摘要:
The present invention provides a grain-oriented silicon steel sheet excellent in adhesiveness to tension-creating insulating coating films formed on the grain-oriented silicon steel sheet produced by removing inorganic mineral films composed of forsterite and so on with pickling or the like or by deliberately preventing the formation thereof, characterized by: having, at the interface between each of the tension-creating insulating coating films and the steel sheet, an external oxidation type membranous oxide film of 2 to 500 nm in average thickness mainly composed of amorphous silica and/or a mixed oxide film consisting of an external oxidation type membranous oxide film of 2 to 500 nm in average thickness mainly composed of amorphous silica and particulate oxides mainly composed of amorphous silica: and satisfying any one or more of the specified requirements.
摘要:
In a method for manufacturing grain-oriented silicon steel with mirror-like surface by applying an aqueous slurry of an annealing separator, magnetic properties are stabilized by controlling the amount of moisture, carried in the annealing separator consisting mainly of alumina after application and drying thereof, to not more than 1.5%, controlling the partial water vapor pressure during finish-annealing and eliminating the variation (instability) in secondary recrystallization caused by the inhibitor reaction at the interface.
摘要:
The present invention, in a method to produce a grain-oriented electrical steel sheet, proposes conditions for stable production by clarifying the causes by which secondary recrystallization is rendered unstable when primary recrystallization is controlled by raising the heating rate of decarburization annealing. The primary recrystallization structure is controlled by changing the heating rate and the oxide layer of a steel sheet is controlled by changing the conditions of soaking annealing in the decarburization annealing. The composition of the (Al, Si)N inhibitor is also controlled in the nitriding treatment thereafter.
摘要:
In a method for manufacturing grain-oriented silicon steel with mirror-like surface by applying an aqueous slurry of an annealing separator, magnetic properties are stabilized by controlling the amount of moisture, carried in the annealing separator consisting mainly of alumina after application and drying thereof, to not more than 1.5%, controlling the partial water vapor pressure during finish-annealing and eliminating the variation (instability) in secondary recrystallization caused by the inhibitor reaction at the interface.
摘要:
The present invention provides a method for producing a grain-oriented silicon steel sheet not having inorganic mineral films by using an annealing separator capable of preventing the inorganic mineral films composed of forsterite (Mg2SiO4), and so on, from forming during final annealing, comprising the steps of decarburization annealing followed by coating of annealing separator and final annealing, wherein alumina powder calcined at a calcination temperature of 900 to 1,400° C., or further having a BET specific surface area of 1 to 100 m2/g, an oil absorption of 1 to 70 ml/100 g, and/or having a gamma ratio of 0.001 to 2.0, is used as the annealing separator. Magnesia having a BET specific surface area of 0.5 to 5 m2/g may be added to said alumina powder.
摘要:
Disclosed is a method for producing a grain-oriented electrical steel sheet having mirror surface containing 0.8 to 4.8% of Si in the form of a strip which has been subjected to a conventional series of operations including hot rolling with or without annealing, cold rolling once or at least twice with intermediate annealing to obtain a final thickness, decarburization annealing with or without nitriding treatment, coating the steel sheet with an annealing separator mainly containing non-hydrating oxide and final annealing, the improvement comprising:satisfying the relationship A!>0.2.times. O!where A! is the total concentration of alkali metal impurity in the annealing separator (weight %), and O! is the amount of oxygen contained in the steel sheet just prior to the final annealing (g/m.sup.2).
摘要翻译:公开了一种具有镜面的晶面取向电工钢板的制造方法,其具有含有带状的0.8〜4.8%的Si的方式,该钢带经过常规的一系列操作,包括或不进行退火的热轧,冷轧一次 或至少两次中间退火以获得最终厚度,或者不进行氮化处理的脱碳退火,用主要包含非水合氧化物和最终退火的退火分离器涂覆钢板,改进包括:满足关系[A]> 0.2×[O]其中[A]为退火分离剂中碱金属杂质的总浓度(重量%),[O]为最终退火前的钢板中所含的氧的量(g / m 2 )。
摘要:
Grain oriented silicon steel sheet on which is formed an insulating coating having a thickness that is not less than 2.5 .mu.m that imparts tension to the steel sheet which does not have an inorganic mineral layer formed during a final annealing step (glass film) and a method of forming on grain oriented silicon steel sheet an insulating coating that is not less than 2.5 .mu.m thick and which imparts tension to the steel sheet which does not have the inorganic mineral layer (glass film) that forms during finish annealing, and a method of forming a tensioning insulating coating on grain oriented silicon steel sheet which has been finish annealed and does not have an inorganic mineral surface layer (glass film), after first forming a layer of SiO.sub.2 not less than 0.001 .mu.m thick on the oriented silicon steel sheet.
摘要:
In order to provide a very low iron loss, it is necessary to render the surface of a steel sheet smooth (specular). In the present invention, this is effected in a finish annealing furnace to simultaneously attain a high magnetic flux density and a specular surface. Specifically, after the completion of decarburization annealing, a steel material is pickled to remove an oxide layer present on the surface of the steel sheet, coated with an annealing separator comprising a substance nonreactive or less reactive with SiO.sub.2 and then subjected to finish annealing to provide a grain oriented electrical steel sheet having a specular surface. Magnetic domain division and tension coating of the steel sheet can provide a low iron loss value. In the finish annealing, since no time is required for dehydration, the annealing time can be shortened.
摘要:
The present invention enables magnetic domain control by the method of forming a magnetic coating layer of an Ni—Fe alloy comprised of Fe: 10 to 50 mass % and Ni: 90 to 50 mass % on the surface of grain-oriented electrical steel sheet having mainly {110} orientation texture so that even if annealing after core formation, the iron loss improving effect will not be lost and the magnetic flux density will not be greatly reduced.
摘要:
A method of producing grain oriented silicon steel sheets each having a low watt loss, at an inexpensive cost and a high operational efficiency, wherein surfaces of each silicon steel sheet are given a mirror surface is disclosed. After completion of a finish annealing, forsterite films on the surface of each grain oriented silicon steel sheet are removed therefrom, and thereafter, the silicon steel sheet is annealed within the temperature range of 1000.degree. C. or higher in an atmosphere composed of a mixture gas comprising 20 to 80% by volume of hydrogen gas and 0 to 80% by volume of an inert gas, whereby surfaces of the silicon steel sheet are given a mirror surface. Subsequently, tensile stress additive films are formed on the surfaces of the silicon steel sheet, and consequently, the resultant silicon steel sheet exhibits a remarkably reduced watt loss.