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1.发明授权公开(公告)号：US08460497B2
公开(公告)日：2013-06-11
申请号：US12799984
申请日：2010-05-06
IPC分类号： B29C51/14
CPC分类号： B29C51/14 , C08G18/10 , C08G18/5015 , C08G63/682 , C08G63/6824 , C08G65/18 , C08G65/226 , C08J3/244 , C08J7/047 , C08J2367/00 , C08J2467/00 , C08L61/20 , C08L67/00 , C09D167/00 , Y10T156/1028 , Y10T428/31786 , C08G18/46 , C08L2666/14 , C08L2666/16
摘要： A coating composition is based on a polyester mixed with an alkyl-etherified melamine formaldehyde. The coating composition is partially cured in a first stage to provide a thermoformable partially cured, tack-free, non-blocking, coating layer, followed by application to generally a contoured substrate and thermoforming to conform thereto. The contoured partially cured coating layer is then heat cured to form a cured coating. A hydroxyl-terminated polyoxetane containing repeat units derived from oxetane monomers having one or two pendent —CH2—O—(CH2)n—Rf groups, wherein Rf is partially or fully fluorinated, can be esterified with polyester-forming reactants to form a fluorinated polyoxetane-modified polyester.
摘要翻译： 涂料组合物基于与烷基醚化的三聚氰胺甲醛混合的聚酯。 涂料组合物在第一阶段中部分固化，以提供可热成型的部分固化的，无粘性的，非阻塞的涂层，然后通常用于轮廓基材和热成型以符合其。 然后将轮廓部分固化的涂层热固化以形成固化涂层。 含有衍生自具有一个或两个侧基-CH 2 -O-（CH 2）n -R f基团的氧杂环丁烷单体的重复单元的羟基封端的聚氧杂环丁烷，其中Rf部分或完全氟化，可以与形成聚酯的反应物酯化以形成氟化 聚氧乙烯改性聚酯。
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2.发明授权公开(公告)号：US06465565B1
公开(公告)日：2002-10-15
申请号：US09610743
申请日：2000-07-06
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/3812 , C08G18/4607 , Y10T428/31551 , C08G18/3228
摘要： Anionic waterborne polyurethane dispersions are formed in the presence of polyfluorooxetane oligomers, polymers, or copolymers so that the polyfluorooxetanes are incorporated in the polyurethane. Coatings made from such polyurethanes have good low temperature flexibility, good chemical resistance and abrasion resistance, as well as a low coefficient of friction. Alternatively, the anionic water borne polyurethane dispersion can be blended with vinyl ester monomers such as various acrylates and subsequently polymerized by radiation, for example ultraviolet light, to form a comingled blend of at least two different types of polymers.
摘要翻译： 聚氟乙烯低聚物，聚合物或共聚物的存在下形成阴离子水性聚氨酯分散体，使聚氟氧杂环丁烷并入聚氨酯中。 由这种聚氨酯制成的涂料具有良好的低温柔韧性，良好的耐化学性和耐磨性，以及较低的摩擦系数。 或者，阴离子水性聚氨酯分散体可与乙烯基酯单体如各种丙烯酸酯共混，随后通过辐射例如紫外光聚合，形成至少两种不同类型的聚合物的混合物。
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3.发明授权Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coating containing the same 有权一元多氟氧杂环丁烷低聚物，聚合物和共聚物以及含有它们的涂层公开(公告)号：US06927276B2
公开(公告)日：2005-08-09
申请号：US10316412
申请日：2002-12-11
申请人： Robert Medsker , Gary L. Jialanella , Raymond J. Weinert , Guillermina C. Garcia , Aslam Malik , Roland Carlson
发明人： Robert Medsker , Gary L. Jialanella , Raymond J. Weinert , Guillermina C. Garcia , Aslam Malik , Roland Carlson
IPC分类号： C08G18/50 , C08G18/67 , C08G65/22 , C09D175/16
CPC分类号： C09D175/16 , C08G18/5015 , C08G18/672 , C08G65/226 , C08G18/50
摘要： Monofunctional polyfluorooxetane oligomers, polymers, and copolymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.
摘要翻译： 单官能聚氟乙烯低聚物，聚合物和共聚物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 除了作为引发剂外，一元醇还可以用作氟氧杂环丁烷或其它单体的溶剂，以制备具有低循环含量的低聚物，聚合物或共聚物。 合适的共聚单体通常包括各种环醚。 具有单个羟基端基的多氟全息聚氧乙烯低聚物，聚合物或共聚物可以用各种化合物进行官能化，以产生官能化的端基如丙烯酸酯，甲基丙烯酸酯，烯丙基，胺等，其官能化 低聚物或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化以提供润湿和表面性能的改进。
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公开(公告)号：US06673889B1
公开(公告)日：2004-01-06
申请号：US09397715
申请日：1999-09-16
IPC分类号： C08G1850
CPC分类号： C09D175/16 , C08F290/06 , C08F290/067 , C08G18/5015 , C08G18/672 , C08G65/18 , C08G65/226 , G03F7/0388 , C08G18/50
摘要： Acrylate, or methacrylate, or allylic, functionalized polyfluorooxetanes are disclosed for use in radiation curable coating compositions. These acrylate, or methacrylate, or allylic, functionalized polymers provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.
摘要翻译： 公开了丙烯酸酯或甲基丙烯酸酯或烯丙基官能化聚氟氧杂环烷用于可辐射固化涂料组合物中。 这些丙烯酸酯，或甲基丙烯酸酯或烯丙基官能化聚合物提供先前由迁移化学品如蜡和油提供的润湿性和表面性质的改善。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。
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公开(公告)号：US06465566B2
公开(公告)日：2002-10-15
申请号：US09833383
申请日：2001-04-12
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/3812 , C08G18/4607 , Y10T428/31551 , C08G18/3228
摘要： Anionic waterborne polyurethane dispersions are formed in the presence of polyfluorooxetane oligomers, polymers, or copolymers so that the polyfluorooxetanes are incorporated in the polyurethane. Coatings made from such polyurethanes have good low temperature flexibility, good chemical resistance, stain resistance, and abrasion resistance, as well as a low coefficient of friction. Alternatively, the anionic water borne polyurethane dispersion can be blended with vinyl ester monomers such as various acrylates and subsequently polymerized by radiation, for example ultraviolet light, to form a comingled blend of at least two different types of polymers. Another embodiment relates to a preformed copolymer made by reacting the polyfluorooxetane oligomer, polymer, or copolymer with a polycarboxylic acid such as a dicarboxylic acid and subsequently reacting the same with a polyol intermediate, such as a polymer, or with monomers forming the polyol intermediate.
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6.发明授权Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer 有权一元多氟氧杂环丁烷聚合物和含有单官能多氟氧杂环丁烷聚合物的可辐射固化涂层公开(公告)号：US06727344B2
公开(公告)日：2004-04-27
申请号：US10108318
申请日：2002-03-28
IPC分类号： C08G6522
CPC分类号： C09D175/16 , C08G18/5015 , C08G18/672 , C08G65/226 , Y10T428/31794 , C08G18/50
摘要： Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.
摘要翻译： 单官能聚氟乙烯低聚物和聚合物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 氟氧杂环丁烷低聚物或聚合物可以与通常的环醚共聚。 或者，具有单个羟基端基的多氟氧杂环丁烷低聚物或聚合物可以用各种化合物进行官能化，以产生官能化低聚物如丙烯酸酯，甲基丙烯酸酯，烯丙基胺，胺等官能端基 或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化，以提供以前由迁移的化学品如蜡和油提供的润湿和表面性能的改进。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。
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7.发明申请公开(公告)号：US20100218886A1
公开(公告)日：2010-09-02
申请号：US12799984
申请日：2010-05-06
IPC分类号： B29C51/14
CPC分类号： B29C51/14 , C08G18/10 , C08G18/5015 , C08G63/682 , C08G63/6824 , C08G65/18 , C08G65/226 , C08J3/244 , C08J7/047 , C08J2367/00 , C08J2467/00 , C08L61/20 , C08L67/00 , C09D167/00 , Y10T156/1028 , Y10T428/31786 , C08G18/46 , C08L2666/14 , C08L2666/16
摘要： A coating composition is based on a polyester mixed with an alkyl-etherified melamine formaldehyde. The coating composition is partially cured in a first stage to provide a thermoformable partially cured, tack-free, non-blocking, coating layer, followed by application to generally a contoured substrate and thermoforming to conform thereto. The contoured partially cured coating layer is then heat cured to form a cured coating. A hydroxyl-terminated polyoxetane containing repeat units derived from oxetane monomers having one or two pendent —CH2—O—(CH2)n—Rf groups, wherein Rf is partially or fully fluorinated, can be esterified with polyester-forming reactants to form a fluorinated polyoxetane-modified polyester.
摘要翻译： 涂料组合物基于与烷基醚化的三聚氰胺甲醛混合的聚酯。 涂料组合物在第一阶段中部分固化，以提供可热成型的部分固化的，无粘性的，非阻塞的涂层，然后通常用于轮廓基材和热成型以符合其。 然后将轮廓部分固化的涂层热固化以形成固化涂层。 含有衍生自具有一个或两个侧基-CH 2 -O-（CH 2）n -R f基团的氧杂环丁烷单体的重复单元的羟基封端的聚氧杂环丁烷，其中Rf部分或完全氟化，可以与形成聚酯的反应物酯化，以形成氟化 聚氧乙烯改性聚酯。
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8.发明授权公开(公告)号：US07727436B2
公开(公告)日：2010-06-01
申请号：US10492572
申请日：2003-03-05
CPC分类号： B29C51/14 , C08G18/10 , C08G18/5015 , C08G63/682 , C08G63/6824 , C08G65/18 , C08G65/226 , C08J3/244 , C08J7/047 , C08J2367/00 , C08J2467/00 , C08L61/20 , C08L67/00 , C09D167/00 , Y10T156/1028 , Y10T428/31786 , C08G18/46 , C08L2666/14 , C08L2666/16
摘要： A coating composition is based on a polyester mixed with an alkyl-etherified melamine formaldehyde. The coating composition is partially cured in a first stage to provide a thermoformable partially cured, tack-free, non-blocking, coating layer, followed by application to generally a contoured substrate and thermoforming to conform thereto. The contoured partially cured coating layer is then heat cured to form a cured coating. A hydroxyl-terminated polyoxetane containing repeat units derived from oxetane monomers having one or two pendent —CH2—O—(CH2)n—Rf groups, wherein Rf is partially or fully fluorinated, can be esterified with polyester-forming reactants to form a fluorinated polyoxetane-modified polyester.
摘要翻译： 涂料组合物基于与烷基醚化的三聚氰胺甲醛混合的聚酯。 涂料组合物在第一阶段中部分固化，以提供可热成型的部分固化的，无粘性的，非阻塞的涂层，然后通常用于轮廓基材和热成型以符合其。 然后将轮廓部分固化的涂层热固化以形成固化涂层。 含有衍生自具有一个或两个侧基-CH 2 -O-（CH 2）n -R f基团的氧杂环丁烷单体的重复单元的羟基封端的聚氧杂环丁烷，其中Rf部分或完全氟化，可以与形成聚酯的反应物酯化，以形成氟化 聚氧乙烯改性聚酯。
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9.发明授权Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coatings containing the same 有权一元多氟氧杂环丁烷低聚物，聚合物，共聚物和含有它们的涂料公开(公告)号：US06962966B2
公开(公告)日：2005-11-08
申请号：US09727637
申请日：2000-12-01
申请人： Robert Medsker , Gary L. Jialanella , Raymond J. Weinert , Guillermina C. Garcia , Aslam Malik , Roland Carlson
发明人： Robert Medsker , Gary L. Jialanella , Raymond J. Weinert , Guillermina C. Garcia , Aslam Malik , Roland Carlson
IPC分类号： C08G18/50 , C08G18/67 , C08G65/22 , C09D175/16
CPC分类号： C09D175/16 , C08G18/5015 , C08G18/672 , C08G65/226 , C08G18/50
摘要： Monofunctional polyfluorooxetane oligomers, polymers, and co-polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.
摘要翻译： 通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备单官能聚氟乙烯低聚物，聚合物和共聚物。 除了作为引发剂外，一元醇还可以用作氟氧杂环丁烷或其它单体的溶剂，以制备具有低循环含量的低聚物，聚合物或共聚物。 合适的共聚单体通常包括各种环醚。 具有单个羟基端基的多氟全息聚氧乙烯低聚物，聚合物或共聚物可以用各种化合物进行官能化，以产生官能化的端基如丙烯酸酯，甲基丙烯酸酯，烯丙基，胺等，其官能化 低聚物或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化以提供润湿和表面性能的改进。
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10.发明授权Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer 失效一元多氟氧杂环丁烷聚合物和含有单官能多氟氧杂环丁烷聚合物的可辐射固化涂层公开(公告)号：US06972317B2
公开(公告)日：2005-12-06
申请号：US10108916
申请日：2002-03-28
IPC分类号： C08G18/50 , C08G18/67 , C08G65/22 , C09D175/16
CPC分类号： C09D175/16 , C08G18/5015 , C08G18/672 , C08G65/226 , Y10T428/31794 , C08G18/50
摘要： Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.
摘要翻译： 单官能聚氟乙烯低聚物和聚合物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 氟氧杂环丁烷低聚物或聚合物可以与通常的环醚共聚。 或者，具有单个羟基端基的多氟氧杂环丁烷低聚物或聚合物可以用各种化合物进行官能化，以产生官能化低聚物等丙烯酸酯，甲基丙烯酸酯，烯丙基胺，胺等功能性端基 或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化，以提供以前由迁移的化学品如蜡和油提供的润湿和表面性能的改进。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。
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