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公开(公告)号：US4146684A
公开(公告)日：1979-03-27
申请号：US817491
申请日：1977-07-20
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： An electrochemical storage cell or battery based on an alkali metal and sulfur having at least one anode chamber and at least one cathode chamber separated from each other by an ion-conducting solid electrolyte, and felt with course-pores and/or low electric conductivity and felt with fine-pores and/or higher electric conductivity located in the cathode chamber, with the felt of coarse-pores and/or low conductivity disposed near the solid electrolyte and the felt of fine-pores and/or higher conductivity disposed further away from the solid electrolyte. This permits rapid and more complete recharging of the cell for covering peak loads in electrical networks.
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公开(公告)号：US4184013A
公开(公告)日：1980-01-15
申请号：US972285
申请日：1978-12-22
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： An electrochemical storage cell or battery with at least one anode filled with a molten alkali metal as the anolyte and at least one cathode chamber filled with a sulfur-containing catholyte substance with the anode chamber and the cathode chamber separated from each other by an alkali-ion-conducting solid electrolyte. To the catholyte substance is added an additive which converts the sulfur chains into an electrically charged state for obtaining electromigration of the sulfur phase. This induces mobilization of the sulfur phase in the cathode chamber and prevents major accumulation of liquid sulfur as an insulator. As a result the cell can be repeatedly recharged with large currents to a greater capacity. Additives are a dienophilic compound or a reaction product of a dienophilic compound and sulfur.
摘要翻译： 一种具有填充有作为阳极电解液的熔融碱金属的至少一个阳极和填充有含硫阴极电解质物质的至少一个阴极室的电化学蓄电池或电池，阳极室和阴极室通过碱 - 离子导电固体电解质。 向阴极电解质物质中加入一种将硫链转化为带电状态以获得硫相的电迁移的添加剂。 这导致硫相在阴极室中的动员并且防止液体硫作为绝缘体的主要积聚。 结果，电池可以用大电流反复充电到更大的容量。 添加剂是二亲性化合物或二亲性化合物和硫的反应产物。
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公开(公告)号：US4127705A
公开(公告)日：1978-11-28
申请号：US817379
申请日：1977-07-20
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： An electrochemical storage cell or battery based on an alkali metal and sulfur having at least one anode chamber and at least one cathode chamber separated from each other by an ion-conducting solid electrolyte, a felt fabric with capillary activity located in the cathode chamber, and an additive lowering the viscosity of the sulfur in the cathode chamber. Preferred additives are selenium, boron and iodine. Lowering the viscosity of the sulfur permits recharging the cell to a greater capacity.
摘要翻译： 一种基于碱金属和硫的电化学存储单元或电池，具有至少一个阳极室和至少一个阴离子室，所述至少一个阴极室由离子传导固体电解质彼此分开，毛细管活性位于阴极室中的毛毡织物，以及 降低阴极室中硫的粘度的添加剂。 优选的添加剂是硒，硼和碘。 降低硫的粘度允许将电池充电到更大的容量。
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公开(公告)号：US4029857A
公开(公告)日：1977-06-14
申请号：US638174
申请日：1975-12-05
CPC分类号： H01M10/3909
摘要： Electrochemical storage cell or battery based on sodium and sulfur having an anode chamber and a cathode chamber separated from each other by a dividing wall capable of conducting sodium ions, is provided with a screening electrode disposed in the chamber containing sulfur as a reactant between the dividing wall and the outer cell wall of said chamber to electrically screen the cell wall and thereby minimize corrosion of the cell wall.
摘要翻译： 具有通过能够进行钠离子的分隔壁彼此隔开的阳极室和阴极室的基于钠和硫的电化学储存电池或电池设置有设置在室内的屏蔽电极，其中含有作为反应物的硫分隔 壁和所述室的外细胞壁以电屏蔽细胞壁，从而使细胞壁的腐蚀最小化。
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公开(公告)号：US4018969A
公开(公告)日：1977-04-19
申请号：US670864
申请日：1976-03-26
CPC分类号： H01M10/3909 , H01M10/3954
摘要： An electrochemical storage cell or battery based on alkali metal and sulfur with at least one anode chamber containing alkali metal and one cathode chamber containing sulfur-alkali compounds separated from each other by an ion-conducting solid electrolyte wherein the sulfur-alkali compounds are at least partially dissolved in an organic liquid solvent with a boiling point above the operating temperature of the cell, the operating temperature being in the range of about 100.degree. to 200 C. The solvent permits lower operating temperature with reduced rate of corrosion.
摘要翻译： 一种基于碱金属和硫的电化学蓄电池或电池，其中至少一个阳极室含有碱金属和一个阴离子室，其中含有通过离子导电固体电解质彼此分离的硫碱化合物，其中硫 - 碱化合物至少 部分溶解在沸点高于电池工作温度的有机液体溶剂中，操作温度在约100℃至200℃的范围内。溶剂允许较低的操作温度和较低的腐蚀速率。
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6.发明授权Process for preparing polyacetylenes and substituted polyacetylenes produced thereby 失效由此制备聚乙炔和取代的聚乙炔的方法
公开(公告)号：US4444970A
公开(公告)日：1984-04-24
申请号：US413165
申请日：1982-08-30
申请人： Gert Weddigen
发明人： Gert Weddigen
IPC分类号： C08F4/22 , C08F238/02
CPC分类号： C08F238/02
摘要： Substituted polyacetylenes are prepared by contacting a mixture of acetylene and a substituted acetylene with a polymerization catalyst. The substituents on the polyacetylene chains increase the distance between neighboring parallel chains and shield the chains from attack by oxygen, thereby preventing crosslinking of the chains.
摘要翻译： 取代的聚乙炔通过使乙炔和取代乙炔的混合物与聚合催化剂接触来制备。 聚乙炔链上的取代基增加相邻平行链之间的距离，并且屏蔽链免受氧的侵蚀，从而防止链的交联。
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7.发明授权
公开(公告)号：US4221848A
公开(公告)日：1980-09-09
申请号：US853842
申请日：1977-11-22
申请人： Gert Weddigen
发明人： Gert Weddigen
CPC分类号： H01M4/36 , H01M10/3909 , H01M10/3954
摘要： An electrochemical storage cell or battery with at least one anode filled with a molten alkali metal as the anolyte and at least one cathode chamber filled with a sulfur-containing catholyte substance with the anode chamber and the cathode chamber separated from each other by an alkali-ion-conducting solid electrolyte. To the catholyte substance in the cathode chamber is added a chemical compound of the polar bond type which can charge the sulfur positively while absorbing electrons. This induces mobilization of the sulfur phase in the cathode chamber and prevents major accumulation of liquid sulfur as an insulator. As a result the cell can be repeatedly recharged with large currents to a greater capacity.
摘要翻译： 一种具有填充有作为阳极电解液的熔融碱金属的至少一个阳极和填充有含硫阴极电解质物质的至少一个阴极室的电化学蓄电池或电池，阳极室和阴极室通过碱 - 离子导电固体电解质。 向阴极室中的阴极电解质物质添加极性键型化合物，其可以在吸收电子的同时对硫进行正电荷充电。 这导致硫相在阴极室中的动员并且防止液体硫作为绝缘体的主要积聚。 结果，电池可以用大电流反复充电到更大的容量。
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公开(公告)号：US5492661A
公开(公告)日：1996-02-20
申请号：US358772
申请日：1994-12-19
申请人： Gert Weddigen , Paul Szasz , Axel Kranzmann
发明人： Gert Weddigen , Paul Szasz , Axel Kranzmann
CPC分类号： C04B28/26 , C04B26/14 , H01B19/00 , H01F41/005 , C04B2111/00844 , Y10T428/259
摘要： A process for producing a casting ceramic including water glass and a powder containing silicon and aluminum, includes mixing epoxy resin based on bisphenol-A into a casting ceramic to reduce open porosity. The casting ceramic is subsequently subjected to at least one heat treatment.
摘要翻译： 包括水玻璃和含硅和铝的粉末的铸造陶瓷的制造方法包括将基于双酚A的环氧树脂混合到铸造陶瓷中以降低开孔率。 随后对铸造陶瓷进行至少一次热处理。
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公开(公告)号：US4388381A
公开(公告)日：1983-06-14
申请号：US286452
申请日：1981-07-24
申请人： Stefan Mennicke , Gert Weddigen
发明人： Stefan Mennicke , Gert Weddigen
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： Electrochemical storage cell or battery of the alkali metal and chalcogen type with at least one anode space intended for receiving the anolyte and a cathode space for receiving the catholyte. The spaces are separated from each other by an alkali-ion-conducting solid electrolyte wall, and sulfur or sulfides are filled into the cathode space. The cathode space is filled with two or more porous layers of which always at least one is ion-conducting and one is electron-conducting. At least one ion-conducting layer rests at least in regions against the solid electrolyte, and at least one electron-conducting layer rests at least in some areas against the metallic housing of the storage cell. An electron-conducting layer is adjacent to each ion-conducting layer and vice versa. At least the electron-conducting layer is impregnated with sulfur.
摘要翻译： 具有用于接收阳极电解液的至少一个阳极空间和用于接收阴极电解液的阴极空间的碱金属和硫属类型的电化学存储电池或电池。 空间通过碱离子传导固体电解质壁彼此分离，硫或硫化物填充到阴极空间中。 阴极空间填充有两个或多个多孔层，其中至少一个是离子传导的，一个是导电的。 至少一个离子传导层至少在抵靠固体电解质的区域中搁置，并且至少一个电子传导层至少在一些区域中抵靠存储单元的金属外壳。 电子传导层与每个离子传导层相邻，反之亦然。 至少电子传导层用硫浸渍。
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公开(公告)号：US4691082A
公开(公告)日：1987-09-01
申请号：US839070
申请日：1986-03-13
申请人： Josef Flatz , Gert Weddigen , Hans-Joachim Bohme , Fritz Grieser , Robert Huber , Hans Nienburg
发明人： Josef Flatz , Gert Weddigen , Hans-Joachim Bohme , Fritz Grieser , Robert Huber , Hans Nienburg
摘要： Plastic cable with at least one electric conductor which is surrounded by a cable covering which, besides an insulating layer comprises several electrically conducting layers of a polymer material. At least one electrically conducting layer is made of a polymer, a mixed polymerizate or a polymer alloy which is meltable and/or soluble, and the electric conductivity of which can be adjusted to a defined value by a content of charge transfer complexes.
摘要翻译： 具有至少一个电导体的塑料电缆，其被电缆覆盖物覆盖，除了绝缘层包括多个聚合物材料的导电层之外， 至少一个导电层由可熔融和/或可溶的聚合物，混合聚合物或聚合物合金制成，其电导率可以通过电荷转移络合物的含量调节到规定的值。
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