture is maintained at 120.degree.-250.degree. C., and in a second stage the formed initial product is allowed to continue to react or postreact under continuation of the mixing at 250.degree.-480.degree. C., until a Na.sub.2 S content of at least 95% by weight has been attained.
摘要翻译： 通过在保护气体下使钠和硫反应制备单硫化钠的方法，其中单硫化钠以细分散的固体状态放置在接收器中的第一阶段中，将初始材料预热至120℃-150℃。 在浓缩混合下以所需量的比率交替地添加硫和钠，由此将该回收混合物的温度保持在120〜-250℃，在第二阶段使形成的初始产物继续反应或 在250°-480℃的混合下继续反应，直至达到至少95重量％的Na 2 S含量。
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8.发明授权
公开(公告)号：US4584068A
公开(公告)日：1986-04-22
申请号：US668051
申请日：1984-11-05
申请人： Walter Hinrichs , Ludwig Lange , Friederich Hammer , Hans Ludwig
发明人： Walter Hinrichs , Ludwig Lange , Friederich Hammer , Hans Ludwig
摘要： A device for the fused salt electrolysis of alkali metal halides by the Downs principle becomes operable on an expanded scale, by a process ensuring a favorable thermal economy of the cell, through the incorporation of a double bottom, an improved housing for receiving the anode sleeves, and a differentiatedly heat controllable base, shell, and cover construction with variable current load.
摘要翻译： 用于通过Downs原理进行的碱金属卤化物的熔融盐电解的装置可通过加入双层底部，用于接纳阳极套筒的改进的壳体，通过确保电池的良好的热经济性的方法，在扩展的尺度上可操作 ，以及具有可变电流负载的差分热可控的基座，外壳和盖结构。
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公开(公告)号：US4536938A
公开(公告)日：1985-08-27
申请号：US255512
申请日：1981-04-17
申请人： Walter Hinrichs , Friedrich Hammer , Ludwig Lange
发明人： Walter Hinrichs , Friedrich Hammer , Ludwig Lange
IPC分类号： B21C23/00 , B21C29/00 , B21C33/02 , B22D11/126
CPC分类号： B21C33/02 , Y10T29/49988 , Y10T29/49989
摘要： A process is described for the production of solid alkali metal strands, whereby molten alkali metal is introduced to an extrusion apparatus and is continuously cooled down as the metal travels along a section of the extrusion apparatus by means of a worm. There is a temperature gradient between the point at which the molten alkali metal enters the extruder down to a temperature below its solidification point near the nozzle, at which the metal is still sufficiently ductile for extrusion, and is then fed to a nozzle for shaping into the stands.
摘要翻译： 描述了用于生产固体碱金属股线的方法，其中熔融碱金属被引入到挤出装置中，并且随着金属通过蠕虫沿挤出装置的一部分行进而连续冷却。 在熔融碱金属进入挤压机的点之间存在温度梯度，其温度低于喷嘴附近的凝固点的温度，在该温度下金属仍然足够延展挤出，然后被供给到用于成形的喷嘴 立场。
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