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公开(公告)号：US06790925B2
公开(公告)日：2004-09-14
申请号：US10310313
申请日：2002-12-05
申请人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell D. Wayt , Edward P. Squiller , Richard R. Roesler
发明人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell D. Wayt , Edward P. Squiller , Richard R. Roesler
IPC分类号： C08G1850
CPC分类号： C08G73/1092
摘要： The present invention relates to polyaspartate mixtures containing a) 5 to 50 equiv. %, based on the total equivalents of aspartate groups, of a polyoxypropylene polyaspartate corresponding to the formula wherein X1 represents the residue obtained by removing the amino groups from a polyoxypropylene polyamine having a functionality of n, R1 and R2 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, R3 and R4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n is 2 to 4, and b) 50 to 95 equiv. %, based on the total equivalents of aspartate groups, of a polyether polyaspartate corresponding to the formula I wherein X1 represents the residue obtained by removing the amino groups from a polyether polyamine having a functionality of n and a number average molecular weight of less than 5000, wherein the amino groups are attached to primary carbon atoms and the ether groups are separated by at least two carbon atoms. The present invention also relates to a process for preparing these polyaspartate mixtures and to the polyureas prepared by reacting the polyaspartate mixtures and optionally other isocyanate-reactive compounds with polyisocyanates.
摘要翻译： 本发明涉及含有a）5至50当量的聚天冬氨酸盐混合物 基于天冬氨酸酯基团的总当量的％，对应于方解石的聚氧丙烯聚天冬氨酸酯X1代表通过从具有官能度n的聚氧丙烯多胺除去氨基而获得的残基，R 1和R 2相同或不同，并且表示有机基团 其在100℃或更低的温度下对异氰酸酯基团是惰性的，R3和R4相同或不同，并且表示在100℃或更低的温度下对异氰酸酯基团呈惰性的氢或有机基团，n为2 至4，和b）50至95当量 ％，基于天冬氨酸酯基团的总当量，对应于式I的聚醚聚天冬氨酸，其中X1表示通过从官能度为n且数均分子量小于5000的聚醚多胺除去氨基而获得的残基 ，其中所述氨基连接到伯碳原子上，并且所述醚基团被至少两个碳原子分开。 本发明还涉及制备这些聚天冬氨酸酯混合物的方法和通过使聚天冬氨酸盐混合物和任选的其它异氰酸酯反应性化合物与多异氰酸酯反应制备的聚脲。
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公开(公告)号：US06762274B2
公开(公告)日：2004-07-13
申请号：US10203496
申请日：2002-08-10
申请人： Simon Waddington , Jean-Marie L. Sonney , Richard J. Elwell , Francois M. Casati , Antoine Storione
发明人： Simon Waddington , Jean-Marie L. Sonney , Richard J. Elwell , Francois M. Casati , Antoine Storione
IPC分类号： C08G1850
CPC分类号： C08G18/632 , C08G18/4072 , C08G18/482 , C08G18/5024 , C08G18/6674 , C08G2101/0008 , C08G2101/0025 , C08G2101/005 , C08G2101/0083
摘要： The present invention discloses a process for producing a polyurethane product with autocatalytic polyols. These auto-catalytic polyols are based on an initiator of the formula (I): HmA-(CH2)n—N(R)-(CH2)p-AHm where n and p are independently integers from 2 to 6, A at each occurrence is independently oxygen, nitrogen or hydrogen, with the proviso that only one of A can be hydrogen at one time, R is a C1 to C3 alkyl group, m is equal to 0 when A is hydrogen, is 1 when A B is oxygen and is 2 when A is nitrogen; or are polyols which contain an alkyl amine of within the polyol chain or a dialkylylamino group pendant to the polyol chain wherein the polyol chain is obtained by copolymerization of at least one monomer containing an alkyl aziridine or N,N-dialkyl glycidylamine with at least one alkylene oxide. These auto-catalytic polyols are reacted with a polyisocyanate in the presence of other additives and/or auxiliary agents known per se to produce polyurethane products.
摘要翻译： 本发明公开了一种用自催化多元醇制备聚氨酯产品的方法。 这些自催化多元醇基于式（I）的引发剂：HmA-（CH2）nN（R） - （CH2）p-AHm，其中n和p独立地为2至6的整数，每次出现A 独立地是氧，氮或氢，条件是A中只有一个可以同时为氢，R为C1至C3烷基，当A为氢时m等于0，当AB为氧时为1，当AB为氧时为2 当A是氮时; 或者是含有多元醇链中的烷基胺或多元醇链侧基的二烷基氨基的多元醇，其中所述多元醇链通过至少一种含烷基氮丙啶或N，N-二烷基缩水甘油胺与至少一种 环氧烷。 在本身已知的其它添加剂和/或辅助剂的存在下，这些自动催化多元醇与多异氰酸酯反应以生产聚氨酯产品。
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公开(公告)号：US06642283B2
公开(公告)日：2003-11-04
申请号：US10036285
申请日：2001-10-26
申请人： Mark E. Ragsdale , Sandy G. Belue
发明人： Mark E. Ragsdale , Sandy G. Belue
IPC分类号： C08G1850
CPC分类号： C08J9/0004 , C08G18/38 , C08G2101/0008 , C08G2101/0083 , C08J2375/04
摘要： Polyurethane article black colorants which comprise a novel blue polymeric anthraquinone colorant, rather than the previous standard polymeric triphenylmethane blue-type colorants are provided. Such a novel blend of colorants to produce black colorations within the target polyurethane foams exhibits very low color degradation within polyurethane foams, primarily due to the stability and resiliency of the novel anthraquinone-based polymeric colorant in the presence of high isocyanate levels, as well as large amounts of reactive tertiary amines (from catalyst residue, for example). A black colorant comprising such a novel blue polymeric colorant, as well as polyurethane foams comprising such a novel black coloring agent and methods of producing such foams are all contemplated within this invention.
摘要翻译： 提供了包含新型蓝色聚合蒽醌着色剂的聚氨酯制品黑色着色剂，而不是以前的标准聚合物三苯基甲烷蓝型着色剂。 这种新型的着色剂混合物在目标聚氨酯泡沫内产生黑色着色表现出聚氨酯泡沫内的非常低的颜色降解，主要是由于在高异氰酸酯水平存在下新型的基于蒽醌的聚合物着色剂的稳定性和弹性，以及 大量的反应性叔胺（例如来自催化剂残基）。 包含这种新型蓝色聚合物着色剂的黑色着色剂以及包含这种新型黑色着色剂的聚氨酯泡沫以及制备这种泡沫的方法都在本发明中。
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公开(公告)号：US06437078B1
公开(公告)日：2002-08-20
申请号：US09775898
申请日：2001-02-02
申请人： Stuart B. Smith
发明人： Stuart B. Smith
IPC分类号： C08G1850
CPC分类号： C08G18/6692 , C08G18/12 , C08G18/348 , C08G18/5024 , C08G18/792
摘要： An aliphatic polyurea prepolymer prepared by the catalyst-free, exothermic reaction of a caprolactone monomer, an aliphatic primary polyamine, and an aliphatic monomer-free polyisocyanate, such as a hexamethylene diisocyanate dimer or trimer or mixtures thereof.
摘要翻译： 通过己内酯单体，脂族一级多胺和不含脂族单体的多异氰酸酯如六亚甲基二异氰酸酯二聚体或三聚体或其混合物的无催化剂放热反应制备的脂族聚脲预聚物。
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公开(公告)号：US06790924B2
公开(公告)日：2004-09-14
申请号：US10168117
申请日：2002-06-13
IPC分类号： C08G1850
CPC分类号： C04B41/4884 , Y10T428/3154
摘要： This invention relates to the application of fluorinated urethane compositions to stone in order to protect the stone from the deleterious effects of water and pollution.
摘要翻译： 本发明涉及氟化氨基甲酸酯组合物在石头上的应用，以保护石头免受水和污染的有害影响。
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公开(公告)号：US06723821B2
公开(公告)日：2004-04-20
申请号：US10078591
申请日：2002-02-19
申请人： Stuart B. Smith
发明人： Stuart B. Smith
IPC分类号： C08G1850
CPC分类号： C08G18/643 , C08G59/184 , C09D175/02
摘要： The invention features a polyamine epoxide adduct, prepared by admixing a source of epoxy group with a polyamine, and allowing the epoxy groups to react with the terminal amino groups of the polyamine so as to form the polyamine epoxy adduct. The polyamine epoxide adduct of the invention can be used as a component for preparing a polyurea polymer, thereby providing the resulting polyurea polymer with improved adhesiveness and greater chemical resistance to acidic conditions. Polyurea polymer coatings prepared from polyamine epoxide adducts demonstrate better chemical resistance and adhesion when applied to substrates than do conventionally prepared polyurea formulations.
摘要翻译： 本发明的特征在于通过将环氧基团与多胺混合并使环氧基与多胺的末端氨基反应以形成多胺环氧加合物制备的多胺环氧化物加合物。 本发明的多胺环氧化物加合物可用作制备聚脲聚合物的组分，从而提供所得聚脲聚合物具有改善的粘合性和对酸性条件的更高的耐化学性。 由多胺环氧化物加合物制成的聚脲聚合物涂层与常规制备的聚脲配方相比，在施加到基材上时具有更好的耐化学性和粘附性。
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公开(公告)号：US06673889B1
公开(公告)日：2004-01-06
申请号：US09397715
申请日：1999-09-16
IPC分类号： C08G1850
CPC分类号： C09D175/16 , C08F290/06 , C08F290/067 , C08G18/5015 , C08G18/672 , C08G65/18 , C08G65/226 , G03F7/0388 , C08G18/50
摘要： Acrylate, or methacrylate, or allylic, functionalized polyfluorooxetanes are disclosed for use in radiation curable coating compositions. These acrylate, or methacrylate, or allylic, functionalized polymers provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.
摘要翻译： 公开了丙烯酸酯或甲基丙烯酸酯或烯丙基官能化聚氟氧杂环烷用于可辐射固化涂料组合物中。 这些丙烯酸酯，或甲基丙烯酸酯或烯丙基官能化聚合物提供先前由迁移化学品如蜡和油提供的润湿性和表面性质的改善。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。
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公开(公告)号：US06770730B1
公开(公告)日：2004-08-03
申请号：US09439435
申请日：1999-11-15
申请人： Peter Roche , Thomas Bartz , Georg Knoblauch
发明人： Peter Roche , Thomas Bartz , Georg Knoblauch
IPC分类号： C08G1850
CPC分类号： C08G18/798 , C08G18/10 , C08G18/4841 , C08G18/4854 , C08G18/6674 , C08G18/48
摘要： A compact veneer is based on a reaction mixture comprising a) isocyanate, b) as compounds which are reactive toward isocyanates, a mixture (b1) comprising: b11) from 15 to 90% by weight, preferably from 50 to 80% by weight, based on the weight of the mixture (b1), of at least one polyether polyalcohol having a molecular weight of from 400 to 6000, preferably from 1000 to 4000 and a mean functionality of from 1.5 to 3 and based on hydroxyl-containing initiator substances and propylene oxide and also, if desired, ethylene oxide, b12) from 0 to 20% by weight, preferably from 0 to 10% by weight, based on the weight of the mixture (b1), of at least one polyether polyalcohol having a molecular weight of from 400 to 6000, preferably from 400 to 4000, and a mean functionality of from 1.5 to 3 and based on amino-containing initiator substances and propylene oxide and also, if desired, ethylene oxide, b13) from 0 to 35% by weight, preferably from 2 to 15% by weight, based on the weight of the mixture (b1), of at least one polyether polyalcohol having a molecular weight of from 150 to 7000 and a mean functionality of from 2.1 to 5, preferably from 3.1 to 5, b14) from 0 to 30% by weight, preferably from 10 to 25% by weight, based on the weight of the mixture (b1), of at least one bifunctional chain extender, plus, if desired, c) catalysts and/or d) auxiliaries and/or additives, where the sum of the percentages by weight of the components b11), (b12), (b13) and (b14) is preferably 100% by weight.
摘要翻译： 紧凑的单板基于包含a）异氰酸酯的反应混合物，b）作为对异氰酸酯反应的化合物，混合物（b1）包含：b11）15至90重量％，优选50至80重量％的基于 至少一种分子量为400至6000，优选1000至4000，平均官能度为1.5至3的聚醚多元醇和基于含羟基的引发剂物质和丙烯的混合物（b1）的重量 至少一种具有分子量的聚醚多元醇的氧化物，以及根据需要的氧化乙烯，b12）基于混合物（b1）的重量计，0至20重量％，优选0至10重量％ 从400至6000，优选400至4000，平均官能度为1.5至3，并且基于含氨基的引发剂物质和环氧丙烷以及根据需要的氧化乙烯b13）0至35重量％ ，优选2至15重量％，基于混合物的重量 （b1），至少一种分子量为150至7000且平均官能度为2.1至5，优选为3.1至5，b14的聚醚多元醇为0至30重量％，优选为10至25 基于混合物（b1）的重量，至少一种双功能扩链剂，如果需要，加上c）催化剂和/或）辅助剂和/或添加剂，其中重量百分比的总和 组分b11），（b12），（b13）和（b14）优选为100重量％。
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9.发明授权公开(公告)号：US06509387B1
公开(公告)日：2003-01-21
申请号：US09077914
申请日：1998-06-04
IPC分类号： C08G1850
CPC分类号： C08G18/482 , C08G2101/0025 , C08J9/141 , C08J2375/04
摘要： The description relates to production of rigid foamed plastics containing urethane groups, by use of a blowing-agent mixture containing 5 to 50 parts by weight of C3 and/or C4 alkanes and 50 to 95 parts by weight of cyclopentane. There is also a description of use of the thus-produced rigid foamed plastics as composite components or for foam filling of cavities in refrigerator construction.
摘要翻译： 该描述涉及使用含有5至50重量份的C3和/或C4烷烃和50至95重量份环戊烷的发泡剂混合物来生产含有氨基甲酸酯基的刚性发泡塑料。 还描述了如此制造的硬质泡沫塑料作为复合部件或在冰箱结构中用于泡沫填充空腔的用途。
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公开(公告)号：US06479614B1
公开(公告)日：2002-11-12
申请号：US09517458
申请日：2000-03-02
申请人： Guy Ampleman , Andre Marois , Sylvain Desilets
发明人： Guy Ampleman , Andre Marois , Sylvain Desilets
IPC分类号： C08G1850
CPC分类号： C06B45/105 , C08G18/5021 , Y10S149/122
摘要： An energetic copolyurethane thermoplastic elastomer (ETPE) is prepared by polymerizing a dihydroxyl terminated telechelic energetic polymer having a functionality of two or less with a diisocyanate at a NCO/OH ratio of about 0.7 to 1.2. The resulting copolymer is easy to incorporate in gun propellant or explosive formulations and is recyclable. These energetic copolyurethane thermoplastic elastomers were obtained mainly by macropolymerization of GAP prepolymers with 4,4′-methylenebis-phenyl isocyanate (MDI). In these syntheses, GAPs having molecular weights of 500, 1000 and 2000 were used as macromonomers and polymerized with MDI to yield three different copolyurethane thermoplastic elastomers. This process may be applied to any dihydroxyl terminated energetic prepolymers. The hard segments of the ETPE are obtained by the formation of hydrogen bonds between the urethane groups.
摘要翻译： 通过使官能度为2以下的二羟基封端的遥爪高分子聚合物与NCO / OH比约为0.7〜1.2的二异氰酸酯聚合，制备出能量高的共聚氨酯热塑性弹性体（ETPE）。 所得共聚物易于掺入喷枪或爆炸制剂中，并且是可回收利用的。 这些高分子聚氨酯热塑性弹性体主要通过GAP预聚物与4,4'-亚甲基双苯基异氰酸酯（MDI）的大分子聚合获得。 在这些合成中，使用分子量为500,1000和2000的GAP作为大分子单体，并与MDI聚合，得到三种不同的共聚氨酯热塑性弹性体。 该方法可以应用于任何二羟基封端的能量预聚物。 通过在氨基甲酸酯基团之间形成氢键，得到ETPE的硬链段。
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