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公开(公告)号：US20230242284A1
公开(公告)日：2023-08-03
申请号：US17801701
申请日：2021-02-24
Applicant: GS Yuasa International Ltd.
Inventor： Hiromasa Muramatsu
Abstract: A method of controlling a flying object 1 including a generator 5, which includes solar cells, and an energy storage apparatus 7 is configured such in a case where, during flying of the flying object 1, a voltage of an energy storage device 6 in the energy storage apparatus 7 reaches a lower limit voltage of a voltage range in which charge and discharge of electricity can be reversibly repeated, the flying object 1 is made to keep flying and/or descend while making the energy storage device 6 discharge electricity within a voltage range lower than the lower limit voltage.
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2.发明申请POSITIVE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY, MANUFACTURING METHOD THEREOF, LITHIUM SECONDARY BATTERY ELECTRODE, AND LITHIUM SECONDARY BATTERY 审中-公开用于锂二次电池的正极活性材料，其制造方法，锂二次电池电极和锂二次电池公开(公告)号：US20140038053A1
公开(公告)日：2014-02-06
申请号：US13792372
申请日：2013-03-11
Applicant: GS YUASA INTERNATIONAL LTD.
Inventor： Daisuke Endo , Motonobu Murakami , Hiromasa Muramatsu
CPC classification number: H01M4/525 , C01G53/50 , C01P2006/11 , C01P2006/12 , C01P2006/14 , C01P2006/16 , H01M4/0471 , H01M4/505
Abstract: A positive active material for a lithium secondary battery contains a lithium-transition metal composite oxide represented by a composition formula of Li1+αMe1−αO2 (Me is a transition metal element including Co, Ni, and Mn; 1.2
Abstract translation: 锂二次电池用正极活性物质含有由Li1 +αMe1-αO2组成式表示的锂 - 过渡金属复合氧化物（Me是包括Co，Ni和Mn的过渡金属元素; 1.2（1 +α） /(1-alpha)<1.6）。 Me中所含的Co的摩尔比（Co / Me）为0.24〜0.36，当使用空间群R3-m作为基于X射线衍射图的晶体结构模型时，衍射的半值宽度 归属于（003）线的峰在0.204°至0.303°的范围内，或属于（104）线的衍射峰的半值宽度范围为0.278°至0.424°。
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3.发明申请公开(公告)号：US20130344387A1
公开(公告)日：2013-12-26
申请号：US13914907
申请日：2013-06-11
Applicant: GS YUASA INTERNATIONAL LTD.
Inventor： Daisuke Endo , Hiromasa Muramatsu
IPC: H01M4/48
CPC classification number: H01M4/131 , C01G53/006 , C01G53/50 , C01P2002/20 , C01P2002/76 , C01P2004/51 , C01P2004/61 , C01P2006/40 , H01M4/48 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2220/20 , Y02E60/122 , Y02P70/54 , Y02T10/7011
Abstract: Provided is a positive active material for a lithium secondary battery includes a lithium transition metal composite oxide having an α-NaFeO2-type crystal structure and represented by the composition formula of Li1+αMe1-αO2 (Me is a transition metal including Co, Ni and Mn and α>0). The positive active material contains Na in an amount of 900 ppm or more and 16000 ppm or less, or K in an amount of 1200 ppm or more and 18000 ppm or less.
Abstract translation: 提供的锂二次电池用正极活性物质包括具有α-NaFeO 2型晶体结构并由组成式Li1 +αMe1-αO2表示的锂过渡金属复合氧化物（Me是包括Co，Ni的过渡金属和 Mn和α> 0）。 正极活性物质含有900ppm以上且16000ppm以下的Na，或1200ppm以上至18000ppm以下的K。
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公开(公告)号：US10319998B2
公开(公告)日：2019-06-11
申请号：US15026429
申请日：2014-10-01
Applicant: GS Yuasa International Ltd.
Inventor： Daisuke Endo , Hiromasa Muramatsu
Abstract: A positive active material for a lithium secondary battery containing a lithium transition metal composite oxide having a hexagonal crystal structure in which the transition metal (Me) includes Ni, Co and Mn, wherein in the lithium transition metal composite oxide, a molar ratio of Ni to the transition metal (Me) (Ni/Me) is 0.5 or more and 0.9 or less, a molar ratio of Co to the transition metal (Me) (Co/Me) is 0.1 or more and 0.3 or less, a molar ratio of Mn to the transition metal (Me) (Mn/Me) is 0.03 or more and 0.3 or less, and a value obtained by dividing a half width ratio F(003)/F(104) at a potential of 4.3 V (vs. Li/Li+) by a half width ratio F(003)/F(104) at a potential of 2.0 V (vs. Li/Li+) is 0.9 or more and 1.1 or less.
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5.发明授权公开(公告)号：US09105924B2
公开(公告)日：2015-08-11
申请号：US13914907
申请日：2013-06-11
Applicant: GS YUASA INTERNATIONAL LTD.
Inventor： Daisuke Endo , Hiromasa Muramatsu
IPC: H01M4/505 , H01M4/48 , H01M4/525 , C01G53/00 , H01M10/052
CPC classification number: H01M4/131 , C01G53/006 , C01G53/50 , C01P2002/20 , C01P2002/76 , C01P2004/51 , C01P2004/61 , C01P2006/40 , H01M4/48 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2220/20 , Y02E60/122 , Y02P70/54 , Y02T10/7011
Abstract: Provided is a positive active material for a lithium secondary battery includes a lithium transition metal composite oxide having an α-NaFeO2-type crystal structure and represented by the composition formula of Li1+αMe1−αO2 (Me is a transition metal including Co, Ni and Mn and α>0). The positive active material contains Na in an amount of 900 ppm or more and 16000 ppm or less, or K in an amount of 1200 ppm or more and 18000 ppm or less.
Abstract translation: 本发明提供一种锂二次电池用正极活性物质，其具有由Li-1 +αMe1-αO2组成式表示的具有α-NaFeO 2型晶体结构的锂过渡金属复合氧化物（Me是包括Co，Ni的过渡金属和 Mn和α> 0）。 正极活性物质含有900ppm以上且16000ppm以下的Na，或1200ppm以上至18000ppm以下的K。
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Patent Agency Ranking
6.发明申请POSITIVE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY, METHOD FOR PRODUCTION THEREOF, ELECTRODE FOR LITHIUM SECONDARY BATTERY AND LITHIUM SECONDARY BATTERY 审中-公开用于锂二次电池的正极活性材料，其生产方法，锂二次电池和锂二次电池的电极公开(公告)号：US20140004423A1
公开(公告)日：2014-01-02
申请号：US13915025
申请日：2013-06-11
Applicant: GS Yuasa International Ltd.
Inventor： Daisuke Endo , Hiromasa Muramatsu
CPC classification number: H01M4/364 , C01D15/02 , C01G53/006 , C01G53/50 , C01P2004/61 , C01P2006/80 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2220/20 , Y02E60/122
Abstract: The positive active material for a lithium secondary battery includes a lithium transition metal composite oxide having an α-NaFeO2-type crystal structure and represented by the composition formula of Li1+αMe1−αO2 (Me is a transition metal including Co, Ni and Mn and α>0). The positive active material contains Na in an amount of no less than 1900 ppm and no more than 8000 ppm, and has a 50% particle size (D50) of 5 μm or less in particle size distribution measurement.
Abstract translation: 用于锂二次电池的正极活性材料包括具有α-NaFeO 2型晶体结构并由组成式Li1 +αMe1-αO2表示的锂过渡金属复合氧化物（Me是包括Co，Ni和Mn的过渡金属和 α> 0）。 正极活性物质的粒径分布测定中含有不低于1900ppm且不超过8000ppm的Na，并且具有5μm以下的50％的粒径（D50）。
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公开(公告)号：US11152616B2
公开(公告)日：2021-10-19
申请号：US16317348
申请日：2017-07-05
Applicant: GS Yuasa International Ltd.
Inventor： Daisuke Endo , Hiromasa Muramatsu
Abstract: To provide a hydroxide precursor having a high density, a method for producing a lithium transition metal composite oxide using the precursor, a positive active material having a large discharge capacity per unit volume, which uses the composite oxide, an electrode for nonaqueous electrolyte secondary battery, and a nonaqueous electrolyte secondary battery. A method for producing a transition metal hydroxide precursor for use in production of a lithium transition metal composite oxide, including adding a solution containing a transition metal (Me) into a reaction tank in which a water solvent of dissolution of a complexing agent and a reducing agent has been charged in advance to coprecipitate a transition metal hydroxide that includes Mn and Ni, or Mn, Ni and Co, and has a mole ratio Mn/Me of larger than 0.5 and a mole ratio Co/Me of 0.15 or less. Further, a lithium transition metal composite oxide having an α-NaFeO2-type crystal structure, in which a mole ratio Li/Me is larger than 1, the mole ratios of Mn and Co are as described above, and which has an X-ray diffraction pattern attributable to R3-m, a ratio (FWHM (003)/FWHM (114)) of a full width at half maximum of a diffraction peak of a (003) plane to a full width at half maximum of a diffraction peak of a (104) plane of 0.72 or less, and a peak differential pore volume of 0.50 mm3/(g·nm) or less as determined by a BJH method from an adsorption isotherm using a nitrogen gas adsorption method.
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公开(公告)号：US20210075012A1
公开(公告)日：2021-03-11
申请号：US16771499
申请日：2018-12-14
Applicant: GS Yuasa International Ltd.
Inventor： Hiromasa Muramatsu
IPC: H01M4/525 , H01M10/0525 , H01M4/505 , C01G53/00
Abstract: Disclosed is a positive active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide, in which the lithium transition metal composite oxide has an α-NaFeO2 structure, a molar ratio Li/Me of Li and a transition metal (Me) is 1
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公开(公告)号：US20160285093A1
公开(公告)日：2016-09-29
申请号：US15172762
申请日：2016-06-03
Applicant: GS Yuasa International Ltd.
Inventor： Daisuke ENDO , Hiromasa Muramatsu
IPC: H01M4/525 , H01M10/0525 , H01M4/505
CPC classification number: H01M4/131 , C01G53/006 , C01G53/50 , C01P2002/20 , C01P2002/76 , C01P2004/51 , C01P2004/61 , C01P2006/40 , H01M4/48 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2220/20 , Y02E60/122 , Y02P70/54 , Y02T10/7011
Abstract: Provided is a positive active material for a lithium secondary battery includes a lithium transition metal composite oxide having an α-NaFeO2-type crystal structure and represented by the composition formula of Li1+αMe1−αO2 (Me is a transition metal including Co, Ni and Mn and α>0). The positive active material contains Na in an amount of 900 ppm or more and 16000 ppm or less, or K in an amount of 1200 ppm or more and 18000 ppm or less.
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公开(公告)号：US20200381720A1
公开(公告)日：2020-12-03
申请号：US16771281
申请日：2018-12-14
Applicant: GS Yuasa International Ltd.
Inventor： Daisuke Endo , Hiromasa Muramatsu
Abstract: Disclosed is a positive active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide, in which the lithium transition metal composite oxide has an α-NaFeO2 structure, a molar ratio Li/Me of Li and a transition metal (Me) of 1.05≤Li/Me≤1.4, and a porosity of 5 to 15%.
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