摘要:
A CROSS-LINKABLE COMPOSITION IS OBTAINED BY ADMIXING AN UNSATURATED POLYMER, A PRECURSOR OF A POLYFUNCTIONAL NITRILE N-OXIDE OR NITRILE IMINE COMPOUND AND AN AMMONIA- OR AMINE-YIELDING COMPOUND SELECTED FROM THE GROUP CONSISTING OF AMMONIA-OR AMINE-YIELDING COORDINATION COMPOUNDS OF CERTAIN METALS, AMMONIA- OR AMINE YIELDING EXTRA-COORDINATE SILICONATE SALTS AND AMINE-YIELDING ORGANIC-SUBSTITUTED AMMONIUM SALTS.
摘要:
A cross-linkable polymer composition is obtained by admixing an unsaturated polymer, a polyfunctional hydrazide halide of a specified formula, and material that provides upon contact with atmospheric moisture at least one alkaline reactant that reacts with the hydrazide halide to form the corresponding polyfunctional nitrile imine which in turn cross-links the unsaturated polymer.
摘要:
CROSS-LINKABLE ETHYLENICALLY UNSATURATED POLYMER COMPOSITIONS ARE DESCRIBED, WHICH COMPOSITIONS COMPRISE AN ETHYLENICALLY UNSATURATED POLYMER, A PRECURSOR OF A POLYFUNCTIONAL NITRILE N-OXIDE OR NITRILE IMINE AND A LACTONE OR SULTONE. THESE COMPOSITIONS CROSS-LINK WHEN HEATED. SUITABLE LACTONES ARE THOSE CONTAINING 3 OR 4 CARBON ATOMS IN THE LACTONE RING SUCH AS PROPIOLACTONES AND BUTYROLACTONES AND SUITABLE SULTONES ARE THOSE CONTAINING 3 CARBON ATOMS IN THE SULTONE RING SUCH AS 1,3-PROPANE SULTONE. THESE COMPOSITIONS ARE USEFUL AS SEALANTS AND ADHESIVES.
摘要:
CROSS-LINKABLE POLYMER COMPOSITIONS ARE DESCRIBED WHICH COMPRISE AN ETHYLENICALLY UNSATURATED POLYMER, THE SULTONE ADDUCT OF A TERTIARY AMINE AND A PRECURSOR OF A POLYFUNCTIONAL NITRILE N OR NITRILE IMINE. TYPICAL SULTONE ADDUCTS ARE THE 1,3-PROPANE SULTONE ADDUCTS OF TRIETHYLAMINE, TRIETHYLENEDIAMINE, N-METHYL MORPHOLINE AND QUINUCLIDINE. THESE COMPOSITIONS, WHICH CROSS-LINK ON HEATING, ARE USEFUL AS SEALANTS AND ADHESIVES AND IN COATING COMPOSITIONS.
摘要:
A CROSS-LINKABLE POLYMER COMPOSITION IS OBTAINED BY ADMIXING AN UNSATURATED POLYMER, A POLYFUNCTIONAL HYDRAZIDE HALIDE OF A SPECIFIED FORMULA, AND MATERIAL THAT PROVIDES UPON CONTACT WITH WATER AT LEAST ONE ALKALINE REACTANT THAT REACTS WITH THE HYDRAZIDE HALIDE TO FORM THE CORRESPONDING POLYFUNCTIONAL NITRILE IMINE WHICH IN TURN CROSS-LINKS THE UNSATURATED POLYMER.
摘要:
DISCLOSED IS A SULFUR DIOXIDE ADDITION PRODUCT HAVING THE FORMULA:
(R-C(-R) (-C(-R)2-C(-R)2-)).SO2
WITH SULFUR DIOXIDE UNDER SUBSTANTIALLY ANHYDROUS CONDITIONS AND PREFERABLY IN AN INERT LIQUID IN WHICH THE COMPOUND IS SUBSTANTIALLY SOLUBLE AND THE ADDITION PRODUCT IS SUBSTANTIALLY INSOLUBLE.
(-C(-R)2-C(-R)2-)
(R-)2-C WHEREIN Z IS SELECTED FROM THE GROUP CONSISTING OF THE N AND R-C RADICALS, EACH R IS INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF THE HYDROGEN AND C1-C8 ALKYL RADICALS N IS 1 WHEN Z IS THE R-C RADICAL AND N IS 1-2 WHEN Z IS THE N RADICAL. THIS ADDITION PRODUCT IS MADE BY CONTACTING A COMPOUND HAVING THE FORMULA:
摘要:
The disclosed compositions contain an ethylenically unsaturated polymer and an addition product of sulfur dioxide with certain bicyclic tertiary amines, representative of which is triethylenediamine. The compositions may be cross-linked by the application of heat.