-
公开(公告)号:US11124423B2
公开(公告)日:2021-09-21
申请号:US16481619
申请日:2018-03-07
申请人: Haldor Topsøe A/S
发明人: Christian Henrik Speth , Per Juul Dahl , Annette E. Krøll Jensen , Niels Christian Schjødt , Marcus Symreng
摘要: A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
-
公开(公告)号:US11840448B2
公开(公告)日:2023-12-12
申请号:US16622044
申请日:2018-07-11
申请人: Haldor Topsøe A/S
CPC分类号: C01B3/025 , C01B3/382 , C01B3/384 , C01C1/0405 , C25B1/04 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/046 , C01B2203/0445 , C01B2203/0475 , C01B2203/1235
摘要: Method for the preparation of ammonia synthesis gas based on a combination of autothermal reforming and electrolysis of water.
-
公开(公告)号:US10941038B2
公开(公告)日:2021-03-09
申请号:US16074515
申请日:2017-02-02
申请人: HALDOR TOPSØE A/S
摘要: A process for producing an ammonia synthesis gas, said process including the steps of: reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O; and shifting said synthesis gas in a high temperature shift step over a promoted zinc-aluminum oxide based high temperature shift catalyst, wherein the steam/carbon ratio in the reforming step is less than 2.6.
-
公开(公告)号:US20200172394A1
公开(公告)日:2020-06-04
申请号:US16622044
申请日:2018-07-11
申请人: Haldor Topsøe A/S
摘要: Method for the preparation of ammonia synthesis gas based on a combination of autothermal reforming and electrolysis of water.
-
公开(公告)号:US20190382277A1
公开(公告)日:2019-12-19
申请号:US16481619
申请日:2018-03-07
申请人: HALDOR TOPSØE A/S
发明人: Christian Henrik Speth , Per Juul Dahl , Annette E. Krøll Jensen , Niels Christian Schjødt , Marcus Symreng
摘要: A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
-
公开(公告)号:US11498835B2
公开(公告)日:2022-11-15
申请号:US16071313
申请日:2017-02-28
申请人: HALDOR TOPSØE A/S
发明人: Annette E. Krøll Jensen , Christian Henrik Speth , Thomas Rostrup-Nielsen , Niels Christian Schjødt
摘要: The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH4, CO, CO2, H2 and H2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step, said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
-
公开(公告)号:US11370658B2
公开(公告)日:2022-06-28
申请号:US16622068
申请日:2018-07-11
申请人: Haldor Topsøe A/S
摘要: Method for the preparation of ammonia synthesis gas by a combination of ATR or secondary reforming process using oxygen from an air separation unit and electrolysis of water for the production of ammonia synthesis gas.
-
公开(公告)号:US11286159B2
公开(公告)日:2022-03-29
申请号:US16620150
申请日:2018-06-28
申请人: HALDOR TOPSØE A/S
摘要: In a process for the production of ammonia synthesis gas from a hydrocarbon-containing feedstock, comprising steam reforming of the feedstock and treatment of the synthesis gas obtained, the shift of the synthesis gas comprises two shift steps, both including stable catalysts, whereby the formation of hazardous by-products is avoided or at least reduced to an acceptable low level. The two shift steps can both be HTS, or they can be one HTS and one LTS or one HTS and one MTS. The catalyst used in the HTS and the LTS steps is based on zinc oxide and zinc aluminum spinel, and the catalyst used in the MTS and the LTS steps can be based on copper.
-
公开(公告)号:US20210206634A1
公开(公告)日:2021-07-08
申请号:US16071313
申请日:2017-02-28
申请人: HALDOR TOPSØE A/S
发明人: Annette E. Krøll Jensen , Christian Henrik Speth , Thomas Rostrup-Nielsen , Niels Christian Schjødt
摘要: The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH4, CO, CO2, H2 and H2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step, said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
-
公开(公告)号:US20210198104A1
公开(公告)日:2021-07-01
申请号:US16622068
申请日:2018-07-11
申请人: Haldor Topsøe A/S
摘要: Method for the preparation of ammonia synthesis gas by a combination of ATR or secondary reforming process using oxygen from an air separation unit and electrolysis of water for the production of ammonia synthesis gas.
-
-
-
-
-
-
-
-
-