摘要:
A device for the thermal decomposition of a volatile compound, and for deposition of particles which are formed by the decomposition, includes (a) a pressure vessel, (b) at least one reaction tube located inside the pressure vessel such that, an open end of the reaction tube extends into the pressure vessel and an other end of the reaction tube is located outside the pressure vessel and is provided with a gas feed, wherein a longitudinal axis of the reaction tube is oriented in the direction of gravity and parallel to a longitudinal axis of the pressure vessel and wherein the reaction tube can be heated on a gas inlet side and cooled on a gas outlet side, wherein the pressure vessel, in its lower part, comprises a collection cone, wherein the open end of the at least one reaction tube extends into a gas space of the collection cone, wherein the collection cone is connected to an outlet lock for particles, and (c) a gas outlet unit located mainly inside the pressure vessel, the gas outlet unit comprising a gas guide, a gas inlet region, wherein the gas inlet region is in communication with the gas space of the collection cone, a filter system, and a gas outlet, which is located outside the pressure vessel.
摘要:
The present invention relates to a device, to the use thereof, and to a method for the substantially energy-independent continuous production of chlorosilanes, particularly for the production of trichlorosilane as an intermediate product for yielding high-purity silicon.
摘要:
The invention relates to a method for the treatment of a composition containing inorganic silanes and at least one foreign metal and/or a compound containing a foreign metal, wherein the composition is brought in contact with at least one adsorption agent, and for obtaining the composition, in which the content of foreign metal and/or of a compound containing a foreign metal is reduced, and to a corresponding composition having a reduced foreign metal content, and further to the use of organic resins, activated carbons, silicates, and/or zeolites for the reduction of foreign metals and/or compounds containing foreign metals in compositions of inorganic silanes.
摘要:
The invention relates to an apparatus, for preparing silanes of the general formula HnSiCl4-n where n=1, 2, 3 and/or 4 by dismutation of at least one relatively highly chlorinated silane in the presence of a catalyst, which is based on at least one distillation column (1) having a column bottom (1.1) and a column top (1.2), at least one side reactor (2) with catalyst bed (3), at least one feed inlet (1.3), a product offtake (1.4) and at least one further product offtake (1.5 or 1.8), where the distillation column (1) is provided with at least one chimney tray (4) and at least one side reactor (2) is connected to the distillation column (1) via at least three pipes (5, 6, 7) in such a way that the connection point of the line (5) to the distillation column (1) for the discharge of the condensate from the chimney tray (4, 4.1) is at a higher level than the upper edge of the catalyst bed (3, 3.1 or 3.2), the line (6) for the discharge of the liquid phase from the side reactor (2) opens (6.1) into the distillation column (1) below the chimney tray (4) and this opening (6, 6.1) is at a lower level than the upper edge of the catalyst bed (3, 3.1 or 3.2) and the line (7) for the discharge of the gas phase from the associated side reactor (2) opens (7.1) into the distillation column (1) above the level (4.1) of the chimney tray (4). Furthermore, the present invention provides a process for preparing said silanes in the apparatus of the invention.
摘要:
Compacting device for the low-metal compaction of a powder with a casing which at least in part surrounds a working chamber, with a feed arrangement arranged on the casing and feeding a powder, which is to be compacted, into the working chamber, with at least a compacting roller which is rotatably arranged in the working chamber, comprises a roller jacket and, together with an opposing wall, forms a compacting gap for compacting the powder therein, characterised in that the at least one compacting roller consists of ceramic, at least on the roller jacket.
摘要:
The invention relates to a process for the preparation of organosilylalkylpolysulfanes, of the general formula I (R1R2R3SiR4)2Sx (I) by reaction of organosilylalkylpolysulfanes of the general formula II (R1R2R3SiR4)2Sy (II) with an ionic sulfide of the general formula M+2S2− (III) and an organosilylalkyl halide of the general formula R1R2R3SiR4X (IV), the long-chain organosilylalkylpolysulfane of the general formula (II) and the organosilylalkyl halide of the general formula (IV) being initially introduced into the reaction vessel and the ionic sulfide of the general formula (III) being added to this solution in several portions.
摘要翻译:本发明涉及制备通式Ⅰ(R1R2R3SiR4)2Sx(Ⅰ)的有机甲硅烷基烷基聚硫烷的方法,通过使通式II(R1R2R3SiR4)2Sy(Ⅱ)的有机甲硅烷基烷基聚硫与通式M + 2SII(III)和通式为R 1 R 2 R 3 SiR 4 X(IV)的有机甲硅烷基烷基卤化物,通式(II)的长链有机甲硅烷基烷基聚 硫烷和通式(IV)的有机甲硅烷基烷基卤化物最初引入反应容器中, 将通式(III)的离子性硫化物分几部分加入到该溶液中。
摘要:
A process for continuous production of methyl mercaptan by catalytic reaction of methanol and hydrogen sulfide. Significant improvements in the pretreatment of the feed gas mixture and in utilization of the heat of reaction and the heat content of the product gas mixture. The energy required to vaporize the methanol is derived partly from utilization of the heat of compression of the hydrogen sulfide gas and from the heat content of the product gas leaving the reactor. The heat of reaction is utilized to heat the feed gas mixture to the reaction temperature, with the help of an external gas heater.
摘要:
A process for separating the product gas mixture from the catalytic synthesis of methyl mercaptan. Because of improved separation of the product gas mixture into its components, less hydrogen sulfide and methyl mercaptan are lost in discharging the inert gases than in the known process. The inert gases can be burned without after-treatment of the exhaust gas. Likewise, the process water that is discharged is less contaminated with polysulfides.
摘要:
In a reactor for the decomposition of a silicon-containing gas, provision is made, to avoid silicon deposition on an inner wall of a reactor vessel, for at least one catalytically active mesh to be provided within a reaction chamber between at least one gas feed line and the inner wall (4). The mesh accelerates the thermal decomposition of the gas and reduces the deposition of silicon on the inner wall. Also described is a process for the preparation of silicon using the reactor according to the invention and the use in photovoltaics of the silicon prepared.
摘要:
The present invention relates to a process for producing silicon by thermal decomposition of a gaseous mixture comprising monosilane, monochlorosilane and, if desired, further chlorosilanes, e.g. dichlorosilane.