公开(公告)号：US06402814B1

公开(公告)日：2002-06-11

申请号：US09679611

申请日：2000-10-05

申请人： Georges Kraus ,  Patrick Le Bot ,  Lian-Ming Sun

发明人： Georges Kraus ,  Patrick Le Bot ,  Lian-Ming Sun

IPC分类号： B01D5304

CPC分类号： F25J3/04181 ,  B01D53/0462 ,  B01D53/261 ,  B01D2253/104 ,  B01D2257/504 ,  B01D2257/80 ,  B01D2259/40015 ,  B01D2259/40052 ,  B01D2259/40066 ,  B01D2259/40081 ,  B01D2259/4009 ,  B01D2259/402 ,  B01D2259/416 ,  F25J3/04412 ,  F25J3/04775 ,  F25J2205/68 ,  F25J2205/72 ,  Y02C10/08

摘要： The regeneration phase of the adsorption cycle includes a depressurization step, a heating/elution step, during which the bed is purged with a hot heating/elution gas, and a cooling/elution step, during which the bed is purged with a cold cooling/elution gas. The cooling/elution step is terminated while the cooling/elution gas leaving the bed is at a temperature markedly higher than the temperature of the gas to be treated and the adsorption phase comprises an initial adsorption step during which the bed is cooled down to the low adsorption temperature due to the effect of the gas to be treated.

摘要翻译： 吸附循环的再生阶段包括减压步骤，加热/洗脱步骤，在此期间用热加热/洗脱气体吹扫床，以及冷却/洗脱步骤，在该步骤中用冷冷/ 洗脱气体。 冷却/洗脱步骤终止，而离开床的冷却/洗脱气体的温度显着高于待处理气体的温度，吸附阶段包括初始吸附步骤，在此阶段将床冷却至低 吸附温度由于待处理气体的影响。

公开(公告)号：US06240745B1

公开(公告)日：2001-06-05

申请号：US09503182

申请日：2000-02-14

申请人： Georges Kraus ,  Patrick Le Bot ,  Alain Guillard ,  Philippe Fraysse

发明人： Georges Kraus ,  Patrick Le Bot ,  Alain Guillard ,  Philippe Fraysse

IPC分类号： F25J300

CPC分类号： B01D53/0462 ,  B01D53/261 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/25 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2259/40001 ,  B01D2259/4009 ,  B01D2259/402 ,  B01D2259/416 ,  F25J3/04169 ,  F25J3/04412 ,  F25J2290/12 ,  Y02C10/08

摘要： A plant and a process for the purification and cryogenic separation of air containing impurities, which process is carried out according to the steps of (a) compressing the air; (b) introducing the air compressed in step (a) into one or more adsorption vessels containing particles of adsorbent without, beforehand, precooling the air; (c) adsorbing the impurities (CO2, H2O, NOx, SOx, etc) contained in the air on the particles of adsorbent at room temperature and at a pressure of at least 11.4 bar, preferably ranging from 20.1 to 40 bar; (d) cooling the air purified in step (c) down to a cryogenic temperature; and (e) cryogenically distilling the cooled air in order to produce nitrogen, oxygen, argon or mixtures thereof.

摘要翻译： 一种用于纯化和低温分离包含杂质的空气的设备和方法，该方法根据（a）压缩空气的步骤进行; （b）将预先将空气预冷却，将步骤（a）中压缩的空气引入含有吸附剂颗粒的一个或多个吸附容器中; （c）在室温和至少11.4巴，优选为20.1至40巴的压力下吸附空气中包含的杂质（CO 2，H 2 O，NO x，SO x等）于吸附剂颗粒上; （d）将步骤（c）中纯化的空气冷却至低温; 和（e）对冷却的空气进行低温蒸馏以产生氮气，氧气，氩气或其混合物。

公开(公告)号：US6129780A

公开(公告)日：2000-10-10

申请号：US258391

申请日：1999-02-26

申请人： Cyrille Millet ,  Philippe Bourgeois ,  Georges Kraus ,  Jean-Pierre Gabillard

发明人： Cyrille Millet ,  Philippe Bourgeois ,  Georges Kraus ,  Jean-Pierre Gabillard

IPC分类号： B01D53/04 ,  B01J8/00

CPC分类号： B01D53/0423 ,  B01J8/008 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2259/402 ,  B01D2259/4146 ,  B01D2259/416 ,  B01D53/0462 ,  B01D53/047 ,  Y02C10/08

摘要： Process and apparatus for the purification of a gaseous flow containing at least one impurity which can be carbon dioxide, water vapor and/or hydrocarbon. The impurity is adsorbed on a bed of adsorbent containing at least one adsorbent material, it being possible to use stacked adsorbent beds. Atop the uppermost bed is a layer of particulate ballast having a density greater than that of the adsorbent. The bed of ballast exerts a mechanical pressure on the subjacent adsorbent and prevents fluidization of the upper portion of the subjacent adsorbent. As a result, the rate of gas flow through the adsorbent can be increased.

摘要翻译： 用于净化含有至少一种可以是二氧化碳，水蒸汽和/或烃的杂质的气流的方法和装置。 杂质被吸附在含有至少一种吸附材料的吸附剂床上，可以使用堆叠的吸附剂床。 在最上层的顶部是一层密度大于吸附剂的颗粒状镇流器。 压载床对下层吸附剂施加机械压力，并防止下层吸附剂的上部流化。 结果，可以增加通过吸附剂的气体流量。

公开(公告)号：US6125655A

公开(公告)日：2000-10-03

申请号：US204220

申请日：1998-12-03

申请人： Cyrille Millet ,  Philippe Bourgeois ,  Georges Kraus ,  Jean-Pierre Gabillard

发明人： Cyrille Millet ,  Philippe Bourgeois ,  Georges Kraus ,  Jean-Pierre Gabillard

IPC分类号： B01D53/02 ,  B01D53/047 ,  B01J20/04 ,  B01J20/08 ,  B01J20/32 ,  F25J3/00

CPC分类号： B01J20/28004 ,  B01D53/02 ,  B01J20/041 ,  B01J20/08 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3483 ,  B01J20/3491 ,  B01D2253/104 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2256/24 ,  B01D2257/504 ,  B01D2257/80 ,  B01D2259/402 ,  B01D2259/416 ,  B01D53/0462 ,  B01D53/047 ,  B01J2220/58 ,  Y02C10/08

摘要： Process for purifying an air flow containing carbon dioxide (CO.sub.2) and water vapour, in which at least some of the CO.sub.2 and water vapour impurities are removed by adsorbing the impurities on at least one calcined alumina containing at most 10% by weight of at least one alkali or alkaline-earth metal oxide, the adsorption being carried out at a temperature of between -10.degree. C. and 80.degree. C.

摘要翻译： 用于净化含有二氧化碳（CO 2）和水蒸汽的空气流的方法，其中至少一些CO 2和水蒸气杂质通过将杂质吸附在至少一种煅烧氧化铝上，所述煅烧氧化铝至少含有10重量％ 一种碱金属或碱土金属氧化物，吸附在-10℃至80℃的温度下进行。

公开(公告)号：US06425937B1

公开(公告)日：2002-07-30

申请号：US09609370

申请日：2000-07-03

申请人： Georges Kraus ,  Cyrille Millet ,  Serge Moreau ,  Jean-Pierre Gabillard

发明人： Georges Kraus ,  Cyrille Millet ,  Serge Moreau ,  Jean-Pierre Gabillard

IPC分类号： B01D5304

CPC分类号： B01D53/0462 ,  B01D53/047 ,  B01D53/0476 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/30 ,  B01D2253/304 ,  B01D2253/308 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/7022 ,  B01D2257/80 ,  B01D2259/40064 ,  B01D2259/4009 ,  B01D2259/416 ,  B01J20/186 ,  Y02C10/08 ,  Y02C20/10 ,  Y10S95/902

摘要： A process for purifying a gas stream containing at least one impurity chosen from the group formed by propane, nitrogen protoxide and ethylene, in which process: (a) the gas stream to be purified is brought into contact with at least one adsorbent including at least one X zeolite containing barium cations; (b) at least one impurity is adsorbed on the adsorbent. Preferably, the adsorbent includes particles of X zeolite exchanged to at least 70%, preferably at least 89%, with barium cations, it being possible for the adsorbent to furthermore include a bed of activated alumina particles which is located upstream of the bed of barium-exchanged X zeolite.

摘要翻译： 一种净化含有选自由丙烷，氮氧化物和乙烯形成的基团中的至少一种杂质的气流的方法，其中将待纯化的气流与至少一种吸附剂接触，所述至少一种吸附剂至少包括 含有钡阳离子的X沸石;（b）至少一种杂质吸附在吸附剂上。 优选地，吸附剂包括与钡阳离子交换为至少70％，优选至少89％的X沸石的颗粒，吸附剂还可以包含位于钡床上游的活性氧化铝颗粒床 - 交换X沸石。

公开(公告)号：US06273939B1

公开(公告)日：2001-08-14

申请号：US09421224

申请日：1999-10-20

申请人： Cyrille Millet ,  Serge Moreau ,  Georges Kraus ,  Jean-Pierre Gabillard

发明人： Cyrille Millet ,  Serge Moreau ,  Georges Kraus ,  Jean-Pierre Gabillard

IPC分类号： B01D5304

CPC分类号： B01D53/02 ,  B01D2257/402 ,  Y02C10/08 ,  Y02C20/10 ,  Y02C20/20 ,  Y10S95/902

摘要： A process, particularly of the TSA type, for separating impurities of the nitrogen protoxide (N2O) and possibly carbon dioxide (CO2) or ethylene (C2H4) type which are contained in a gas stream, such as air. The impurities of nitrogen protoxide type are removed on a faujasite zeolite having a Si/Al ratio of 1 to 1.5 and containing from 0 to 35% of K+ cations, between 1 and 99% of Na+ cations and between 1 and 99% of Ca2+ cations, preferably at least 50% of Ca2+ cations. The separation is preferably carried out at a temperature of approximately −40° C. to +80° C., preferably at room temperature. Advantageously, the process is employed for prepurifying atmospheric air before cryogenic distillation of the air thus prepurified.

摘要翻译： 一种特别是TSA型的方法，用于分离包含在气流如空气中的氮氧化物（N 2 O）和可能的二氧化碳（CO 2）或乙烯（C 2 H 4）型的杂质。 在Si / Al比为1〜1.5，含有0〜35％的K +阳离子，1〜99％的Na +阳离子和1〜99％的Ca2 +阳离子的八面沸石上除去氮氧化物型杂质 ，优选至少50％的Ca 2+阳离子。 分离优选在约-40℃至+ 80℃的温度下进行，优选在室温下进行。 有利地，该方法用于在由此预净化的空气进行低温蒸馏之前对大气进行预净化。

公开(公告)号：US06270557B1

公开(公告)日：2001-08-07

申请号：US09221846

申请日：1998-12-29

申请人： Cyrille Millet ,  Philippe Bourgeois ,  Georges Kraus ,  Jean-Pierre Gabillard

发明人： Cyrille Millet ,  Philippe Bourgeois ,  Georges Kraus ,  Jean-Pierre Gabillard

IPC分类号： B01D5347

CPC分类号： B01J20/186 ,  B01D53/04 ,  B01D53/0462 ,  B01D53/047 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2259/416 ,  Y02C10/08 ,  Y10S95/902

摘要： Process for separating at least carbon dioxide (CO2) contained in a gas stream, preferably air, in which at least carbon dioxide is adsorbed on a zeolite-X having a Si/Al ratio of approximately 1 to 1.5 and containing at most 35% of K+ cations, between 1 and 99% of Na+ cations and at most 99% of Ca2+ cations. This process is carried out at a temperature ranging from −40° C. to +80° C. Optionally, impurities chosen from water vapour and hydrocarbons, particularly ethylene, are also removed. The air thus purified is then capable of being cryogenically distilled.

摘要翻译： 至少分离至少二氧化碳（CO2）的方法，其中至少二氧化碳吸附在Si / Al比约为1〜1.5的沸石-X上，最多含有35％ K +阳离子，1至99％的Na +阳离子和至多99％的Ca 2+阳离子。 该方法在-40℃至+ 80℃的温度范围内进行。也可以选择从水蒸汽和烃，特别是乙烯中选出的杂质。 然后如此纯化的空气能够被低温蒸馏。