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公开(公告)号:US20240317952A1
公开(公告)日:2024-09-26
申请号:US18611853
申请日:2024-03-21
Applicant: HYDROLITE LTD
Inventor: Charly David AZRA , Yauhen AKAYEU , Amiram SISSO
IPC: C08J5/22 , B01D67/00 , B01D69/02 , B01D71/26 , B01D71/28 , B01D71/78 , B01J41/05 , B01J41/14 , B01J47/12 , C02F1/46 , C08J3/00 , C08J3/24 , C08J7/12 , C25B13/08 , H01M8/0221
CPC classification number: C08J5/2287 , B01D67/0006 , B01D69/02 , B01D71/26 , B01D71/281 , B01D71/78 , B01J41/05 , B01J41/14 , B01J47/12 , C02F1/4604 , C08J3/005 , C08J3/24 , C08J7/123 , C25B13/08 , H01M8/0221 , B01D2323/081 , B01D2323/30 , B01D2323/385 , B01D2323/60 , B01D2325/42 , C08J2323/06 , C08J2327/04 , C08J2353/02 , C08J2423/06 , C08J2427/04 , C08J2453/02
Abstract: Methods of preparing reinforced anion exchange membranes are provided, as well as produced membranes and corresponding devices utilizing the membranes. Methods comprise compounding a halide-functionalized polymer (selected to react with amines to yield anion-conducting quaternary amine groups) with thermoplastic polymer(s) (selected to support and/or reinforce the membrane), and with copolymer(s) (selected to enhance the compounding of the polymers)—by heating, mixing and cooling—to form blend pellets, extruding the blend pellets to form a blend film, cross-linking polymer(s), and functionalizing the blend film to prepare the anion exchange membrane. Functionalization comprises a quaternization step comprising reacting halogen groups of the first polymer with tertiary amines to produce the quaternary amine groups with ion-exchange functionality. Reinforced anion exchange membranes are provided, which are produced by the disclosed methods, functionalized to yield a membrane for fuel cell(s), electrolyzer(s), reversible electrochemical device(s), desalination unit(s), etc.