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    Aliphatic polycarbonates, methods of making, and articles formed therefrom
    1.
    发明授权
    Aliphatic polycarbonates, methods of making, and articles formed therefrom 有权
    脂肪族聚碳酸酯，制造方法和由其形成的制品

    公开(公告)号：US07671164B2

    公开(公告)日：2010-03-02

    申请号：US12124583

    申请日：2008-05-21

    申请人： Hans-Peter Brack ,  Maarten Antoon Jan Campman ,  Jorge Garcia Agudo ,  Jan Henk Kamps ,  Hans Looij ,  Fernando Olmedo Fernandez ,  Dennis James Patrick Maria Willemse

    发明人： Hans-Peter Brack ,  Maarten Antoon Jan Campman ,  Jorge Garcia Agudo ,  Jan Henk Kamps ,  Hans Looij ,  Fernando Olmedo Fernandez ,  Dennis James Patrick Maria Willemse

    IPC分类号： C08G63/00 ,  C08G63/02

    CPC分类号： C08G64/305 ,  C08G64/0208

    摘要： A method of making a polycarbonate is described. The method comprises melt reacting an ester-substituted diaryl carbonate and a multifunctional compound of the formula: in the presence of catalyst to form an oligomer comprising less than 2,000 ppm of an ester-linked terminal group, and melt polymerizing the oligomer to form a polycarbonate. Use of specific reaction conditions produces a polycarbonate having an Mw of greater than or equal to 25,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising units derived from the multifunctional compound, including homopolycarbonates, aliphatic copolycarbonates further comprising units derived from an aromatic dihydroxy compound, and aliphatic polycarbonate-polyesters, are also disclosed, as are a thermoplastic composition and an article including the disclosed polycarbonates.

    摘要翻译： 描述制造聚碳酸酯的方法。 该方法包括使酯取代的碳酸二芳酯和下式的多官能化合物熔融反应：在催化剂存在下，形成包含小于2,000ppm的酯连接的末端基团的低聚物，并将该低聚物熔融聚合以形成聚碳酸酯 。 使用特定的反应条件产生通过凝胶渗透色谱法相对于聚苯乙烯标准测定的Mw大于或等于25,000g / mol的聚碳酸酯。 还公开了包含衍生自多官能化合物的单元的聚碳酸酯，包括均聚碳酸酯，还包含衍生自芳族二羟基化合物的单元的脂族共聚碳酸酯和脂族聚碳酸酯聚酯，以及包含所公开的聚碳酸酯的热塑性组合物和制品。

    MELT POLYMERIZATION REACTOR SYSTEM AND METHOD
    6.
    发明申请
    MELT POLYMERIZATION REACTOR SYSTEM AND METHOD 有权
    熔融聚合反应器系统和方法

    公开(公告)号：US20160039971A1

    公开(公告)日：2016-02-11

    申请号：US14239618

    申请日：2012-08-17

    申请人： Ignacio Vic Fernandez ,  Jorge Garcia Agudo ,  Maarten Campman

    发明人： Ignacio Vic Fernandez ,  Jorge Garcia Agudo ,  Maarten Campman

    IPC分类号： C08G64/06 ,  B01J19/24

    CPC分类号： C08G64/06 ,  B01J19/24 ,  B01J2219/24 ,  C08G64/307

    摘要： A reactor system for producing polycarbonate includes a surface area in contact with a reaction mixture. The reaction mixture comprises a melt transesterification catalyst, a dihydroxy compound, a diaryl carbonate, and an phenolic byproduct. The surface area in contact with the reaction mixture contains one or more welds joining reactor system parts. All welds in contact with the reaction mixture join reactor system parts made from the same type of metal. If a filler metal is contained in the weld, the filler metal is made from the same type of metal as the metal parts joined by the weld.

    摘要翻译： 用于生产聚碳酸酯的反应器系统包括与反应混合物接触的表面积。 反应混合物包括熔融酯交换催化剂，二羟基化合物，碳酸二芳基酯和酚类副产物。 与反应混合物接触的表面积包含连接反应器系统部件的一个或多个焊缝。 与反应混合物接触的所有焊缝都加入由相同类型金属制成的反应器系统部件。 如果焊缝中含有填充金属，则填充金属由与焊缝接合的金属部件相同类型的金属制成。

    METHODS AND SYSTEMS FOR THE CONTINUOUS ADDITION OF BRANCHING AGENTS INTO MELT POLYCARBONATE POLYMERIZATION PROCESSES
    7.
    发明申请
    METHODS AND SYSTEMS FOR THE CONTINUOUS ADDITION OF BRANCHING AGENTS INTO MELT POLYCARBONATE POLYMERIZATION PROCESSES 审中-公开
    分批代理连续添加到熔融聚碳酸酯聚合方法中的方法和系统

    公开(公告)号：US20120296064A1

    公开(公告)日：2012-11-22

    申请号：US13470494

    申请日：2012-05-14

    申请人： Ignacio Vic Fernandez ,  Jorge Garcia Agudo

    发明人： Ignacio Vic Fernandez ,  Jorge Garcia Agudo

    IPC分类号： C08G64/30

    CPC分类号： C08G64/307 ,  C08G64/14

    摘要： This disclosure relates generally to methods for the manufacture of melt polymerized branched polycarbonates. The methods disclosure herein introduce branching agent into the melt process as a dissolved component in a solution comprised of a solvent and dissolved branching agent. Also disclosed are systems and apparatuses for performing the disclosed methods.

    摘要翻译： 本公开一般涉及用于制造熔融聚合的支化聚碳酸酯的方法。 本文的方法公开了将支化剂作为溶解组分引入到由溶剂和溶解的支化剂组成的溶液中的熔融过程中。 还公开了用于执行所公开的方法的系统和装置。

    Melt polymerization reactor system and method
    8.
    发明授权
    Melt polymerization reactor system and method 有权
    熔体聚合反应器系统及方法

    公开(公告)号：US09382379B2

    公开(公告)日：2016-07-05

    申请号：US14239618

    申请日：2012-08-17

    申请人： Ignacio Vic Fernandez ,  Jorge Garcia Agudo ,  Maarten Campman

    发明人： Ignacio Vic Fernandez ,  Jorge Garcia Agudo ,  Maarten Campman

    IPC分类号： C08G64/00 ,  C08G64/06 ,  C08G64/30 ,  B01J19/24

    CPC分类号： C08G64/06 ,  B01J19/24 ,  B01J2219/24 ,  C08G64/307

    摘要： A reactor system for producing polycarbonate includes a surface area in contact with a reaction mixture. The reaction mixture comprises a melt transesterification catalyst, a dihydroxy compound, a diaryl carbonate, and an phenolic byproduct. The surface area in contact with the reaction mixture contains one or more welds joining reactor system parts. All welds in contact with the reaction mixture join reactor system parts made from the same type of metal. If a filler metal is contained in the weld, the filler metal is made from the same type of metal as the metal parts joined by the weld.

    摘要翻译： 用于生产聚碳酸酯的反应器系统包括与反应混合物接触的表面积。 反应混合物包括熔融酯交换催化剂，二羟基化合物，碳酸二芳基酯和酚类副产物。 与反应混合物接触的表面积包含连接反应器系统部件的一个或多个焊缝。 与反应混合物接触的所有焊缝都加入由相同类型金属制成的反应器系统部件。 如果焊缝中含有填充金属，则填充金属由与焊缝接合的金属部件相同类型的金属制成。

    Method of making polycarbonate
    9.
    发明授权
    Method of making polycarbonate 有权
    制作聚碳酸酯的方法

    公开(公告)号：US07985824B1

    公开(公告)日：2011-07-26

    申请号：US12730441

    申请日：2010-03-24

    申请人： Jorge Garcia Agudo ,  Ignacio Vic Fernandez ,  David Domingo Fuster ,  Miguel Angel Salomon

    发明人： Jorge Garcia Agudo ,  Ignacio Vic Fernandez ,  David Domingo Fuster ,  Miguel Angel Salomon

    IPC分类号： C08G64/00 ,  C08G63/02

    CPC分类号： C08G64/305

    摘要： A method of making a polycarbonate is described. The method comprises reacting an activated diaryl carbonate and a dihydroxy compound at a reaction temperature in a reactor to form a reaction mixture wherein the reactor comprises a heated cover and an open space between the cover and the reaction mixture. The dihydroxy compound comprises a vapor pressure greater than or equal to 0.01 kiloPascals at the reaction temperature and the temperature of the open space in the reactor, the temperature of the cover, or the temperature of the open space and the cover is greater than or equal to the melt temperature of the monomer having the highest melt temperature.

    摘要翻译： 描述制造聚碳酸酯的方法。 该方法包括在反应器中的反应温度下使活化的碳酸二芳基酯和二羟基化合物反应以形成反应混合物，其中反应器包括加热的盖和盖和反应混合物之间的开放空间。 二羟基化合物在反应温度和反应器中的开放空间的温度，盖的温度或开放空间和盖的温度大于或等于包括蒸气压大于或等于0.01千帕 至熔体温度最高的单体的熔融温度。