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1.发明授权
公开(公告)号：US4356289A
公开(公告)日：1982-10-26
申请号：US223720
申请日：1981-01-09
IPC分类号： C08F8/22
CPC分类号： C08F8/22
摘要： A process is disclosed for making polyfunctional N-chloramide derivatives of homo--or copolymers of acrylamide or metharylamide wherein a homo--or copolymer of acrylamide or methacrylamide is chlorinated by means of chloride in a dilute aqueous suspension of a mineral acid at a temperature of 0.degree. to 40.degree. C.
摘要翻译： 公开了一种制备丙烯酰胺或甲基丙烯酰胺的均聚或共聚物的多官能N-氯酰胺衍生物的方法，其中丙烯酰胺或甲基丙烯酰胺的均聚物或共聚物通过氯化物在无机酸的稀无水悬浮液中在0℃的温度下氯化 DEG至40℃
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2.发明授权Mixture hardening under the influence of air moisture and a process for production of polyisocyanate-poly-addition products or of cross-linked polyepoxides 失效在空气湿度的影响下的混合物硬化和生产多异氰酸酯 - 聚加成产物或交联聚环氧化物的方法
公开(公告)号：US4289869A
公开(公告)日：1981-09-15
申请号：US152368
申请日：1980-05-22
IPC分类号： C08G18/00 , C08G18/18 , C08G18/20 , C08G18/30 , C08G18/32 , C08G18/64 , C08G59/00 , C08G59/40 , C08G59/50 , C08G59/52 , C08G59/64 , C08G59/18
CPC分类号： C08G59/5073 , C08G18/3256 , C08G18/6415 , C08G59/52 , C08G59/64
摘要： Mixtures hardenable under the influence of air moisture are provided. They comprise at least one organic polyisocyanate or an polyepoxide and as a moisture activated hardener an N,N'-substituted imidazolidine derivative or an N,N'-substituted hexahydropyrimidine derivative, which show at no nitrogen atom a --CO--NH-- grouping and which are present in sufficient amount to provide for cross-linking. The mixtures for example provide lacquers and adhesives having various touch dry times.
摘要翻译： 提供在空气湿度影响下可硬化的混合物。 它们包含至少一种有机多异氰酸酯或聚环氧化物，并且作为水分活化的固化剂，N，N'-取代的咪唑烷衍生物或N，N'-取代的六氢嘧啶衍生物，其在无氮原子上表示-CO-NH-基团， 它们以足够的量存在以提供交联。 混合物例如提供具有各种触摸干燥时间的漆和粘合剂。
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公开(公告)号：US4342707A
公开(公告)日：1982-08-03
申请号：US947795
申请日：1978-10-02
IPC分类号： C07C231/00 , C07C67/00 , C07C231/08 , C07C233/12 , C07C239/06 , C07C51/58
CPC分类号： C07C233/12
摘要： Bis-N-chloramides of saturated aliphatic dicarboxylic acids are prepared by chlorinating a saturated aliphatic dicarboxylic diamide, the aliphatic residue of which has 4 to 40 carbon atoms, in an aqueous inorganic acid medium, at a temperature between 0.degree. and 40.degree. C.; the chlorination is advantageously carried out in presence of an inorganic salt.
摘要翻译： 饱和脂肪族二羧酸的双-N-氯酰胺通过在0〜40℃的温度下，在无机酸水溶液中氯化饱和脂肪族二羧酸二酰胺（脂肪族残基为4〜40个碳原子）来制备。 ; 氯化有利地在无机盐的存在下进行。
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公开(公告)号：US4699841A
公开(公告)日：1987-10-13
申请号：US832582
申请日：1986-02-24
IPC分类号： B32B15/08 , B32B15/088 , B32B15/092 , B32B27/00 , B32B27/28 , B32B27/34 , C08J5/12 , H05K1/03
CPC分类号： H05K1/036 , B32B27/28 , H05K2201/0154 , H05K2201/0358 , H05K2203/066 , Y10T428/26 , Y10T428/2826 , Y10T428/294 , Y10T428/2947 , Y10T428/3154 , Y10T428/31721
摘要： A multilayer laminate having at least one layer of a no longer formable fully aromatic polyimide and at least one layer of substrate material, the layer of no longer formable polyimide adhering directly on one side to the layer of substrate material with a peel strength of at least 4.0 N/cm. The layer of no longer also formable polyimide is also insoluble in phenolic solvents, has a tensile strength of from 100 to 150 N/mm.sup.2, a breaking elongation of from 15 to 100%, a dielectric dissipation factor of from 1.5.times.10.sup.-3 to 5.times.10.sup.-3 at 1 kHz. Additionally, a layer of heat-sealable high-temperature adhesive selected from the class of polyacrylates, polysulfone resins, epoxy resins, fluoropolymer resins, silicone resins or butyl rubbers is joined to that side of the polyimide layer which is remote from the substrate material.
摘要翻译： 具有至少一层不可成形的完全芳香族聚酰亚胺和至少一层基材的多层层压体，不可再生成的聚酰亚胺层直接粘在基材材料层上，剥离强度至少为 4.0 N / cm。 不再是可成型聚酰亚胺的层也不溶于酚类溶剂，拉伸强度为100〜150N / mm2，断裂伸长率为15〜100％，介电损耗因数为1.5×10 -3〜5×10 -3，1 kHz。 此外，选自聚丙烯酸酯类，聚砜树脂，环氧树脂，含氟聚合物树脂，有机硅树脂或丁基橡胶的一类可热封的高温粘合剂被接合到远离基材的聚酰亚胺层的那一侧。
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公开(公告)号：US4558135A
公开(公告)日：1985-12-10
申请号：US324181
申请日：1981-11-23
IPC分类号： C07D277/20 , B01J31/26 , C07D277/36 , C07D277/78 , C07D277/70
CPC分类号： C07D277/78
摘要： A process for the preparation of dithiazolyl disulfides by the catalytic oxidation of a 2-mercaptothiazole with ammonia and either oxygen or an oxygen-containing gas at a temperature of between 0.degree. and 150.degree. C.
摘要翻译： 通过在0℃至150℃的温度下，用氨和氧气或含氧气体催化氧化2-巯基噻唑来制备二噻唑基二硫化物的方法。
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公开(公告)号：US4437960A
公开(公告)日：1984-03-20
申请号：US329562
申请日：1981-12-10
CPC分类号： C09D5/4453 , C08G59/38 , C08G59/4035 , C08G59/44 , C08G59/46 , C09D5/4403 , Y10T428/31529 , Y10T428/31678
摘要： Method for the crosslinking of cathodically depositable coating agents, optionally containing pigment, dyestuff, filler, solvent, varnish adjuvant or additional crosslinking components, based upon a water-soluble or -dispersible nitrogen based cationic resin, at least partially present as salt, in which a cationic resin of molecular weight greater than 1000, containing 2 to 20 equivalents of double bonds per 1000 g, is contacted with sulfur and/or one or more sulfur-containing vulcanization acceleration. The coating mixture is then electrophoretically deposited upon an object, and hardened at temperatures above 120.degree. C. The resin may contain tertiary atoms of carbon, and also one or more sulfur-free vulcanization accelerators may be used. The resin is a reaction product of at least (A) one epoxidized polydiene and/or (B) one bisglicydylether of a polyphenol and (C) one amide compound formed from one or more higher, essentially unsaturated fatty acids and a polyamine, and can contain a ketimino or hydroxyl group, and/or (D) one hydrazide compound, which contains tertiary amino groups, and if necessary (E) one organic secondary amine, and has been made with an acid under formation of cationic groups dispersible in water. The invention also encompasses hardened coatings obtained according to this method.
摘要翻译： 基于至少部分以盐形式存在的水溶性或可分散的基于氮的阳离子树脂交联阴极可沉积的涂层剂，任选地含有颜料，染料，填料，溶剂，清漆助剂或其它交联组分的方法，其中 分子量大于1000的阳离子树脂，每1000克含有2至20当量的双键，与硫和/或一种或多种含硫硫化加速剂接触。 然后将涂料混合物电泳沉积在物体上，并在高于120℃的温度下硬化。树脂可以含有碳原子，也可以使用一种或多种无硫硫化促进剂。 树脂是至少（A）一种环氧化聚二烯和/或（B）一种多酚的双羟基乙醚和（C）一种由一种或多种更高，基本上不饱和的脂肪酸和多胺形成的酰胺化合物的反应产物，并且可以 含有酮亚胺基或羟基的化合物，和/或（D）含有叔氨基的一个酰肼化合物，如果需要（E）一种有机仲胺，并且在酸形成时可以分散在水中形成阳离子基团。 本发明还包括根据该方法获得的硬化涂层。
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公开(公告)号：US4393238A
公开(公告)日：1983-07-12
申请号：US265321
申请日：1981-05-18
IPC分类号： C07C271/60 , B01J23/02 , B01J23/04 , C07B61/00 , C08G18/70 , C07C131/00
CPC分类号： C08G18/701
摘要： Blocked isocyanates of the general formula ##STR1## are obtained by converting terephthalic dialdoxime, isophthalic dialdoxime or an aliphatic, cycloaliphatic or aromatic ketoxime or an aromatic aldoxime of the general formula ##STR2## in the presence of 10-100 Mol % sodium, potassium or calcium hydroxide, with the sodium, potassium or calcium salt of a bis-N-chloramide of the general formulaCl-NH-CO-R-CO-NH-Clin water or a mixture of water and an aprotic solvent. Preferred first components include terephthalic dialdoxime, benzaldehyde-, cyclohexanone-, acetone- and acetophenoneoxime. Preferred aprotic solvents include dimethyl acetamide, dimethylformamide, sulfolan and tetramethylurea.
摘要翻译： 通过在10-100Mol％钠，钾或钾的存在下，将对苯二甲酸二肟，间苯二甲酸二肟或脂肪族，脂环族或芳族酮肟或芳族肟基转化为通式“IMAGE”，得到通式“IMAGE”的封闭异氰酸酯， 氢氧化钙与通式为Cl-NH-CO-R-CO-NH-Cl的双-N-氯酰胺的钠，钾或钙盐在水中或水和非质子溶剂的混合物中。 优选的第一组分包括对苯二甲酸二肟，苯甲醛，环己酮，丙酮和苯乙酮肟。 优选的非质子溶剂包括二甲基乙酰胺，二甲基甲酰胺，环丁砜和四甲基脲。
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公开(公告)号：US4316031A
公开(公告)日：1982-02-16
申请号：US23986
申请日：1979-03-26
IPC分类号： C07D277/72
CPC分类号： C07D277/72
摘要： A process for the preparation of 2-mercaptobenzothiazole is disclosed. The process comprises heating a reaction mixture comprising nitrosobenzene, hydrogen sulfide and carbon disulfide in a molar ratio of about 1:1.5 to 4:1 to 3, respectively, to a temperature from about 200 to about 300.degree. C., for a time sufficient to convert at least a portion of the reactants into 2-mercaptobenzothiazole. In an alternative process, there is first reacted nitrosobenzene with hydrogen sulfide in a molar ratio of about 1:1.5 to 4, at a temperature from about 20 to about 100.degree. C. for a period of time sufficient to substantially reduce the nitrosobenzene, and subsequently reacting the resulting product mixture with from about 1 to about 3 mole equivalents of carbon disulfide per mole of originally charged nitrosobenzene, at a temperature from about 200.degree. C. to about 300.degree. C.
摘要翻译： 公开了制备2-巯基苯并噻唑的方法。 该方法包括将包含亚甲基苯，硫化氢和二硫化碳的反应混合物以约1:1.5至4:1至3的摩尔比加热至约200至约300℃的温度持续足够的时间 将至少一部分反应物转化为2-巯基苯并噻唑。 在另一种方法中，首先使反应的亚硝基苯与摩尔比为约1:1.5至4的硫化氢在约20至约100℃的温度下反应一段足以显着降低亚硝基苯的时间，以及 随后在约200℃至约300℃的温度下使得到的产物混合物与每摩尔初始加入的亚硝基苯约1至约3摩尔当量的二硫化碳反应。
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公开(公告)号：US4259258A
公开(公告)日：1981-03-31
申请号：US928118
申请日：1978-07-26
IPC分类号： C07C231/00 , C07C20060101 , C07C67/00 , C07C231/08 , C07C233/59 , C07C233/66 , C07C239/06 , C07C313/00 , C07C315/04 , C07C317/44 , C07C103/737
CPC分类号： C07C233/12
摘要： Novel Bis-N-chloramides of aromatic dicarboxylic acids, such as alkyl-isophthalic or alkyl terephthalic acid, or of cycloaliphatic dicarboxylic acids such as cyclohexane dicarboxylic acid, are obtained by chlorinating the corresponding diamides, in an aqueous acid medium at a temperature of about 0.degree. to 40.degree. C.
摘要翻译： 芳族二羧酸的新型二-N-氯酰胺，例如烷基间苯二甲酸或烷基对苯二甲酸，或脂环族二羧酸如环己烷二羧酸，是通过在含水酸性介质中在约 0〜40℃
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公开(公告)号：US4783572A
公开(公告)日：1988-11-08
申请号：US836984
申请日：1986-03-06
IPC分类号： B01J23/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C2/84 , C07C9/06 , C07C11/04 , C07C67/00 , C07C2/00
CPC分类号： C07C2/84 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/14 , C07C2523/34 , C07C2527/224 , Y02P20/52 , Y10S585/943
摘要： A process for the preparation of ethane and ethylene by oxidation of methane with oxygen at a temperature of 600.degree. to 900.degree. C., in which lead (II) oxide is used as catalyst (a) dispersed on a carrier of pumice, silicon carbide, zinc oxide, zirconium dioxide, and/or oxides of alkaline-earth elements, or (b) in a mixture with manganese (II) oxide dispersed on a carrier of pumice, silicon carbide, silicon dioxide, titanium dioxide, zirconium dioxide, zinc oxide, and/or oxides of alkaline-earth elements, or (c) without a carrier in a mixture with sodium silicate alone or in combination with silicon dioxide, titanium dioxide, zirconium dioxide, manganese (II) oxide, zinc oxide, and/or oxides of alkaline-earth elements. Ethane and ethylene are obtained with this process in high selectivities with good catalyst activities.
摘要翻译： 一种通过在600℃至900℃的温度下用氧气氧化甲烷和乙烯的方法，其中使用氧化铅（II）作为分散在浮石载体上的催化剂（a），碳化硅 ，氧化锌，二氧化锆和/或碱土金属的氧化物，或（b）与分散在浮石载体上的氧化锰（II）的混合物，碳化硅，二氧化硅，二氧化钛，二氧化锆，锌 氧化物和/或碱土元素的氧化物，或（c）不含与硅酸钠的混合物中的载体，或与二氧化硅，二氧化钛，二氧化锆，氧化锰（II），氧化锌和/ 或碱土元素的氧化物。 乙酸和乙烯通过该方法以高选择性获得，具有良好的催化剂活性。
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