公开(公告)号：US20060246216A1

公开(公告)日：2006-11-02

申请号：US11332494

申请日：2006-01-13

申请人： Gye-Won Hong ,  Hee-Gyon Lee ,  Sang-Im Yoo ,  Jai-Moo Yoo

发明人： Gye-Won Hong ,  Hee-Gyon Lee ,  Sang-Im Yoo ,  Jai-Moo Yoo

IPC分类号： B05D5/12 ,  B05D3/02

CPC分类号： H01L39/2425 ,  C01G3/006 ,  C01P2002/72 ,  C01P2006/40 ,  C04B35/4508 ,  C04B35/6264 ,  C04B35/6325 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C23C18/1216 ,  C23C18/1254 ,  C23C18/1291 ,  C23C18/1295

摘要： There is provided a method of fabricating a precursor solution for a metal organic deposition method using a superconducting oxide as a starting material, the method including dispersing a superconducting material powder in a TFA acid aqueous solution and heating them to dissolve the powder in the TFA solution; increasing a temperature of a hot substrate if the powder is completely dissolved, and the solution is clear, and continuously heating until the solution is vaporized and is in a viscous jelly state; stopping the heating if the solution loses its flowing property completely, and cooling the solution; and dissolving the compound in the jelly state, hardened at a room temperature, into an organic solvent, to provide metal organic deposition solution for coating. There is also provided a method of fabricating a thin film-typed superconductor using a metal organic deposition method, the method including dispersing a superconducting material powder in a TFA acid aqueous solution and heating them to dissolve the powder in the TFA solution; increasing a temperature of a hot substrate if the powder is completely dissolved, and the solution is clear, and continuously heating until the solution is vaporized and is in a viscous jelly state; stopping the heating if the solution loses its flowing property completely, and cooling the solution; dissolving the compound in the jelly state, hardened at a room temperature, into an organic solvent, to provide a superconducting material powder-TFA precursor solution; after forming a textured oxide buffer layer on a textured metal substrate, or forming a textured oxide template on a metal substrate and forming an oxide buffer layer thereon, dropping the superconducting material powder-TFA precursor solution on the single crystal metal substrate so as to deposit a thin film; and drying it to form the thin film; and applying a calcination heat treatment on the thin film to provide the thin film with a superconducting property. In the method of fabricating a thin film superconducting conductor using REBa2Cu3O7-x (RE=rare earth elements such as Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, etc. or mixture thereof), a precursor solution is fabricated by dissolving REBa2Cu3O7-x (RE=rare earth elements such as Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, etc. or mixture thereof) group of oxide into TFA acid aqueous solution, and using the precursor solution, the superconducting conductor can be provided more easily with a lower price than a conventional precursor solution.

公开(公告)号：US07625843B2

公开(公告)日：2009-12-01

申请号：US11332494

申请日：2006-01-13

申请人： Gye-Won Hong ,  Hee-Gyon Lee ,  Sang-Im Yoo ,  Jai-Moo Yoo

发明人： Gye-Won Hong ,  Hee-Gyon Lee ,  Sang-Im Yoo ,  Jai-Moo Yoo

IPC分类号： H01L39/24

CPC分类号： H01L39/2425 ,  C01G3/006 ,  C01P2002/72 ,  C01P2006/40 ,  C04B35/4508 ,  C04B35/6264 ,  C04B35/6325 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C23C18/1216 ,  C23C18/1254 ,  C23C18/1291 ,  C23C18/1295

摘要： There is provided a method of fabricating a precursor solution for a metal organic deposition method using a superconducting oxide as a starting material, wherein the method includes dispersing a superconducting material powder in a TFA acid aqueous solution, heating to dissolve the powder in the TFA solution, increasing a temperature of a hot substrate if the powder is completely dissolved and the solution is clear, continuously heating until the solution is vaporized and is in a viscous jelly state, stopping heating if the solution loses its flowing property completely, cooling the solution, and dissolving the compound in the jelly state, hardened at a room temperature, into an organic solvent to provide a metal organic deposition solution for coating. There is also provided a method of fabricating a thin film-type superconductor using a metal organic deposition method.

摘要翻译： 提供了一种使用超导氧化物作为起始材料制备用于金属有机沉积方法的前体溶液的方法，其中所述方法包括将超导材料粉末分散在TFA酸水溶液中，加热以将粉末溶解在TFA溶液中 如果粉末完全溶解并且溶液澄清，则继续加热直到溶液蒸发并处于粘稠的果冻状态，如果溶液完全失去流动性，停止加热，冷却溶液， 并将化合物溶解在熟化状态下，在室温下硬化成有机溶剂，得到用于涂布的金属有机沉积溶液。 还提供了使用金属有机沉积方法制造薄膜型超导体的方法。