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公开(公告)号:US07011806B2
公开(公告)日:2006-03-14
申请号:US10714382
申请日:2003-11-14
申请人: Hans Christian Alt , Andreas Gölz , Alfred Alig
发明人: Hans Christian Alt , Andreas Gölz , Alfred Alig
IPC分类号: C01B17/38
CPC分类号: C01B17/38 , B01J2/04 , C01P2004/50 , C01P2004/60
摘要: A process and a device for producing anhydrous alkali sulfide, wherein an alkali sulfide solution, alkali sulfide suspension, alkali sulfide dispersion or alkali water of crystallization melt is dried by spray drying with inert drying gas loaded with water vapor.
摘要翻译: 一种用于生产无水碱硫化物的方法和装置,其中碱金属硫化物溶液,碱金属硫化物悬浮液,碱金属硫化物分散体或结晶熔融碱性水通过用负载有水蒸汽的惰性干燥气体喷雾干燥而干燥。
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公开(公告)号:US07518009B2
公开(公告)日:2009-04-14
申请号:US11415183
申请日:2006-05-02
申请人: Karsten Korth , Dorit Wolf , Steffen Seebald , Philipp Albert , Reimund Pieter , Alfred Alig
发明人: Karsten Korth , Dorit Wolf , Steffen Seebald , Philipp Albert , Reimund Pieter , Alfred Alig
CPC分类号: C07F7/1892
摘要: The present invention relates to a process for preparing mercaptoorganyl(alkoxysilanes), by hydrogenating bis(alkoxy-silylorganyl) polysulphides with hydrogen in the presence of at least one alcohol and a doped metal catalyst. The doped metal catalyst comprises at least one substance from the group consisting of iron, iron compound, nickel, nickel compound, palladium, palladium compound, osmium, osmium compound, ruthenium, ruthenium compound, rhodium, rhodium compound, iridium and iridium compound plus at least one doping component.
摘要翻译: 本发明涉及通过在至少一种醇和掺杂的金属催化剂的存在下用氢气氢化双(烷氧基 - 甲硅烷基有机基)多硫化物来制备巯基有机基(烷氧基硅烷)的方法。 掺杂金属催化剂包括至少一种物质,由铁,铁化合物,镍,镍化合物,钯,钯化合物,锇,锇化合物,钌,钌化合物,铑,铑化合物,铱和铱化合物 至少一种掺杂成分。
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公开(公告)号:US08129556B2
公开(公告)日:2012-03-06
申请号:US12509089
申请日:2009-07-24
申请人: Karsten Korth , Ingo Kiefer , Alfred Alig , Ulrich Deschler , Helmut Droege , Sefan Koenigstein , Stephanie Schwan
发明人: Karsten Korth , Ingo Kiefer , Alfred Alig , Ulrich Deschler , Helmut Droege , Sefan Koenigstein , Stephanie Schwan
IPC分类号: C07F7/04
CPC分类号: C07F7/1892
摘要: The invention relates to a process for preparing organosilanes of the general formula I by reacting (haloorganyl)alkoxysilane of the formula II with hydrous alkali metal hydrogensulphide, sulphur and alkali metal carbonate in alcohol, wherein the molar (haloorganyl)alkoxysilane of the formula II to alkali metal hydrogensulphide ratio is between 1:0.4 and 1:0.75, and the molar alkali metal hydrogensulphide to alkali metal carbonate ratio is between 1:0.5 and 1:1.5.
摘要翻译: 本发明涉及通式(Ⅱ)的(卤代有机基)烷氧基硅烷与含水碱金属硫化氢,硫和碱金属碳酸盐在醇中反应制备通式Ⅰ的有机硅烷的方法,其中式Ⅱ的摩尔(卤代有机基) 碱金属硫化氢的比例在1:0.4至1:0.75之间,碱金属硫化氢与碱金属碳酸盐的摩尔比为1:0.5至1:1.5。
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公开(公告)号:US07371881B2
公开(公告)日:2008-05-13
申请号:US11497633
申请日:2006-08-02
申请人: Albert Frings , Louis Janssens , Stefan Lotter , Ulrich Deschler , Alfred Alig
发明人: Albert Frings , Louis Janssens , Stefan Lotter , Ulrich Deschler , Alfred Alig
IPC分类号: C07F7/08
CPC分类号: C07F7/1892
摘要: A process for the preparation of an organosilicon compound of the formula (I) (R1R2R3SiR4)2Sx (I) by reacting haloalkoxysilanes of the general formula (II) R1R2R3SiR4X (II) with a dry polysulphide of the general formula (III) M2Sz (III) and/or dry sulphide of the general formula IV M2S (IV) and optionally sulphur in an organic solvent, the organic solvent being removed from the resulting suspension, the mixture containing the organosilicon compound of the general formula (I) and the solid MX being mixed with water containing at least one buffer, and the resulting phases being separated.
摘要翻译: 制备式(I)的有机硅化合物的方法<?in-line-formula description =“In-line Formula”end =“lead”→>(R 1) > 2 u> 3 i> S u> S u> S u> 通过使通式(II)的卤代烷氧基硅烷与式(II)中的<?in-line-formula description =“In-Line Formulas”end =“lead”→> R X(II)<β在线公式描述=“In” 用“通式(III)”表示的干燥多硫化物“-line”=“尾”→“in-line-formula description =”In-line Formulas“end =”lead“?> M& (III)<?in-line-formula description =“In-line Formulas”end =“tail”?>和/或通式IV <β的干硫化物 -line-formula description =“In-line Formulas”end =“lead”?> M 2 S(IV)<?in-line-formula description =“In-line Formulas”end =“ 尾“→和有机溶剂中的硫,有机溶剂 从所得悬浮液中除去含有通式(I)的有机硅化合物和固体MX的混合物与含有至少一种缓冲液的水混合,并将所得相分离。
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公开(公告)号:US20100029971A1
公开(公告)日:2010-02-04
申请号:US12509089
申请日:2009-07-24
申请人: Karsten Korth , Ingo Kiefer , Alfred Alig , Ulrich Deschler , Helmut Droege , Sefan Koenigstein , Stephanie Schwan
发明人: Karsten Korth , Ingo Kiefer , Alfred Alig , Ulrich Deschler , Helmut Droege , Sefan Koenigstein , Stephanie Schwan
IPC分类号: C07F7/08
CPC分类号: C07F7/1892
摘要: The invention relates to a process for preparing organosilanes of the general formula I by reacting (haloorganyl)alkoxysilane of the formula II with hydrous alkali metal hydrogensulphide, sulphur and alkali metal carbonate in alcohol, wherein the molar (haloorganyl)alkoxysilane of the formula II to alkali metal hydrogensulphide ratio is between 1:0.4 and 1:0.75, and the molar alkali metal hydrogensulphide to alkali metal carbonate ratio is between 1:0.5 and 1:1.5.
摘要翻译: 本发明涉及通式(Ⅱ)的(卤代有机基)烷氧基硅烷与含水碱金属硫化氢,硫和碱金属碳酸盐在醇中反应制备通式Ⅰ的有机硅烷的方法,其中式Ⅱ的摩尔(卤代有机基) 碱金属硫化氢的比例在1:0.4至1:0.75之间,碱金属硫化氢与碱金属碳酸盐的摩尔比为1:0.5至1:1.5。
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公开(公告)号:US20060252952A1
公开(公告)日:2006-11-09
申请号:US11415183
申请日:2006-05-02
申请人: Karsten Korth , Dorit Wolf , Steffen Seebald , Philipp Albert , Reimund Pieter , Alfred Alig
发明人: Karsten Korth , Dorit Wolf , Steffen Seebald , Philipp Albert , Reimund Pieter , Alfred Alig
IPC分类号: C07F7/04
CPC分类号: C07F7/1892
摘要: The present invention relates to a process for preparing mercaptoorganyl(alkoxysilanes), by hydrogenating bis(alkoxy-silylorganyl) polysulphides with hydrogen in the presence of at least one alcohol and a doped metal catalyst. The doped metal catalyst comprises at least one substance from the group consisting of iron, iron compound, nickel, nickel compound, palladium, palladium compound, osmium, osmium compound, ruthenium, ruthenium compound, rhodium, rhodium compound, iridium and iridium compound plus at least one doping component.
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公开(公告)号:US20070066841A1
公开(公告)日:2007-03-22
申请号:US11497633
申请日:2006-08-02
申请人: Albert Frings , Louis Janssens , Stefan Lotter , Ulrich Deschler , Alfred Alig
发明人: Albert Frings , Louis Janssens , Stefan Lotter , Ulrich Deschler , Alfred Alig
IPC分类号: C07F7/08
CPC分类号: C07F7/1892
摘要: A process for the preparation of an organosilicon compound of the formula (I) (R1R2R3SiR4)2Sx (I) by reacting haloalkoxysilanes of the general formula (II) R1R2R3SiR4X (II) with a dry polysulphide of the general formula (III) M2Sz (III) and/or dry sulphide of the general formula IV M2S (IV) and optionally sulphur in an organic solvent, the organic solvent being removed from the resulting suspension, the mixture containing the organosilicon compound of the general formula (I) and the solid MX being mixed with water containing at least one buffer, and the resulting phases being separated.
摘要翻译: 制备式(I)的有机硅化合物的方法<?in-line-formula description =“In-line Formula”end =“lead”→>(R 1) > 2 u> 3 i> S u> S u> S u> 通过使通式(II)的卤代烷氧基硅烷与式(II)中的<?in-line-formula description =“In-Line Formulas”end =“lead”→> R X(II)<β在线公式描述=“In” 用“通式(III)”表示的干燥多硫化物“-line”=“尾”→“in-line-formula description =”In-line Formulas“end =”lead“?> M& (III)<?in-line-formula description =“In-line Formulas”end =“tail”?>和/或通式IV <β的干硫化物 -line-formula description =“In-line Formulas”end =“lead”?> M 2 S(IV)<?in-line-formula description =“In-line Formulas”end =“ 尾“”和任选地在有机溶剂中的硫,即有机溶剂 从所得悬浮液中除去含有通式(I)的有机硅化合物和固体MX的混合物与含有至少一种缓冲液的水混合,并将所得相分离。
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公开(公告)号:US20060008411A1
公开(公告)日:2006-01-12
申请号:US11199403
申请日:2005-08-08
申请人: Hans Alt , Andreas Golz , Alfred Alig
发明人: Hans Alt , Andreas Golz , Alfred Alig
IPC分类号: C01B17/22
CPC分类号: B01J2/16 , C01B17/38 , C01P2004/50 , C01P2004/60
摘要: A process and a device for producing anhydrous alkali sulfide, wherein hydrous alkali sulfide is dried by fluidized bed spray granulation.
摘要翻译: 一种生产无水碱硫化物的方法和装置,其中含水碱硫化物通过流化床喷雾造粒干燥。
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公开(公告)号:US06582675B2
公开(公告)日:2003-06-24
申请号:US09813934
申请日:2001-03-22
申请人: Alfred Alig
发明人: Alfred Alig
IPC分类号: C01B1722
CPC分类号: C01B17/38
摘要: A method of preparing anhydrous sodium sulfide having an Na2S content of at least 98 wt %, by drying hydrous sodium sulfide having a water content of 35 to 45%, provided as a solid or in liquefied form, by intensively kneading and mixing hydrated sodium sulfide at an elevated temperature and pressure to thereby liquify said hydrated sodium sulfide and obtain the anhydrous sodium sulfide.
摘要翻译: 通过将水分含量为35〜45%的含水硫化钠作为固体或液化形式,通过将水合硫化钠强烈混合并混合而制备NaS 2 S含量为至少98wt%的无水硫化钠的方法 在升高的温度和压力下,使所述水合硫化钠液化,得到无水硫化钠。
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公开(公告)号:US06423859B1
公开(公告)日:2002-07-23
申请号:US09903858
申请日:2001-07-13
申请人: Alfred Alig , Christoph Batz-Sohn , Ulrich Deschler , Rudolf Michel , Jörg Münzenberg , Raymund Sonnenschein , Werner Will , Gerd Rainhard Zezulka , Karl-Heinz Rützel
发明人: Alfred Alig , Christoph Batz-Sohn , Ulrich Deschler , Rudolf Michel , Jörg Münzenberg , Raymund Sonnenschein , Werner Will , Gerd Rainhard Zezulka , Karl-Heinz Rützel
IPC分类号: C07R708
CPC分类号: C07F7/1892
摘要: The invention relates to a process for the preparation of organosilylalkylpolysulfanes, of the general formula I (R1R2R3SiR4)2Sx (I) by reaction of organosilylalkylpolysulfanes of the general formula II (R1R2R3SiR4)2Sy (II) with an ionic sulfide of the general formula M+2S2− (III) and an organosilylalkyl halide of the general formula R1R2R3SiR4X (IV), the long-chain organosilylalkylpolysulfane of the general formula (II) and the organosilylalkyl halide of the general formula (IV) being initially introduced into the reaction vessel and the ionic sulfide of the general formula (III) being added to this solution in several portions.
摘要翻译: 本发明涉及制备通式Ⅰ(R1R2R3SiR4)2Sx(Ⅰ)的有机甲硅烷基烷基聚硫烷的方法,通过使通式II(R1R2R3SiR4)2Sy(Ⅱ)的有机甲硅烷基烷基聚硫与通式M + 2SII(III)和通式为R 1 R 2 R 3 SiR 4 X(IV)的有机甲硅烷基烷基卤化物,通式(II)的长链有机甲硅烷基烷基聚
硫烷和通式(IV)的有机甲硅烷基烷基卤化物最初引入反应容器中, 将通式(III)的离子性硫化物分几部分加入到该溶液中。
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