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1.发明授权Aqueous isocyanate emulsions and their use as binders in a process for the production of shaped articles 失效水性异氰酸酯乳液及其在成型制品生产过程中作为粘合剂的用途
公开(公告)号：US4576771A
公开(公告)日：1986-03-18
申请号：US641801
申请日：1984-08-17
CPC分类号： C08G18/706 , C08L97/02 , C08L75/04 , Y10T428/253
摘要： The present invention relates to aqueous isocyanate emulsions and their use as binders in the production of shaped articles. These emulsions contain(A) from 80 to 20% by weight, based on the total emulsion, of water;(B) from 18 to 79% by weight, based on the total emulsion, of an organic polyisocyanate;(C) from 0.5 to 15% by weight, based on the total emulsion of a sulfonic acid corresponding to the formula:R.sub.1 --SO.sub.3 H).sub.n whereinn represents the integers 1 or 2, andR.sub.1 represents an aromatic hydrocarbon radical containing from 6 to 14 carbon atoms, an aliphatic hydrocarbon radical containing from 10 to 18 carbon atoms, a cyclo-aliphatic hydrocarbon radical containing from 6 to 15 carbon atoms, an araliphatic hydrocarbon radical containing from 7 to 15 carbon atoms or an alkaromatic hydrocarbon radical containing from 7 to 24 carbon atoms; and(D) from 0 to 10% by weight, based on the polyisocyanate, of a nonionic, surface-active agent as an emulsifier.
摘要翻译： 本发明涉及异氰酸酯水乳液及其在成型制品生产中作为粘合剂的用途。 这些乳液含有（A）基于总乳液80至20重量％的水; （B）有机多异氰酸酯为18至79重量％，基于总乳液; （C）0.5至15重量％，基于对应于下式的R 1 -SO 3 H）n的磺酸的总乳液，其中n表示整数1或2，并且R 1表示芳族烃基，其含有6至 14个碳原子，含有10至18个碳原子的脂族烃基，含有6至15个碳原子的环脂族烃基，含有7至15个碳原子的芳脂族烃基或含有7至 24个碳原子; 和（D）基于多异氰酸酯0至10重量％的非离子表面活性剂作为乳化剂。
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2.发明授权Aqueous isocyanate emulsions and their use as binders in a process for the production of shaped articles 失效水性异氰酸酯乳液及其在成型制品生产过程中作为粘合剂的用途
公开(公告)号：US4528117A
公开(公告)日：1985-07-09
申请号：US150488
申请日：1980-05-16
CPC分类号： C08G18/706 , C08L97/02 , C08L75/04 , Y10T428/253
摘要： The present invention relates to aqueous isocyanate emulsions and their use as binders in the production of shaped articles. These emulsions contain(A) from 80 to 20% by weight, based on the total emulsion, of water;(B) from 18 to 79% by weight, based on the total emulsion, of an organic polyisocyanate;(C) from 0.5 to 15% by weight, based on the total emulsion of a sulfonic acid corresponding to the formula:R.sub.1 --SO.sub.3 H).sub.nwhereinn represents the integers 1 or 2, andR.sub.1 represents an aromatic hydrocarbon radical containing from 6 to 14 carbon atoms, an aliphatic hydrocarbon radical containing from 10 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical containing from 6 to 15 carbon atoms, an araliphatic hydrocarbon radical containing from 7 to 15 carbon atoms or an alkaromatic hydrocarbon radical containing from 7 to 24 carbon atoms; and(D) from 0 to 10% by weight, based on the polyisocyanate, of a nonionic, surface-active agent as an emulsifier.
摘要翻译： 本发明涉及异氰酸酯水乳液及其在成型制品生产中作为粘合剂的用途。 这些乳液含有（A）基于总乳液80至20重量％的水; （B）有机多异氰酸酯为18至79重量％，基于总乳液; （C）0.5至15重量％，基于对应于下式的R 1 -SO 3 H）n的磺酸的总乳液，其中n表示整数1或2，并且R 1表示含有6至 含有10至18个碳原子的脂族烃基，含有6至15个碳原子的脂环族烃基，含有7至15个碳原子的芳脂族烃基或含有7至24个碳原子的烷基烃基 原子 和（D）基于多异氰酸酯0至10重量％的非离子表面活性剂作为乳化剂。
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3.发明授权Process for producing molded particulate articles utilizing a self-releasing binder based on a sulfonic acid modified isocyanate 失效利用基于磺酸改性的异氰酸酯的自释放粘合剂来生产模塑颗粒制品的方法
公开(公告)号：US4528153A
公开(公告)日：1985-07-09
申请号：US422407
申请日：1982-09-20
申请人： Hans-Joachim Scholl , Hanns I. Sachs , Gert Jabs , Gunther Loew
发明人： Hans-Joachim Scholl , Hanns I. Sachs , Gert Jabs , Gunther Loew
IPC分类号： C08G18/00 , C08G18/30 , C08G18/70 , C08G18/72 , C08K5/41 , C08K5/42 , C08L75/00 , C08L75/04 , C08L97/02 , B29J5/02
CPC分类号： C08G18/72 , C08G18/70 , C08L97/02 , C08G2125/00
摘要： The present invention relates to a substantially anhydrous binder having a self-releasing effect for the production of pressed articles comprising:(A) a polyisocyanate; and(B) a sulfonic acid corresponding to the general formula:R--SO.sub.3 H).sub.n whereinn represents an integer of 1 or 2;R represents an aromatic hydrocarbon radical having from 6 to 14 carbon atoms, an aliphatic hydrocarbon radical having from 10 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical having from 6 to 15 carbon atoms, an araliphatic hydrocarbon radical having from 7 to 15 carbon atoms or an alkaromatic hydrocarbon radical having from 7 to 24 carbon atoms; and the equivalent ratio of the components (A) and (B) is 100:0.5 to 100:20.The invention is also directed to the use of such binders in the production of shaped articles by the hot pressing of a wide variety of organic and/or inorganic materials.
摘要翻译： 本发明涉及具有用于生产压制制品的自释放效果的基本上无水的粘合剂，其包含：（A）多异氰酸酯; 和（B）对应于通式R-SO 3 H）的磺酸，其中n表示1或2的整数; R表示具有6至14个碳原子的芳族烃基，具有10至18个碳原子的脂族烃基，具有6至15个碳原子的脂环族烃基，具有7至15个碳原子的芳脂族烃基或 具有7至24个碳原子的烷基烃基; 组分（A）和（B）的当量比为100:0.5至100:20。 本发明还涉及这种粘合剂在通过热压多种有机和/或无机材料的成型制品生产中的用途。
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4.发明授权Self-releasing binder based on isocyanate and the use thereof in a process for the production of molded articles 失效基于异氰酸酯的自释放粘合剂及其在制造模制品的方法中的用途
公开(公告)号：US4478738A
公开(公告)日：1984-10-23
申请号：US150495
申请日：1980-05-16
申请人： Hans-Joachim Scholl , Hanns I. Sachs , Gert Jabs , Gunther Loew
发明人： Hans-Joachim Scholl , Hanns I. Sachs , Gert Jabs , Gunther Loew
IPC分类号： C08G18/00 , C08G18/30 , C08G18/70 , C08G18/72 , C08K5/41 , C08K5/42 , C08L75/00 , C08L75/04 , C08L97/02 , C09K3/00
CPC分类号： C08G18/72 , C08G18/70 , C08L97/02 , C08G2125/00
摘要： The present invention relates to a substantially anhydrous binder having a self-releasing effect for the production of pressed articles comprising:(A) a polyisocyanate; and(B) a sulfonic acid corresponding to the general formula:R--SO.sub.3 H).sub.n whereinn represents an integer of 1 or 2;R represents an aromatic hydrocarbon radical having from 6 to 14 carbon atoms, an aliphatic hydrocarbon radical having from 10 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical having from 6 to 15 carbon atoms, an araliphatic hydrocarbon radical having from 7 to 15 carbon atoms or an alkaromatic hydrocarbon radical having from 7 to 24 carbon atoms; andthe equivalent ratio of the components (A) and (B) is 100:0.5 to 100:20.The invention is also directed to the use of such binders in the production of shaped articles by the hot pressing of a wide variety of organic and/or inorganic materials.
摘要翻译： 本发明涉及具有用于生产压制制品的自释放效果的基本上无水的粘合剂，其包含：（A）多异氰酸酯; 和（B）对应于通式R-SO 3 H）的磺酸，其中n表示1或2的整数; R表示具有6至14个碳原子的芳族烃基，具有10至18个碳原子的脂族烃基，具有6至15个碳原子的脂环族烃基，具有7至15个碳原子的芳脂族烃基或 具有7至24个碳原子的烷基烃基; 组分（A）和（B）的当量比为100:0.5至100:20。 本发明还涉及这种粘合剂在通过热压多种有机和/或无机材料的成型制品生产中的用途。
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5.发明授权Emulsifiers, aqueous isocyanate emulsions containing them and their use as binders in a process for the manufacture of molded articles 失效含有它们的乳化剂，含水异氰酸酯乳液及其在制造模制品的方法中作为粘合剂的用途
公开(公告)号：US4413112A
公开(公告)日：1983-11-01
申请号：US150487
申请日：1980-05-16
申请人： Helmut Reiff , Hanns I. Sachs
发明人： Helmut Reiff , Hanns I. Sachs
CPC分类号： B01F17/005 , C08G18/283 , C08G18/285 , C08G18/288 , C08G18/674 , C08G18/706 , C08L97/02 , Y10S516/01 , Y10S516/07
摘要： This invention relates to new emulsifiers for aqueous isocyanate emulsions and to their use as binders in the production of molded articles, in particular plates, e.g., from materials containing lignocellulose.
摘要翻译： 本发明涉及用于异氰酸酯乳液的新的乳化剂，以及它们在制备模塑制品，特别是例如含有木素纤维素的材料的板材中作为粘合剂的用途。
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6.发明授权Emulsifiers, aqueous isocyanate emulsions containing them and their use as binders in a process for the manufacture of molded articles 失效含有它们的乳化剂，含水异氰酸酯乳液及其在制造模制品的方法中作为粘合剂的用途
公开(公告)号：US4472550A
公开(公告)日：1984-09-18
申请号：US456191
申请日：1983-01-07
申请人： Helmut Reiff , Hanns I. Sachs
发明人： Helmut Reiff , Hanns I. Sachs
IPC分类号： B01F17/00 , B01F17/22 , B01F17/42 , C08G18/28 , C08G18/67 , C08G18/70 , C08L97/02 , C08L75/04
CPC分类号： B01F17/005 , C08G18/283 , C08G18/285 , C08G18/288 , C08G18/674 , C08G18/706 , C08L97/02 , Y10S516/01 , Y10S516/07
摘要： This invention relates to new emulsifiers for aqueous isocyanate emulsions and to their use as binders in the production of molded articles, in particular plates, e.g., from materials containing lignocellulose.
摘要翻译： 本发明涉及用于异氰酸酯乳液的新的乳化剂，以及它们在制备模塑制品，特别是例如含有木素纤维素的材料的板材中作为粘合剂的用途。
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7.发明授权Aqueous glue dispersions containing polyisocyanates, their preparation and use 失效含有多异氰酸酯的水性胶体分散体，其制备和用途
公开(公告)号：US4801631A
公开(公告)日：1989-01-31
申请号：US11648
申请日：1987-02-06
申请人： Hanns I. Sachs , Donald R. Larimer
发明人： Hanns I. Sachs , Donald R. Larimer
CPC分类号： C09J175/00 , C08G18/6484 , C08G18/706 , C08L97/02
摘要： This invention relates to formaldehyde-free, aqueous glue dispersions which contain polyisocyanates. These systems are particularly suitable for gluing veneers and surface materials on wood and wood products. The systems are prepared from polyisocyanates in combination with extenders based on flours and cold water-soluble of hydrolyzed natural starch. In this process, polyisocyanates or aqueous dispersions thereof are added while stirring to aqueous solutions or mixtures of starch and flour.The extender-containing adhesive systems are aqueous glue dispersions having increased service life which in their preferred embodiment contain about 15 to 30% by weight of polyisocyanates, preferably polyphenyl-polymethylene polyisocyanate (PMDI), 10 to 15% by weight of starch which is soluble in cold water and 14 to 25% by weight of (cereal) flour and optionally, other additives and the appropriate quantity of water adding up to 100% by weight. The glue dispersions are easily applied with glue spreading machines and if applied in suitable quantities do not bleed through veneers. The implements used for applying the glues can easily be cleaned by rinsing them with water.The invention is also directed to the use of the glue dispersions for gluing, particularly for gluing veneers or other surface coating materials to wood or wood products.
摘要翻译： 本发明涉及含有多异氰酸酯的无甲醛水性胶体分散体。 这些系统特别适用于在木材和木制品上胶合单板和表面材料。 该系统由多异氰酸酯与基于面粉和水解天然淀粉的冷水溶液的增量剂组合制备。 在此过程中，将多异氰酸酯或其水分散体在搅拌下加入淀粉和面粉的水溶液或混合物中。 含增量剂的粘合剂体系是具有使用寿命延长的水性胶体分散体，在其优选实施方案中含有约15至30重量％的多异氰酸酯，优选聚苯基多亚甲基多异氰酸酯（PMDI），10至15重量％的可溶解淀粉 在冷水和14-25％（重量）的（谷物）面粉和任选的其他添加剂和适量的水加起来达100重量％。 胶水分散体可以很容易地用胶涂布机涂抹，如果适量涂抹，则不会通过胶合板渗出。 用于施加胶水的工具可以通过用水冲洗来容易地清洗。 本发明还涉及胶粘剂分散体用于胶合的用途，特别是用于将胶合板或其它表面涂料材料粘合到木材或木材产品上。
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公开(公告)号：US5179143A
公开(公告)日：1993-01-12
申请号：US835652
申请日：1992-02-13
IPC分类号： C08G18/16 , C08K5/1565 , C08L97/02
CPC分类号： C08K5/1565 , C08G18/168 , C08L97/02
摘要： This invention relates to a process for the preparation of compression molded materials comprising compressing a substrate with a binder based on polyisocyanates, wherein said binder comprises polyisocyanates, compounds containing at least two isocyanate reactive hydrogen atoms, and alkylene carbonates.
摘要翻译： 本发明涉及压缩成型材料的制备方法，其包括用基于多异氰酸酯的粘合剂压缩基材，其中所述粘合剂包括多异氰酸酯，含有至少两个异氰酸酯反应性氢原子的化合物和碳酸亚烷基酯。
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9.发明授权
公开(公告)号：US4510184A
公开(公告)日：1985-04-09
申请号：US436132
申请日：1982-10-22
申请人： Hermann Winkler , Hanns I. Sachs
发明人： Hermann Winkler , Hanns I. Sachs
CPC分类号： B27N1/02
摘要： For achieving optimum application of bonding agent to particulate material, in particular chips, without elaborate plant and machinery, it is proposed to carry out the application of bonding agent using a pneumatic conveyor device for material which is in any case present, by arranging at least one spray nozzle for bonding agent in at least one section of the pipes of the material transport device and spraying the particles which are transported in the form of a film, using this spray nozzle for bonding agent.
摘要翻译： 为了实现粘合剂对颗粒材料，特别是芯片的最佳应用，没有精心设计的设备和机械，建议使用气动传送装置对任何情况下存在的材料进行粘合剂的应用，至少安排 一个用于在材料输送装置的管道的至少一个部分中的粘合剂的喷嘴，并且使用该喷嘴用于粘合剂喷射以薄膜形式输送的颗粒。
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10.发明授权Aqueous polyisocyanate emulsions useful as binders in the production of molded articles 失效在制备模塑制品中可用作粘合剂的多异氰酸酯乳液水乳液
公开(公告)号：US4472230A
公开(公告)日：1984-09-18
申请号：US455376
申请日：1983-01-03
申请人： Hanns I. Sachs , Peter Kasperek , Robert Peters
发明人： Hanns I. Sachs , Peter Kasperek , Robert Peters
CPC分类号： C08L75/00 , C08G18/706 , C08L97/02 , C08G2125/00
摘要： Aqueous polyisocyanate emulsions are made by emulsifying 5 to 70 parts by weight (on a basis of 100 parts) of a polyisocyanate which has not been modified to render it hydrophilic and emulsifiable with 30 to 95 parts by weight (on a basis of 100 parts) aqueous paraffin dispersion containing 3 to 65 wt. % paraffin, and optionally known additives in the presence of water. The water is used in a quantity such that the emulsion has a solids content of from 6 to 90 wt. %. These emulsions are particularly useful as binders in the production of molded articles.
摘要翻译： 水性多异氰酸酯乳液通过乳化5〜70重量份（基于100份）未改性以使其亲水和乳化的多异氰酸酯为30至95重量份（基于100份） 含有3〜65重量％ ％石蜡和任选已知的添加剂。 水的使用量使得乳液的固体含量为6〜90重量％。 ％。 这些乳液特别可用作模制品生产中的粘合剂。
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