公开(公告)号：US08030417B2

公开(公告)日：2011-10-04

申请号：US12523265

申请日：2008-01-23

申请人： Gaku Maruyama ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo ,  Shoji Koketsu

发明人： Gaku Maruyama ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo ,  Shoji Koketsu

IPC分类号： C08L69/00

CPC分类号： C08G63/916 ,  C08G63/64 ,  C08G64/18 ,  C08G81/00 ,  C08K3/013

摘要： The present invention is a process for producing a polyester-polycarbonate type thermoplastic polyester elastomer in which a hard segment consisting of a polyester constructed of aromatic dicarboxylic acid, and an aliphatic or alicyclic diol, and a soft segment consisting mainly of aliphatic polycarbonate are connected, comprising at least a step of increasing the molecular weight of an aliphatic polycarbonate diol by a reaction of an aliphatic polycarbonate diol and a chain extender, and a step of reacting aliphatic polycarbonate and a polyester constructed of aromatic dicarboxylic acid and an aliphatic or alicyclic diol in the molten state.

摘要翻译： 本发明是一种聚酯 - 聚碳酸酯型热塑性聚酯弹性体的制造方法，其中将由芳族二羧酸和脂肪族或脂环族二醇构成的聚酯构成的硬链段和主要由脂肪族聚碳酸酯组成的软链段连接， 至少包括通过脂肪族聚碳酸酯二醇和扩链剂的反应来提高脂肪族聚碳酸酯二醇的分子量的步骤，以及将脂肪族聚碳酸酯与由芳香族二羧酸和脂肪族或脂环族二醇构成的聚酯反应的工序 熔融状态。

公开(公告)号：US20090203871A1

公开(公告)日：2009-08-13

申请号：US12158231

申请日：2006-12-15

申请人： Gaku Maruyama ,  Shoji Koketsu ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo

发明人： Gaku Maruyama ,  Shoji Koketsu ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo

IPC分类号： C08G63/56

CPC分类号： C08G63/64 ,  C08G63/914

摘要： The present invention provides a thermoplastic polyester elastomer excellent in heat resistance, heat-aging resistance, water resistance, light resistance, low-temperature property and the like, and further excellent in block order-retaining ability, the thermoplastic polyester elastomer comprising a hard segment which comprises polyester constituted with aromatic dicarboxylic acid and aliphatic or alicyclic diol and a soft segment which comprises mainly aliphatic polycarbonate, wherein the hard segment and the soft segment being connected, and wherein when melting points of the thermoplastic polyester elastomer are obtained by measuring on a differential scanning calorimeter in three cycles in which a temperature is raised from room temperature to 300° C. at a heating rate of 20° C./min., maintained at 300° C. for 3 minutes and lowered to room temperature at a cooling rate of 100° C./min., a melting point difference (Tm1−Tm3) between a melting point obtained in the first cycle (Tm1) and a melting point obtained in the third cycle (Tm3) is 0-50° C., and a tensile strength at break is 15-100 MPa.

摘要翻译： 本发明提供一种耐热性，耐热老化性，耐水性，耐光性，低温性等优异的热塑性聚酯弹性体，并且具有优异的嵌段顺序保持能力，热塑性聚酯弹性体包含硬链段 其包含由芳族二羧酸和脂族或脂环族二醇构成的聚酯和主要包含脂肪族聚碳酸酯的软链段，其中所述硬链段和所述软链段连接，并且其中当所述热塑性聚酯弹性体的熔点通过 差示扫描量热计在三个循环中，其中温度以20℃/分钟的升温速度从室温升至300℃，保持在300℃3分钟，并在冷却下降至室温 速率为100℃/分钟，在第一周期获得的熔点（Tm）之间的熔点差（Tm1-Tm3） 1），在第3循环（Tm3）中得到的熔点为0〜50℃，断裂拉伸强度为15〜100MPa。

公开(公告)号：US07973124B2

公开(公告)日：2011-07-05

申请号：US12158231

申请日：2006-12-15

申请人： Gaku Maruyama ,  Shoji Koketsu ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo

发明人： Gaku Maruyama ,  Shoji Koketsu ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C08G63/64 ,  C08G63/914

摘要： The present invention provides a thermoplastic polyester elastomer excellent in heat resistance, heat-aging resistance, water resistance, light resistance, low-temperature property and the like, and further excellent in block order-retaining ability, the thermoplastic polyester elastomer comprising a hard segment which comprises polyester constituted with aromatic dicarboxylic acid and aliphatic or alicyclic diol and a soft segment which comprises mainly aliphatic polycarbonate, wherein the hard segment and the soft segment being connected, and wherein when melting points of the thermoplastic polyester elastomer are obtained by measuring on a differential scanning calorimeter in three cycles in which a temperature is raised from room temperature to 300° C. at a heating rate of 20° C./min., maintained at 300° C. for 3 minutes and lowered to room temperature at a cooling rate of 100° C./min., a melting point difference (Tm1−Tm3) between a melting point obtained in the first cycle (Tm1) and a melting point obtained in the third cycle (Tm3) is 0-50° C., and a tensile strength at break is 15-100 MPa.

摘要翻译： 本发明提供一种耐热性，耐热老化性，耐水性，耐光性，低温性等优异的热塑性聚酯弹性体，并且具有优异的嵌段顺序保持能力，热塑性聚酯弹性体包含硬链段 其包含由芳族二羧酸和脂族或脂环族二醇构成的聚酯和主要包含脂肪族聚碳酸酯的软链段，其中所述硬链段和所述软链段连接，并且其中当所述热塑性聚酯弹性体的熔点通过 差示扫描量热计在三个循环中，其中温度以20℃/分钟的升温速度从室温升至300℃，保持在300℃3分钟，并在冷却下降至室温 速度为100℃/分钟，在第一循环中获得的熔点之间的熔点差（Tm1-Tm3） Tm1），在第3次循环（Tm3）中得到的熔点为0〜50℃，断裂拉伸强度为15〜100MPa。

公开(公告)号：US20100041858A1

公开(公告)日：2010-02-18

申请号：US12523265

申请日：2009-01-23

申请人： Gaku Maruyama ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo ,  Shoji Koketsu

发明人： Gaku Maruyama ,  Kenta Susuki ,  Katsuaki Kuze ,  Shigeo Ukyo ,  Shoji Koketsu

IPC分类号： C08G63/52 ,  C08G63/64

CPC分类号： C08G63/916 ,  C08G63/64 ,  C08G64/18 ,  C08G81/00 ,  C08K3/013

摘要： The present invention is a process for producing a polyester-polycarbonate type thermoplastic polyester elastomer in which a hard segment consisting of a polyester constructed of aromatic dicarboxylic acid, and an aliphatic or alicyclic diol, and a soft segment consisting mainly of aliphatic polycarbonate are connected, comprising at least a step of increasing the molecular weight of an aliphatic polycarbonate diol by a reaction of an aliphatic polycarbonate diol and a chain extender, and a step of reacting aliphatic polycarbonate and a polyester constructed of aromatic dicarboxylic acid and an aliphatic or alicyclic diol in the molten state.

摘要翻译： 本发明是一种聚酯 - 聚碳酸酯型热塑性聚酯弹性体的制造方法，其中将由芳族二羧酸和脂肪族或脂环族二醇构成的聚酯构成的硬链段和主要由脂肪族聚碳酸酯组成的软链段连接， 至少包括通过脂肪族聚碳酸酯二醇和扩链剂的反应来提高脂肪族聚碳酸酯二醇的分子量的步骤，以及将脂肪族聚碳酸酯与由芳香族二羧酸和脂肪族或脂环族二醇构成的聚酯反应的工序 熔融状态。

公开(公告)号：US09752017B2

公开(公告)日：2017-09-05

申请号：US14346142

申请日：2011-09-21

申请人： Toshiki Shimizu ,  Shigenori Inata ,  Tomohiko Kurahashi ,  Junzo Matsuno ,  Tatsuya Endo ,  Shigeo Ukyo ,  Momoko Daitoku

发明人： Toshiki Shimizu ,  Shigenori Inata ,  Tomohiko Kurahashi ,  Junzo Matsuno ,  Tatsuya Endo ,  Shigeo Ukyo ,  Momoko Daitoku

IPC分类号： B60C1/00 ,  B60C5/14 ,  C08L15/00 ,  C08J5/18 ,  B29D30/06 ,  C08L67/02 ,  C08L67/00 ,  C08L21/00 ,  C08L69/00 ,  C08L23/08

CPC分类号： C08L15/00 ,  B29D30/0681 ,  B29D2030/0682 ,  B60C1/0008 ,  B60C5/14 ,  C08J5/18 ,  C08J2321/00 ,  C08J2367/02 ,  C08L21/00 ,  C08L23/0884 ,  C08L67/00 ,  C08L67/02 ,  C08L67/025 ,  C08L69/005

摘要： Provided is an air permeation resistant film in which flexibility can be imparted to the film without remarkably increasing the proportion of a rubber constituting a dispersed phase. An air permeation resistant film comprising (A) a thermoplastic polyester elastomer which comprises a block copolymer containing a polyester as a hard segment and has a melting point of from 180 to 230° C., and (B) a rubber, in a mass ratio (A)/(B) of from 90/10 to 40/60, wherein the component (A) and the component (B) are melt-kneaded to perform dynamic crosslink, thereby forming a continuous phase composed of the component (A) and a dispersed phase composed of the component (B), and the film has an air permeation coefficient at 80° C. of 5×1013 fm2/Pa·s or less and Young's modulus of 120 MPa or less.

公开(公告)号：US20140238570A1

公开(公告)日：2014-08-28

申请号：US14346142

申请日：2011-09-21

申请人： Toshiki Shimizu ,  Shigenori Inata ,  Tomohiko Kurahashi ,  Junzo Matsuno ,  Tatsuya Endo ,  Shigeo Ukyo ,  Momoko Daitoku

发明人： Toshiki Shimizu ,  Shigenori Inata ,  Tomohiko Kurahashi ,  Junzo Matsuno ,  Tatsuya Endo ,  Shigeo Ukyo ,  Momoko Daitoku

IPC分类号： C08L15/00 ,  B60C1/00 ,  B29D30/06 ,  C08L69/00

CPC分类号： C08L15/00 ,  B29D30/0681 ,  B29D2030/0682 ,  B60C1/0008 ,  B60C5/14 ,  C08J5/18 ,  C08J2321/00 ,  C08J2367/02 ,  C08L21/00 ,  C08L23/0884 ,  C08L67/00 ,  C08L67/02 ,  C08L67/025 ,  C08L69/005

摘要： Provided is an air permeation resistant film in which flexibility can be imparted to the film without remarkably increasing the proportion of a rubber constituting a dispersed phase. An air permeation resistant film comprising (A) a thermoplastic polyester elastomer which comprises a block copolymer containing a polyester as a hard segment and has a melting point of from 180 to 230° C., and (B) a rubber, in a mass ratio (A)/(B) of from 90/10 to 40/60, wherein the component (A) and the component (B) are melt-kneaded to perform dynamic crosslink, thereby forming a continuous phase composed of the component (A) and a dispersed phase composed of the component (B), and the film has an air permeation coefficient at 80° C. of 5×1013 fm2/Pa·s or less and Young's modulus of 120 MPa or less.

摘要翻译： 提供了一种防透气膜，其中可赋予膜的柔软性，而不显着增加构成分散相的橡胶的比例。 一种防透气膜，其包含（A）热塑性聚酯弹性体，其包含含有作为硬链段的聚酯的熔点为180-230℃的嵌段共聚物，和（B）以质量比计的橡胶 （A）/（B）为90/10〜40/60，其中将组分（A）和组分（B）熔融捏合以进行动态交联，从而形成由组分（A）组成的连续相， 和由组分（B）组成的分散相，并且该膜的80℃的透气系数为5×10 13 fm 2 / Pa·s以下，杨氏模量为120MPa以下。