Cerium-iron-based magnetic compounds
    2.
    发明授权
    Cerium-iron-based magnetic compounds 有权
    铈 - 铁基磁性化合物

    公开(公告)号:US09548150B2

    公开(公告)日:2017-01-17

    申请号:US13786807

    申请日:2013-03-06

    CPC classification number: H01F1/0593

    Abstract: New magnetic materials containing cerium, iron, and small additions of a third element are disclosed. These materials comprise compounds Ce(Fe12−xMx) where x=1-4, having the ThMn12 tetragonal crystal structure (space group I4/mmm, #139). Compounds with M=B, Al, Si, P, S, Sc, Co, Ni, Zn, Ga, Ge, Zr, Nb, Hf, Ta, and W are identified theoretically, and one class of compounds based on M=Si has been synthesized. The Si cognates are characterized by large magnetic moments (4πMs greater than 1.27 Tesla) and high Curie temperatures (264≦Tc≦305° C.). The Ce(Fe12−xMx) compound may contain one or more of Ti, V, Cr, and Mo in combination with an M element. Further enhancement in Tc is obtained by nitriding the Ce compounds through heat treatment in N2 gas while retaining the ThMn12 tetragonal crystal structure; for example CeFe10Si2N1.29 has Tc=426° C.

    Abstract translation: 公开了含有铈,铁和少量添加第三元素的新的磁性材料。 这些材料包括具有ThMn12四方晶系结构(空间群I4 / mmm,#139)的x = 1-4的化合物Ce(Fe12-xMx)。 理论上确定M = B,Al,Si,P,S,Sc,Co,Ni,Zn,Ga,Ge,Zr,Nb,Hf,Ta和W的化合物,一类基于M = Si 已被合成。 Si同系物的特征在于大磁矩(4πMs大于1.27特斯拉)和高居里温度(264≤Tc≤305℃)。 Ce(Fe12-xMx)化合物可以含有与M元素组合的Ti,V,Cr和Mo中的一种或多种。 通过在N 2气中热处理氮化Ce化合物同时保留ThMn12四方晶体结构,可以进一步提高Tc; 例如CeFe10Si2N1.29具有Tc = 426℃

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