摘要:
A method for the preparation of a desired molecular weight polysuccinimide by the catalytic polymerization of aspartic acid in the presence of a cyclic carbonate solvent. Polysuccinimide of relatively high weight average molecular weight and high purity can be produced in relatively high yields while employing a relatively low catalyst loading.
摘要:
A method for the preparation of a desired molecular weight polysuccinimide by the catalytic polymerization of aspartic acid in the presence of a cyclic carbonate solvent. Polysuccinimide of relatively high weight average molecular weight and high purity can be produced in relatively high yields while employing a relatively low catalyst loading.
摘要:
A method for the preparation of a succinimide copolymer by the catalytic co-polymerization of aspartic acid with a selected polyfunctional monomer in the presence of a cyclic carbonate solvent. Succinimide copolymers of relatively high weight average molecular weight and high purity can be produced in relatively high yields while employing a relatively low catalyst loading.
摘要:
A method for the preparation of a succinimide copolymer by the catalytic co-polymerization of aspartic acid with a selected polyfunctional monomer in the presence of a cyclic carbonate solvent. Succinimide copolymers of relatively high weight average molecular weight and high purity can be produced in relatively high yields while employing a relatively low catalyst loading.
摘要:
A method for the preparation of a succinimide copolymer by the catalytic co-polymerization of aspartic acid with a selected polyfunctional monomer in the presence of a cyclic carbonate solvent. Succinimide copolymers of relatively high weight average molecular weight and high purity can be produced in relatively high yields while employing a relatively low catalyst loading.
摘要:
Polysuccinimide of varying molecular weight has been prepared by heat polymerization of aspartic acid in the presence of a sulfur-containing dehydrating agent employing a variety of reaction mixtures and reaction conditions. Sulfur trioxide and heat decomposable sulfur trioxide precursor dehydrating agents are preferred for this purpose. The presence of an acid scavenger within the reaction mixture is desirable and leads to a relatively higher molecular weight polysuccinimide, while the absence of an acid scavenger results in a relatively lower molecular weight polysuccinimide.
摘要:
Aspartic acid precursors such as mono and diammonium maleate, maleamic acid, ammonium maleamate, ammonium malate and mixtures of these and other precursors are copolycondensed thermally with a variety of mono, di and multifunctional monomers containing amino, hydroxyl and carboxyl functional groups. The resulting condensation copolymers and terpolymers contain succinimide units derived from aspartic acid precursors, condensed with other functional group monomers usually though amide and ester linkages. Hydrolysis of the polysuccinimide copolymers and terpolymers with alkali, alkaline earth and ammonium hydroxide produces aspartic acid copolymer and terpolymer salts.
摘要:
Aspartic acid precursors such as mono and diammonium maleate, maleamic acid, ammonium maleamate, ammonium malate and mixtures of these and other precursors are copolycondensed thermally with a variety of mono, di and multifunctional monomers containing amino, hydroxyl and carboxyl functional groups. The resulting condensation copolymers and terpolymers contain succinimide units derived from aspartic acid precursors, condensed with other functional group monomers usually .�.though.!. .Iadd.through .Iaddend.amide and ester linkages. Hydrolysis of the polysuccinimide copolymers and terpolymers with alkali, alkaline earth and ammonium hydroxide produces aspartic acid copolymer and terpolymer salts.
摘要:
A phosphinate containing composition which has as its major ingredient more than 32 mole percent of a phosphinicosuccinic acid oligomer having the probable structural formula: ##STR1## M is H, Na, K, NH.sub.4, or mixtures thereof; and m and n are either 0 or a small whole number with the proviso that either m or n is a small whole number and the sum of m plus n is greater than 2.
摘要:
A squeeze treatment for preventing scale utilizes as the scale inhibitor a predominantly phosphinate containing composition comprising:______________________________________ Mole Percent - Ingredients Less Than ______________________________________ A. Monosodium phosphinicobis - 22 (succinic acid) B. Monosodium phosphinico- 26 succinic acid C. Sodium phosphonosuccinic acid 12 D. Sodium phosphate 5 E. Sodium phosphite 6 F. Sodium hypophosphite, and 6 G. A phosphinicosuccinic acid oligomer having the probable structural formula: ##STR1## ______________________________________ wherein G exceeds 25 mole percent, M is H, Na, K, NH.sub.4, amine salts and mixtures thereof and m and n are either 0 or a small whole number with the proviso that either m or n is a small whole number and the sum of m plus n is greater than 2.