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公开(公告)号:US11124423B2
公开(公告)日:2021-09-21
申请号:US16481619
申请日:2018-03-07
申请人: Haldor Topsøe A/S
发明人: Christian Henrik Speth , Per Juul Dahl , Annette E. Krøll Jensen , Niels Christian Schjødt , Marcus Symreng
摘要: A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
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公开(公告)号:US11175040B2
公开(公告)日:2021-11-16
申请号:US16071365
申请日:2017-02-20
申请人: HALDOR TOPSØE A/S
摘要: A method and an apparatus for protection of a combustion unit of a chemical process against over firing, the burner(s) of the combustion unit are limited by a fuel and duty limiter which limits the duty based on process feeds, combustion gas and fuel flows.
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公开(公告)号:US20190382277A1
公开(公告)日:2019-12-19
申请号:US16481619
申请日:2018-03-07
申请人: HALDOR TOPSØE A/S
发明人: Christian Henrik Speth , Per Juul Dahl , Annette E. Krøll Jensen , Niels Christian Schjødt , Marcus Symreng
摘要: A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
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公开(公告)号:US20180299120A1
公开(公告)日:2018-10-18
申请号:US15767709
申请日:2016-12-07
申请人: Haldor Topsøe A/S
IPC分类号: F22B35/00
摘要: The present relates to a method for controlling the inlet temperature Ti to a conversion process, said method comprising the steps of: Providing a feed for a conversion process; In a first temperature control step regulating the temperature of the feed in a waste heat boiler; In a second temperature control step injecting a water stream into the feed downstream the waste heat boiler in an amount and/or at a temperature to obtain the desired inlet temperature into the conversion process.
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公开(公告)号:US11498835B2
公开(公告)日:2022-11-15
申请号:US16071313
申请日:2017-02-28
申请人: HALDOR TOPSØE A/S
发明人: Annette E. Krøll Jensen , Christian Henrik Speth , Thomas Rostrup-Nielsen , Niels Christian Schjødt
摘要: The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH4, CO, CO2, H2 and H2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step, said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
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公开(公告)号:US11286159B2
公开(公告)日:2022-03-29
申请号:US16620150
申请日:2018-06-28
申请人: HALDOR TOPSØE A/S
摘要: In a process for the production of ammonia synthesis gas from a hydrocarbon-containing feedstock, comprising steam reforming of the feedstock and treatment of the synthesis gas obtained, the shift of the synthesis gas comprises two shift steps, both including stable catalysts, whereby the formation of hazardous by-products is avoided or at least reduced to an acceptable low level. The two shift steps can both be HTS, or they can be one HTS and one LTS or one HTS and one MTS. The catalyst used in the HTS and the LTS steps is based on zinc oxide and zinc aluminum spinel, and the catalyst used in the MTS and the LTS steps can be based on copper.
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公开(公告)号:US20210206634A1
公开(公告)日:2021-07-08
申请号:US16071313
申请日:2017-02-28
申请人: HALDOR TOPSØE A/S
发明人: Annette E. Krøll Jensen , Christian Henrik Speth , Thomas Rostrup-Nielsen , Niels Christian Schjødt
摘要: The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH4, CO, CO2, H2 and H2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step, said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
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公开(公告)号:US11040321B2
公开(公告)日:2021-06-22
申请号:US16764655
申请日:2018-12-19
申请人: Haldor Topsøe A/S
摘要: In an adiabatic axial flow converter, in which process gas passes from an outer annulus via a catalyst bed, wherein the process gas is converted to a product, to an inner centre tube, the catalyst bed comprises at least one module comprising one or more catalyst layers. Feed means are arranged to provide a flow of process gas from the outer annulus to an inlet part of one or more modules, and collector means are arranged to provide a flow of product stream of converted process gas which passes axially through the catalyst bed of one or more of the modules to the centre tube.
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公开(公告)号:US20200368706A1
公开(公告)日:2020-11-26
申请号:US16764301
申请日:2018-12-19
申请人: Haldor Topsøe A/S
摘要: A method and reactor for performing exothermic reactions with parallel operated catalyst modules arranged in stacked order within a pressure shell and adapted to axial flow of process gas through one or more catalyst layers and at least one catalyst layer cooled by an intrabed heat exchanger.
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公开(公告)号:US20190152791A1
公开(公告)日:2019-05-23
申请号:US16099893
申请日:2017-06-09
申请人: Haldor Topsøe A/S
CPC分类号: C01C1/0441 , B01J8/0214 , B01J8/0242 , B01J8/0257 , B01J8/0285 , B01J8/0415 , B01J8/0469 , B01J8/0496 , B01J8/067 , B01J19/24 , B01J19/249 , B01J2208/00159 , B01J2208/021 , B01J2208/022 , B01J2208/065 , B01J2219/00085 , B01J2219/2455 , B01J2219/2458 , B01J2219/2462 , B01J2219/2481
摘要: In a cooled axial/radial flow converter, in which process gas passes from an outer annulus via a catalyst bed to an inner centre tube, the catalyst bed is divided into identical modules stacked on top of each other. The process gas reaches the catalyst through openings facing the outer annulus, passes axially down the catalyst bed of each module, leaves the module through collectors in the bottom thereof, and flows to the centre tube. The catalyst bed is cooled by cooling panels, in which the process gas is pre-heated to the reaction temperature, while at the same time the heat of reaction is partly removed from the catalyst bed. The converter is especially suitable as ammonia converter.
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