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公开(公告)号：US09732025B2
公开(公告)日：2017-08-15
申请号：US14888535
申请日：2014-05-02
发明人： Yoshiaki Kawajiri , Andreas Sebastian Bommarius , Timothy C. Frank , Megan E. Donaldson , Jungmin Oh , Gaurav Agrawal
CPC分类号： C07C51/48 , B01D15/1857 , B01D15/362 , B01D15/3857 , C07C67/08 , C07C67/56 , Y02P20/127 , C07C69/14
摘要： A process for conducting equilibrium-limited chemical reactions that produce water as a reaction product. Specifically, a process that uses a reactive chromatography unit (RCU) to improve the efficiency of equilibrium-limited reactions, such as a process for reacting glycol ether (GE) and carboxylic acid (CA) to form water and glycol ether ester (GEE). The process includes supplying GE and CA to the RCU, where one of either the CA or the GE is in a stoichiometric deficit relative to the other reactant. The reactant in the stoichiometric deficit reacts in the presence of the catalyst in the RCU to form a mixture of GEE and water. A raffinate is separated from the mixture using the separation media of the RCU contains at least the GEE. An extract separated from the mixture using the separation media of the RCU contains at least the water.
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公开(公告)号：US20170216740A1
公开(公告)日：2017-08-03
申请号：US15316542
申请日：2015-06-04
CPC分类号： B01D15/1857 , C07C67/08 , C07C67/56 , C07C69/14
摘要： The present disclosure provides for a process for supplying a first reactant and a second reactant (reactants) to a simulated moving bed reactor (SMBR) at each step of a sequential repeating injection cycle, where the SMBR includes zones each having an injection point and each containing a solid separation media; reacting the reactants in the SMBR during the sequential repeating injection cycle (cycle) to form a first product; separating the first product in the SMBR with the solid separation media; and changing an amount of one or both of the reactants injected at one or more of the injection points of the SMBR during a step of the cycle. Changing the amount of the reactants can be done at each step of the sequential repeating injection cycle. Changing the amount can include changing an inlet concentration of the reactants injected at one or more of the injection points during each step of the cycle.
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公开(公告)号：US09914072B2
公开(公告)日：2018-03-13
申请号：US15316542
申请日：2015-06-04
CPC分类号： B01D15/1857 , C07C67/08 , C07C67/56 , C07C69/14
摘要： The present disclosure provides for a process for supplying a first reactant and a second reactant (reactants) to a simulated moving bed reactor (SMBR) at each step of a sequential repeating injection cycle, where the SMBR includes zones each having an injection point and each containing a solid separation media; reacting the reactants in the SMBR during the sequential repeating injection cycle (cycle) to form a first product; separating the first product in the SMBR with the solid separation media; and changing an amount of one or both of the reactants injected at one or more of the injection points of the SMBR during a step of the cycle. Changing the amount of the reactants can be done at each step of the sequential repeating injection cycle. Changing the amount can include changing an inlet concentration of the reactants injected at one or more of the injection points during each step of the cycle.
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公开(公告)号：US20160145184A1
公开(公告)日：2016-05-26
申请号：US14888535
申请日：2014-05-02
发明人： Yoshiaki Kawajiri , Andreas Sebastian Bommarius , Timothy C. Frank , Mega E. Donaldson , Jungmin Oh , Gaurav Agrawal
IPC分类号： C07C51/48
CPC分类号： C07C51/48 , B01D15/1857 , B01D15/362 , B01D15/3857 , C07C67/08 , C07C67/56 , Y02P20/127 , C07C69/14
摘要： A process for conducting equilibrium-limited chemical reactions that produce water as a reaction product. Specifically, a process that uses a reactive chromatography unit (RCU) to improve the efficiency of equilibrium-limited reactions, such as a process for reacting glycol ether (GE) and carboxylic acid (CA) to form water and glycol ether ester (GEE). The process includes supplying GE and CA to the RCU, where one of either the CA or the GE is in a stoichiometric deficit relative to the other reactant. The reactant in the stoichiometric deficit reacts in the presence of the catalyst in the RCU to form a mixture of GEE and water. A raffinate is separated from the mixture using the separation media of the RCU contains at least the GEE. An extract separated from the mixture using the separation media of the RCU contains at least the water.
摘要翻译： 一种产生水作为反应产物的平衡限制化学反应的方法。 具体地，使用反应性色谱单元（RCU）来提高平衡有限反应的效率的方法，例如使二醇醚（GE）和羧酸（CA）反应形成水和二醇醚酯（GEE）的方法， 。 该方法包括向RCU提供GE和CA，其中CA或GE中的一个相对于其他反应物为化学计量的赤字。 化学计量缺口中的反应物在RCU中的催化剂存在下反应以形成GEE和水的混合物。 使用RCU的分离介质至少含有GEE，将萃余液与混合物分离。 使用RCU的分离介质与混合物分离的提取物至少含有水。
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