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    Pentaaryldiamine-containing bismaleimide compound and method of producing the compound
    3.
    发明授权
    Pentaaryldiamine-containing bismaleimide compound and method of producing the compound 有权
    含有五芳基二胺的双马来酰亚胺化合物及其制备方法

    公开(公告)号：US08088932B2

    公开(公告)日：2012-01-03

    申请号：US12427077

    申请日：2009-04-21

    申请人： Guey-Sheng Liou ,  Cha-Wen Chang ,  Hung-Ju Yen ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Jung-Mu Hsu

    发明人： Guey-Sheng Liou ,  Cha-Wen Chang ,  Hung-Ju Yen ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Jung-Mu Hsu

    IPC分类号： C07D207/452

    CPC分类号： C07D207/452 ,  H05K1/0346 ,  H05K3/386

    摘要： Provided is a pentaaryldiamine-containing bismaleimide compound of Formula (I): wherein Ar1 to Ar5 are independently C6-C12 aryl; and Ar4 and Ar5 are optionally substituted by one or more substitutent(s) selected from the group consisting of C1-C6 alkyl, C1-C6 alkoxy, and cyano. The compound of Formula (I) is obtained by a method including the steps of reacting a diamine with maleic anhydride in a solvent to form an amic acid, and cyclodehydrating the amic acid in the presence of a catalyst and a dehydrating agent. The compound of Formula (I) has a nonlinear and asymmetric structure, is amorphous, and is readily soluble in a variety of organic solvents so that the toughness of the product made there from can be improved and processing of the compound can be simplified.

    摘要翻译： 本发明提供式（I）的含五芳基二胺的双马来酰亚胺化合物：其中Ar 1至Ar 5独立地为C 6 -C 12芳基; 并且Ar 4和Ar 5任选被一个或多个选自C 1 -C 6烷基，C 1 -C 6烷氧基和氰基的取代基取代。 通过包括以下步骤的方法获得式（I）化合物：在溶剂中使二胺与马来酸酐反应形成酰胺酸，并在催化剂和脱水剂的存在下将酰胺酸化。 式（I）的化合物具有非线性和不对称结构，是无定形的，并且易溶于各种有机溶剂，从而可以改善制备的产品的韧性，并且可以简化化合物的加工。

    Organic soluble wholly aromatic polyamides and preparation of the same
    4.
    发明授权
    Organic soluble wholly aromatic polyamides and preparation of the same 失效
    有机可溶性全芳族聚酰胺及其制备方法

    公开(公告)号：US5856572A

    公开(公告)日：1999-01-05

    申请号：US696522

    申请日：1996-08-14

    申请人： Guey-Sheng Liou ,  Sheng-Huei Hsiao ,  Jen-Chang Yang

    发明人： Guey-Sheng Liou ,  Sheng-Huei Hsiao ,  Jen-Chang Yang

    IPC分类号： C08G69/32 ,  C07C237/52

    CPC分类号： C08G69/32

    摘要： Disclosed is a wholly aromatic polyamide prepared by reacting 1,4-naphthyl or 2,6-naphthyl containing diacids with aromatic diamines. The polymers of the invention are readily soluble in a variety of organic solvents including DMAc, NMP and pyridine, and have good thermal stability. Transparent, tough and flexible films of these polymers can be cast from the solutions thereof and these polyamides are easily processable high-performance polymer materials.

    摘要翻译： 公开了通过使1,4-萘基或2,6-萘基的二酸与芳族二胺反应制得的全芳族聚酰胺。 本发明的聚合物易溶于包括DMAc，NMP和吡啶在内的各种有机溶剂，具有良好的热稳定性。 这些聚合物的透明，坚韧和柔韧的膜可以从其溶液中浇铸，并且这些聚酰胺易于加工的高性能聚合物材料。

    Naphthyl and ether chain-containing carboxyl derivatives
    6.
    发明授权
    Naphthyl and ether chain-containing carboxyl derivatives 失效
    含萘基和醚链的羧基衍生物

    公开(公告)号：US5712409A

    公开(公告)日：1998-01-27

    申请号：US702388

    申请日：1996-08-14

    申请人： Guey-Sheng Liou ,  Sheng-Huei Hsiao ,  Jen-Chang Yang

    发明人： Guey-Sheng Liou ,  Sheng-Huei Hsiao ,  Jen-Chang Yang

    IPC分类号： C07C51/08 ,  C07C65/24 ,  C07C69/773 ,  C07C69/92 ,  C07C51/60 ,  C07C63/22 ,  C07C63/38

    CPC分类号： C07C69/92 ,  C07C51/08 ,  C07C65/24

    摘要： New aromatic dicarboxylic acids, 1,4- or 2,6-Bis(p-carboxyphenoxy)naphthyl is prepared by the reaction of p-fluorobenzonitrile with 1,4-naphthalenediol, followed by hydrolysis. Wholly aromatic polyamides having superior solubility in a variety of organic solvents and have good thermal stability can be obtained by reacting the new aromatic dicarboxylic acids with aromatic diamines. Transparent, tough and flexible films of these polyamides can be cast from the solutions thereof and these polyamides are easily processable high-performance polymer materials.

    摘要翻译： 新的芳族二羧酸，1,4-或2,6-双（对羧基苯氧基）萘基是通过对氟苄腈与1,4-萘二醇的反应制备的，然后水解。 通过使新的芳族二羧酸与芳族二胺反应，可以获得在各种有机溶剂中具有优异溶解性并具有良好热稳定性的全芳族聚酰胺。 这些聚酰胺的透明，坚韧和柔韧的膜可以从其溶液中浇铸，并且这些聚酰胺易于加工的高性能聚合物材料。