Sulfamic acid halides and processes for the preparation of sulfamic acid
halides
    1.
    发明授权
    Sulfamic acid halides and processes for the preparation of sulfamic acid halides 失效
    氨基磺酰卤和用于制备氨基磺酰卤的方法

    公开(公告)号:US4327034A

    公开(公告)日:1982-04-27

    申请号:US51743

    申请日:1979-06-25

    CPC分类号: C07C311/54

    摘要: Sulfamic acid halides and processes for the preparation of sulfamic acid halides by reaction of monosubstituted sulfamic acid halides with halogen compounds in the presence of specific amounts of a basic compound and in the presence of an organic solvent, if desired with subsequent treatment with water at a pH of at most 7. The compounds obtainable by the process of the invention, some of which are new, are valuable starting materials for the preparation of crop protection agents, dyes and drugs.

    摘要翻译: 氨基磺酰卤和通过在特定量的碱性化合物的存在下,在有机溶剂的存在下,通过单取代的氨基磺酸卤化物与卤素化合物的反应来制备氨基磺酰卤的方法,如果需要,随后用水处理 pH最高为7.可通过本发明方法获得的化合物,其中一些是新的,是用于制备作物保护剂,染料和药物的有价值的起始原料。

    Silyl-benzimidazole-2-carbamic acid esters and their use as fungicides
    5.
    发明授权
    Silyl-benzimidazole-2-carbamic acid esters and their use as fungicides 失效
    苯甲基 - 苯并咪唑-2-氨基甲酸酯及其作为杀真菌剂的用途

    公开(公告)号:US4371525A

    公开(公告)日:1983-02-01

    申请号:US208034

    申请日:1980-11-18

    CPC分类号: C07D235/32 C07F7/10

    摘要: Silyl-benzimidazole-2-carbamic acid esters of the formula I ##STR1## where Y and Z are hydrogen or a silyl radical of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 independently of one another are unsubstituted or halogen-substituted alkyl, alkenyl or alkynyl of up to 12 carbon atoms, cycloalkyl of up to 7 carbon atoms which is unsubstituted or substituted by alkyl or alkynyl of up to 4 carbon atoms, or phenyl which is unsubstituted or substituted by halogen or alkyl of up to 4 carbon atoms, and R is alkyl of up to 4 carbon atoms, with the proviso that Y and Z are not both hydrogen, and their use as fungicides.The new active ingredients are particularly suitable for combating harmful phycomycetes, ascomycetes and fungi imperfecti.

    摘要翻译: 其中Y和Z是氢的式I(I)的甲硅烷基 - 苯并咪唑-2-氨基甲酸酯,或其中R 1,R 2和R 3彼此独立地是未取代的或卤素取代的式 具有至多12个碳原子的取代的烷基,烯基或炔基,未被取代或被至多4个碳原子的烷基或炔基取代的至多7个碳原子的环烷基,或未被取代或被卤素或烷基取代的苯基,直至 4个碳原子,R为至多4个碳原子的烷基,条件是Y和Z不同时为氢,也可用作杀真菌剂。 新的活性成分特别适用于防治有害的菌纲,子囊菌和真菌。

    Preparation of chlorinated phenoxyalkanoic acids
    6.
    发明授权
    Preparation of chlorinated phenoxyalkanoic acids 失效
    氯化苯氧烷酸的制备

    公开(公告)号:US4515985A

    公开(公告)日:1985-05-07

    申请号:US331457

    申请日:1981-12-16

    CPC分类号: C07C51/363 C07C51/367

    摘要: A process for the preparation of 2,4-dichloro- or 2-methyl-4-chlorophenoxyacetic acid or .alpha.-2,4-dichloro- or .alpha.-2-methyl-4-chlorophenoxypropionic acid by reacting phenoxyacetic or 2-methylphenoxyacetic acid or .alpha.-phenoxypropionic or .alpha.-2-methylphenoxypropionic acid with chlorine in water, wherein phenoxyacetic acid or phenoxypropionic acid is precipitated from an aqueous solution thereof, chlorine gas is passed into the resulting suspension of phenoxyacetic or 2-methylphenoxyacetic acid or .alpha.-phenoxypropionic or .alpha.-2-methylphenoxypropionic acid in water at from 30.degree. to 70.degree. C. at a rate not exceeding the rate at which it is consumed in the suspension, until from 100 to 110% of the theoretically required amount of chlorine gas has been taken up by the suspension, and the 2,4-dichloro- or 2-methyl-4-chloro-phenoxyacetic acid or .alpha.-2,4-dichloro- or .alpha.-2-methyl-4-chloro-phenoxypropionic acid is isolated from the suspension.

    摘要翻译: 一种通过使苯氧基乙酸或2-甲基苯氧基乙酸反应制备2,4-二氯或2-甲基-4-氯苯氧基乙酸或α-2,4-二氯或α-甲基-4-氯苯氧基丙酸的方法或 α-苯氧基丙酸或α-2-甲基苯氧基丙酸与氯在水中的反应,其中苯氧基乙酸或苯氧基丙酸从其水溶液中沉淀出来,将氯气送入得到的苯氧基乙酸或2-甲基苯氧基乙酸或α-苯氧基丙酸或α- -2-甲基苯氧基丙酸在30至70℃的水中,其速率不超过其在悬浮液中消耗的速率,直到理论上所需量的氯气的100至110%被吸收 通过悬浮液,从悬浮液中分离出2,4-二氯或2-甲基-4-氯 - 苯氧基乙酸或α-2,4-二氯或α-甲基-4-氯 - 苯氧基丙酸 。

    Production of 2,1,3-benzothiadiazin-4-one-2,2-dioxides
    7.
    发明授权
    Production of 2,1,3-benzothiadiazin-4-one-2,2-dioxides 失效
    制备2,1,3-苯并噻二嗪-4-酮-2,2-二氧化物

    公开(公告)号:US3935201A

    公开(公告)日:1976-01-27

    申请号:US522630

    申请日:1974-11-11

    IPC分类号: C07D285/14 C07D285/16

    CPC分类号: C07D285/16

    摘要: 2,1,3-Benzothiadiazin-4-one-2,2-dioxides are produced by the reaction of esters of anthranilic acid with a sulfamic acid halide in the presence of a solvent and a base at a temperature of from 20.degree. to 100.degree.C. The products are starting materials for the production of dyes and plant protection agents.

    摘要翻译: 2,1,3-苯并噻二嗪-4-酮-2,2-二氧化物是通过在溶剂和碱的存在下,在20〜100℃的温度下,邻氨基苯甲酸的酯与氨基磺酰卤反应制备的 DEG。该产品是用于生产染料和植物保护剂的起始原料。