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1.发明授权Process for the preparation of isocyanate derivatives of aliphatic, cycloaliphatic, and araliphatic compounds 失效制备脂族，脂环族和芳脂族化合物的异氰酸酯衍生物的方法
公开(公告)号：US4238404A
公开(公告)日：1980-12-09
申请号：US040375
申请日：1979-05-18
申请人： Hans Zengel , Manfred Bergfeld , Rainer Zielke , Erich Klimesch
发明人： Hans Zengel , Manfred Bergfeld , Rainer Zielke , Erich Klimesch
IPC分类号： C07C265/00 , C07C67/00 , C07C241/00 , C07C263/12 , C07C265/04 , C07C275/06 , C07C118/04
CPC分类号： C07C263/12 , C07C273/1845 , C07C2101/14
摘要： A process for the preparation of derivatives of aliphatic, cycloaliphatic, and araliphatic compounds containing from 1 to 3 isocyanate groups bonded to from 1 to 3 secondary or tertiary carbon atoms, or a combination thereof, is disclosed. The process comprises reacting a compound of the formula R--(CO--NHCl).sub.n, wherein R represents an aliphatic, cycloaliphatic, or araliphatic radical, with a tertiary amine having a pK.sub.a greater than 7, at a temperature from about 20.degree. to about 180.degree. C., in an inert solvent, to form a compound of the formula R--(N.dbd.C.dbd.O).sub.n, wherein the isocyanate groups are bonded to secondary or tertiary carbon atoms.
摘要翻译： 公开了制备含有1至3个仲或叔碳原子的1至3个异氰酸酯基的脂族，脂环族和芳脂族化合物的衍生物的方法或其组合。 该方法包括使式R-（CO-NHCl）n的化合物（其中R表示脂族，脂环族或芳脂族基团）与pKa大于7的叔胺在约20°至约 180℃，在惰性溶剂中，形成式R-（N = C = O）n的化合物，其中异氰酸酯基团键合到仲或叔碳原子上。
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公开(公告)号：US4301257A
公开(公告)日：1981-11-17
申请号：US129878
申请日：1980-03-13
申请人： Hans Zengel , Rainer Zielke , Manfred Bergfeld
发明人： Hans Zengel , Rainer Zielke , Manfred Bergfeld
CPC分类号： C08F8/32 , C08F2800/20 , C08F2810/20
摘要： This invention relates to a polyfunctional isocyanate which is an acrylamide or methacrylamide homopolymer or interpolymer having 20 to 100% of its secondary .alpha. and tertiary .alpha. carbon atom amide groups converted to isocyanate groups, said polyfunctional isocyanate being free of alkali and urea groups.The polyfunctional isocyanates are prepared by reacting the N-chloramide derivative of the acrylamide or methacrylamide polymer, in an inert solvent, with a tertiary amine having a pK.sub.a value of more than 7.The polyfunctional isocyanates are useful for forming coating compositions.
摘要翻译： 本发明涉及多官能异氰酸酯，其是丙烯酰胺或甲基丙烯酰胺均聚物或互聚物，其具有转化成异氰酸酯基团的二级α-和叔碳原子酰胺基团的20至100％，所述多官能异氰酸酯不含碱和脲基团。 多官能异氰酸酯可以通过使丙烯酰胺或甲基丙烯酰胺聚合物的N-氯酰胺衍生物在惰性溶剂中与pKa值大于7的叔胺反应来制备。多官能异氰酸酯可用于形成涂料组合物。
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3.发明授权
公开(公告)号：US4356289A
公开(公告)日：1982-10-26
申请号：US223720
申请日：1981-01-09
IPC分类号： C08F8/22
CPC分类号： C08F8/22
摘要： A process is disclosed for making polyfunctional N-chloramide derivatives of homo--or copolymers of acrylamide or metharylamide wherein a homo--or copolymer of acrylamide or methacrylamide is chlorinated by means of chloride in a dilute aqueous suspension of a mineral acid at a temperature of 0.degree. to 40.degree. C.
摘要翻译： 公开了一种制备丙烯酰胺或甲基丙烯酰胺的均聚或共聚物的多官能N-氯酰胺衍生物的方法，其中丙烯酰胺或甲基丙烯酰胺的均聚物或共聚物通过氯化物在无机酸的稀无水悬浮液中在0℃的温度下氯化 DEG至40℃
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公开(公告)号：US4357447A
公开(公告)日：1982-11-02
申请号：US131368
申请日：1980-03-18
CPC分类号： C08F8/22
摘要： Polyfunctional N-chloramide derivatives of homo-or copolymers of acrylamide or methacrylamide. These may be copolymers of methacrylamide and acrylamide; or of either of these with any of styrene, methylstyrene, dimethylstyrene, chlorostyrene and alkylacrylate. Preferred alkylacrylate include methyl-, methylmeth-, ethyl-, ethylmethyl-, butylmeth-, hexyl-, hexylmeth-, decyl-, decylmeth-, dodecyl- and dodecylmeth- species. The derivatives may be cross-linked by divinylbenzene or divinylether.
摘要翻译： 丙烯酰胺或甲基丙烯酰胺的均聚或共聚物的多官能N-氯酰胺衍生物。 这些可以是甲基丙烯酰胺和丙烯酰胺的共聚物; 或其中任一种与苯乙烯，甲基苯乙烯，二甲基苯乙烯，氯苯乙烯和丙烯酸烷基酯中的任一种。 优选的丙烯酸烷基酯包括甲基，甲基甲基，乙基 - ，乙基甲基 - ，丁基甲基 - ，己基 - ，己基甲基 - ，癸基 - ，癸基甲基 - ，十二烷基和十二烷基甲基。 衍生物可以通过二乙烯基苯或二乙烯基醚交联。
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公开(公告)号：US4346233A
公开(公告)日：1982-08-24
申请号：US249536
申请日：1981-03-31
IPC分类号： C07C275/24 , C07C273/18 , C07D233/74 , C07C127/15
CPC分类号： C07D233/74 , C07C273/1809 , C07C273/1845
摘要： This disclosure relates to a process for preparing long-chain hydrocarbon substituted ureas by reacting a long chain fatty acid N-chloramide in isopropanol and/or tertiary butanol with an aliphatic or araliphatic primary or secondary amine in the presence of an alkali or alkaline earth hydroxide at a temperature of from 20.degree. to 100.degree. C. The process of this disclosure is particularly useful in preparing long-chain hydrocarbon substituted ureas wherein one of the aliphatic hydrocarbon substituents contains one or more hydroxyl and/or carboxyl groups, as well as the salts of such substituted ureas.
摘要翻译： 本公开涉及通过使长链脂肪酸N-氯酰胺在异丙醇和/或叔丁醇中与脂肪族或芳脂族伯胺或仲胺在碱金属或碱土金属氢氧化物存在下反应制备长链烃取代的脲的方法 本公开的方法特别可用于制备长链烃取代的脲，其中一个脂族烃取代基含有一个或多个羟基和/或羧基，以及 这种取代脲的盐。
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公开(公告)号：US4056400A
公开(公告)日：1977-11-01
申请号：US599364
申请日：1975-07-28
摘要： A composition which consists essentially of a mixture of oligomeric and polymeric oxidation products of cellulose, hemicellulose and lignin containing carboxy, ether and hydroxy groups as obtained by the direct oxidation of a woody plant material, preferably in an aqueous suspension thereof, using alkali hypohalite in a one stage oxidation procedure or nitrogen dioxide, alkali periodate or lead tetraacetate followed by alkali chlorite or alkali hypochlorite in a two stage oxidation procedure. The resulting oxidation products as obtained by one of these specific processes are especially valuable as additives to a surface active detergent or cleaning agent.
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公开(公告)号：US4296260A
公开(公告)日：1981-10-20
申请号：US64691
申请日：1979-08-08
申请人： Rainer Zielke , Helmut Maegerlein
发明人： Rainer Zielke , Helmut Maegerlein
IPC分类号： C07C27/00 , C07C37/055 , C07C39/10 , C07C41/34 , C07C43/225 , C07C67/00 , C07C37/01
CPC分类号： C07C43/225 , C07C37/055 , C07C41/16 , C07C41/24
摘要： A process for the preparation of phloroglucinol is disclosed. The process comprises reacting hexachlorobenzene with sodium propylate or sodium isopropylate, in a molar ratio of from about 1:3 to about 1:20, in an aprotic solvent, at a temperature from about 50 to about 250.degree. C., to form trichlorophloroglucinol tripropylether, or trichlorophloroglucinol triisopropylether. The latter compounds are dechlorinated to form phloroglucinol tripropylether or phloroglucinol triisopropylether, with the use of metallic sodium, and subsequently hydrolyzed to form phloroglucinol.
摘要翻译： 公开了一种制备间苯三酚的方法。 该方法包括在约50至约250℃的温度下，将六氯苯与丙酸钠或异丙醇钠以约1:3至约1:20的摩尔比反应，形成三氯酚三 ，或三氯间苯三醇三异丙醚。 后一种化合物被脱氯以形成间苯三酚三丙醚或间苯三酚三异丙醚，使用金属钠，随后水解形成间苯三酚。
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