6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides
    1.
    发明授权
    6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides 失效
    具有至少两个不对称取代的碳原子的6-取代的2,4-二氨基-1,3,5-三嗪衍生物,其制备及其作为除草剂的用途

    公开(公告)号:US06358886B1

    公开(公告)日:2002-03-19

    申请号:US09623612

    申请日:2000-11-03

    IPC分类号: C07D25118

    摘要: The invention relates to novel substituted optically active aminotriazines having at least two asymmetrically substituted carbon atoms of the formula (I), in which A represents a single bond or represents in each case straight-chain or branched alkanediyl or oxaalkanediyl having in each case up to 6 carbon atoms, Z represents certain carbocyclic or heterocyclic radicals and the substituents R1, R2, R3, R4 and Y are as defined in the description,  with the proviso that in each individual case R2, R3 and Y are different from one another and that the substituents at the two carbon atoms to which R2 and R3 or R4 are attached are configured as follows: (a) R configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“R,R-diastereomers”), (b) R configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“R,S-diastereomers”), (c) S configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“S,R-diastereomers”), (d) S configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“S,S-diastereomers”), (e) R configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“R,racdiastereomers”), (f) S configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“S,rac-diastereomers”), and to a process for preparing the compounds of the formula (I) and to their use as herbicides.

    摘要翻译: 本发明涉及具有式(I)的至少两个不对称取代的碳原子的新的取代的光学活性氨基三嗪,其中A表示单键或表示在每种情况下为直链或支链烷二基或氧杂烷二基,在每种情况下最多为6 碳原子,Z表示某些碳环或杂环基团,并且取代基R 1,R 2,R 3,R 4和Y如说明书中所定义,条件是在各个别情况下,R 2,R 3和Y彼此不同, R2和R3或R4连接的两个碳原子上的取代基配置如下:(a)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的R构型(“ R,R非对映异构体“),(b)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的S构型(”R,S-非对映异构体“),(c)S 配置在碳ato m与R 2相连的碳原子上的R构型(“S,R-非对映异构体”),(d)在R2和R3所连接的碳原子上的S构型, R 4连接的碳原子(“S,S-非对映异构体”),(e)R 2和R 3所连接的碳原子上的R构型,R 4连接的碳原子上的外消旋构型(“R” 外消旋异构体“),(f)R 2和R 3所连接的碳原子上的S构型以及与R4连接的碳原子上的外消旋构型(”S,外消旋 - 非对映体“),以及制备该化合物的方法 的式(I)和它们作为除草剂的用途。

    Substituted 2,4-diamino-1,3,5-triazines as herbicides
    5.
    发明授权
    Substituted 2,4-diamino-1,3,5-triazines as herbicides 失效
    取代的2,4-二氨基-1,3,5-三嗪作为除草剂

    公开(公告)号:US06399541B1

    公开(公告)日:2002-06-04

    申请号:US09381442

    申请日:1999-10-18

    IPC分类号: A01N4368

    CPC分类号: A01N43/68 C07D251/18

    摘要: The invention relates to novel substituted 2,4-diamino-1,3,5-triazines of the formula (I) in which R1 represents (in each case unsubstituted) phenyl or naphthyl R2 represents alkyl, R3 represents hydrogen, represents halogen or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulphinyl or alkylsulphonyl, R4 represents hydrogen, represents halogen or represents optionally substituted alkyl, R5 represents hydrogen, represents halogen or represents optionally substituted alkyl, and R6 represents hydrogen or represents in each case optionally substituted alkyl, alkylcarbonyl or alkylsulphonyl, (but where the compound 2-amino-4-(1-phenyl-ethylamino)-6-trifluoromethyl-1,3,5-triazine is excluded), to processes for preparing the novel compounds and to their use as herbicides.

    摘要翻译: 本发明涉及式(I)的新的取代的2,4-二氨基-1,3,5-三嗪,其中R 1表示(在每种情况下未被取代的)苯基或萘基,R 2表示烷基,R 3表示氢,表示卤素,或各自表示 任选取代的烷基,烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基,R 4表示氢,表示卤素,或表示任选取代的烷基,R 5表示氢,表示卤素或表示任选取代的烷基,R 6表示氢或表示任意取代的烷基,烷基羰基 或烷基磺酰基(但不包括化合物2-氨基-4-(1-苯基 - 乙基氨基)-6-三氟甲基-1,3,5-三嗪)),制备新化合物的方法及其作为除草剂的用途 。

    Substituted 2,4-diamino-1,3,5-triazine as herbicide
    6.
    发明授权
    Substituted 2,4-diamino-1,3,5-triazine as herbicide 失效
    取代的2,4-二氨基-1,3,5-三嗪作为除草剂

    公开(公告)号:US06271178B1

    公开(公告)日:2001-08-07

    申请号:US09284089

    申请日:1999-04-07

    IPC分类号: C07D25152

    摘要: The invention relates to novel substituted 2,4-diamino-1,3,5-triazines of the formula (I) In which R1 represents hydrogen or optionally substitued alkyl, R2 represents formyl or represents in each case optionally substituted alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, arylcarbonyl or arylsulphonyl, R3 represents in each case optionally substituted alkyl or cycloalkyl, R4 represents hydrogen or alkyl, A represents oxygen or methylene, Ar represents in each case optionally substituted aryl or heterocyclyl, and z represents hydrogen, hydroxyl, cyano, nitrogen, halogen or represents in each case optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenyl or alkinyl, (except for three prior-art compounds), to processes and to novel intermediates for preparation of the novel compounds and to their use as herbicides.

    摘要翻译: 本发明涉及式(I)的新型取代的2,4-二氨基-1,3,5-三嗪其中R 1表示氢或任选取代的烷基,R 2表示甲酰基或在各自的情况下表示任选取代的烷基羰基,烷氧基羰基,烷基磺酰基, 芳基羰基或芳基磺酰基,R 3表示在任何情况下为任选取代的烷基或环烷基,R 4表示氢或烷基,A表示氧或亚甲基,Ar表示在各情况下为任选取代的芳基或杂环基,并且z表示氢,羟基,氰基,氮,卤素或 表示在各种情况下任选取代的烷基,烷氧基,烷基羰基,烷氧基羰基,烷硫基,烷基亚磺酰基,烷基磺酰基,烯基或炔基(除三种现有技术化合物之外),用于制备新化合物及其用途的方法和新型中间体 作为除草剂。