摘要:
In a process for producing an alkali metal from alkali metal amalgam by electrolysis using an alkali metal amalgam as anode, a solid electrolyte which conducts alkali metal ions and a liquid alkali metal as cathode, the alkali metal amalgam as anode is kept in motion.
摘要:
The invention relates to an electrolysis cell comprising an anode compartment which comprises an aqueous solution of at least one alkali metal salt, a cathode compartment and a solid electrolyte which separates the anode compartment and the cathode compartment from one another, wherein that part of the surface of the solid electrolyte which is in contact with the anode compartment and/or that part of the surface of the solid electrolyte which is in contact with the cathode compartment has/have at least one further ion-conducting layer.
摘要:
An electrolytic cell comprises an agitated, alkali metal amalgam-containing anode, an alkali metal ion-conducting solid electrolyte and a cathode, wherein the solid electrolyte and the cathode are separated from one another by a liquid electrolyte.
摘要:
A process for producing metallic lithium starting from an aqueous solution of at least one lithium salt comprises the following steps: (I) Production of a lithium amalgam from an aqueous solution of at least one lithium salt; and (II) Electrolysis using an anode comprising the lithium amalgam, a solid electrolyte which conducts lithium ions, and liquid lithium as cathode, wherein the lithium amalgam as anode is kept in motion.
摘要:
A process for preparing sodium and aluminum chloride electrochemically is described in which, in an electrolytic cell containing aluminum as an anode and sodium as a cathode which are separated from one another by a sodium ion-conducting solid electrolyte, a fused electrolyte essentially containing sodium tetrachloroaluminate is electrolyzed in the anode compartment, aluminum chloride formed in this process is evaporated from the electrolytic cell and sodium is removed from the cathode compartment.
摘要:
A process for preparing sodium and aluminum chloride electrochemically is described in which, in an electrolytic cell containing aluminum as an anode and sodium as a cathode which are separated from one another by a sodium ion-conducting solid electrolyte, a fused electrolyte essentially containing sodium tetrachloroaluminate is electrolyzed in the anode compartment, aluminum chloride formed in this process is evaporated from the electrolytic cell and sodium is removed from the cathode compartment.
摘要:
The present invention relates to mixtures of alkali metal polysulfides and to mixtures of alkali metal polysulfides and alkali metal thiocyanates, to processes for preparation thereof, to the use thereof as heat transfer or heat storage fluids, and to heat transfer or heat storage fluids which comprise the mixtures of alkali metal polysulfides or the mixtures of alkali metal polysulfides and alkali metal thiocyanates.
摘要:
The invention relates to a device for storing heat, comprising a heat storage medium which absorbs heat in order to store heat and releases heat in order to use the stored heat, and a container for holding the heat storage medium, the container being closed by a gastight cover, and the device comprising volume compensation means in order to compensate for a volume increase of the heat storage medium (3) due to a temperature rise and a volume decrease due to a temperature reduction. The invention furthermore relates to a method for storing heat, in which heat is transferred to a heat storage medium in order to store heat or heat is discharged from the heat storage medium to the heat carrier in order to use the heat, the heat storage medium being held in a container which is closed by a gastight cover, wherein a volume expansion of the heat storage medium (3) is compensated for by a volume increase of the container (1) or by heat storage medium (3) flowing out of the container (1) into a buffer container (21; 63, 65), and a volume decrease of the heat storage medium (3) is compensated for by a volume decrease of the container (1) or by heat storage medium (3) flowing out of the buffer container (21; 63, 65) into the container (1).
摘要:
A method is provide for preparing potassium metal which comprises embedding a polycrystalline alkali metal β″-Al2O3 molding in an oxidic powder containing potassium and aluminum of a molar K2O:Al2O3 ratio within the range of 1:(x−1) to 1:(x+1), the weight of oxidic powder amounting to at least two times the weight of the molding; heating the embedded molding at a rate of at least 100° C. per hour to at least 1100° C.; and further heating to at least 1300° C., this temperature being maintained for at least one hour prior to cooling.
摘要翻译:提供一种制备金属钾的方法,其包括将多晶碱金属β“-Al 2 O 3成型体在含有K 2 O:Al 2 O 3摩尔比的钾和铝的氧化粉末中包含在1:(x-1)至1: (x + 1),氧化粉的重量为成型体重量的至少两倍; 以至少100℃/小时的速度将嵌入的模制件加热至至少1100℃; 并进一步加热至至少1300℃,该温度在冷却之前保持至少1小时。