公开(公告)号：US11034713B2

公开(公告)日：2021-06-15

申请号：US15319332

申请日：2015-06-18

Applicant: Haldor Topsøe A/S

Inventor： Saravanamurugan Shunmugavel ,  Irantzu Sadaba Zubiri ,  Esben Taarning ,  Martin Spangsberg Holm

IPC: B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/89 ,  C01B37/00 ,  C01B39/02 ,  C01B39/08 ,  C01B39/40 ,  C01B39/46 ,  C07C67/08 ,  C07H1/00 ,  C07H3/02 ,  A23L27/30 ,  A23L33/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/10 ,  C07C51/16 ,  C07D307/36

Abstract: A process for the preparation of C4 oxygenate compounds such as threose, erythrose or erythrulose starting from a composition comprising C1-3 oxygenate compounds such as formaldehyde, glycolaldehyde, glyoxal, pyruvaldehyde or acetol, wherein the process is carried out in the presence of a crystalline microporous material having a ring pore structure selected from an eight-membered ring pore structure or a ten-membered ring pore structure.

公开(公告)号：US10100007B2

公开(公告)日：2018-10-16

申请号：US15525450

申请日：2015-11-12

Applicant: Haldor Topsøe A/S

Inventor： Irantzu Sadaba Zubiri ,  Esben Taarning

IPC: C07C319/18 ,  C07C69/732 ,  C07C69/68 ,  C07C67/47 ,  C07C67/44 ,  C07C67/475

Abstract: A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or α-hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.

公开(公告)号：US20180118673A1

公开(公告)日：2018-05-03

申请号：US15568943

申请日：2016-04-29

Applicant: Haldor Topsøe A/S

Inventor： Irantzu Sadaba Zubiri ,  Esben Taarning ,  Despina Tzoulaki

IPC: C07C319/14 ,  C07C321/04 ,  A23K20/142 ,  A23L33/17

CPC classification number: C07C319/14 ,  A23K20/10 ,  A23K20/142 ,  A23L33/17 ,  A23V2002/00 ,  C07C321/04 ,  C07C323/52

Abstract: A process for the preparation of methionine α-hydroxy analogue and derivatives thereof comprising contacting one or more sugars or derivatives thereof with a metallo-silicate composition in the presence of a compound comprising sulphur and a solvent.

公开(公告)号：US20160175822A1

公开(公告)日：2016-06-23

申请号：US14910319

申请日：2014-08-15

Applicant: HALDOR TOPSØE A/S

Inventor： Martin Spangsberg Holm ,  Irantzu Sadaba Zubiri ,  Søren Tolborg ,  Christian Mårup Osmundsen ,  Esben Taarning

IPC: B01J29/70 ,  B01J29/08 ,  C07C67/00

CPC classification number: B01J29/7057 ,  B01J29/088 ,  B01J29/7049 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/16 ,  C07C67/00 ,  Y02P20/582 ,  C07C69/68

Abstract: A process for the preparation of lactic acid and 2-hydroxy-3-butenoic acid or esters thereof from a sugar in the presence of a metallo-silicate material, a metal ion and a solvent, wherein the metal ion is selected from one or more of the group consisting of potassium ions, sodium ions, lithium ions, rubidium ions and caesium ions.

Abstract translation: 一种在金属硅酸盐材料，金属离子和溶剂的存在下从糖制备乳酸和2-羟基-3-丁烯酸或其酯的方法，其中金属离子选自一种或多种 由钾离子，钠离子，锂离子，铷离子和铯离子组成的组。

公开(公告)号：US11040934B2

公开(公告)日：2021-06-22

申请号：US16394009

申请日：2019-04-25

Applicant: HALDOR TOPSØE A/S

Inventor： Esben Taarning ,  Irantzu Sadaba Zubiri ,  Sebastian Meier

IPC: C07C59/42 ,  C07C67/39 ,  C07C51/16 ,  B01J29/70 ,  C07C69/732

Abstract: Preparation of 2,5,6-trihydroxy-3-hexenoic acid and 2,5-dihydroxy-3-pentenoic acid and esters thereof from C6 and C5 sugars in the presence of a Lewis Acid material, wherein the yield of the 2,5,6-trihydroxy-3-hexenoic acid or 2,5-dihydroxy-3-pentenoic acid or esters thereof exceeds 15%. The process including the steps of contacting a saccharide composition including one or more C6 and/or C5 saccharide units with a Lewis Acid material; and recovering 2,5,6-trihydroxy-3-hexenoic acid and/or 2,5-dihydroxy-3-pentenoic acid or the esters thereof.

公开(公告)号：US09573123B2

公开(公告)日：2017-02-21

申请号：US14910319

申请日：2014-08-15

Applicant: Haldor Topsøe A/S

Inventor： Martin Spangsberg Holm ,  Irantzu Sadaba Zubiri ,  Søren Tolborg ,  Christian Mårup Osmundsen ,  Esben Taarning

IPC: C07C69/66 ,  B01J29/70 ,  C07C67/00 ,  B01J29/08

CPC classification number: B01J29/7057 ,  B01J29/088 ,  B01J29/7049 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/16 ,  C07C67/00 ,  Y02P20/582 ,  C07C69/68

Abstract: A process for the preparation of lactic acid and 2-hydroxy-3-butenoic acid or esters thereof from a sugar in the presence of a metallo-silicate material, a metal ion and a solvent, wherein the metal ion is selected from one or more of the group consisting of potassium ions, sodium ions, lithium ions, rubidium ions and caesium ions.

Abstract translation: 一种在金属硅酸盐材料，金属离子和溶剂的存在下从糖制备乳酸和2-羟基-3-丁烯酸或其酯的方法，其中金属离子选自一种或多种 由钾离子，钠离子，锂离子，铷离子和铯离子组成的组。

公开(公告)号：US10315979B2

公开(公告)日：2019-06-11

申请号：US15737395

申请日：2016-06-20

Applicant: HALDOR TOPSØE A/S

Inventor： Esben Taarning ,  Irantzu Sadaba Zubiri ,  Sebastian Meier

IPC: C07C59/42 ,  C07C67/39 ,  C07C51/16 ,  B01J29/70 ,  C07C69/732

Abstract: Preparation of 2,5,6-trihydroxy-3-hexenoic acid and 2,5-dihydroxy-3-pentenoic acid and esters thereof from C6 and C5 sugars in the presence of a Lewis Acid material, wherein the yield of the 2,5,6-trihydroxy-3-hexenoic acid or 2,5-dihydroxy-3-pentenoic acid or esters thereof exceeds 15%.

公开(公告)号：US10189778B2

公开(公告)日：2019-01-29

申请号：US15568943

申请日：2016-04-29

Applicant: HALDOR TOPSØE A/S

Inventor： Irantzu Sadaba Zubiri ,  Esben Taarning ,  Despina Tzoulaki

IPC: A23K20/10 ,  A23L33/17 ,  A23K20/142 ,  C07C319/14 ,  C07C321/04 ,  C07C323/52

Abstract: A process for the preparation of methionine a-hydroxy analogue and derivatives thereof comprising contacting one or more sugars or derivatives thereof with a metallo-silicate composition in the presence of a compound comprising sulphur and a solvent.