Method for making polycarbonate
    4.
    发明授权
    Method for making polycarbonate 有权
    制作聚碳酸酯的方法

    公开(公告)号:US08263729B2

    公开(公告)日:2012-09-11

    申请号:US12974197

    申请日:2010-12-21

    IPC分类号: C08G64/00 C08G63/02

    CPC分类号: C08G64/307

    摘要: A method of making polycarbonate comprises polymerizing, in a melt polymerization reaction, an aromatic dihydroxy compound and a diaryl carbonate in a presence of a polymerization catalyst and producing a by-product vapor stream comprising the dihydroxy compound, the diaryl carbonate and a diaryl carbonate by-product, adding a low vapor pressure compound to the by-product vapor stream to produce a modified by-product vapor stream, introducing the modified by-product vapor stream to a separation unit, removing the volatile diaryl carbonate by-product from the modified by-product vapor stream in the separation unit to form a treated by-product stream and returning the treated by-product stream to the polymerization reaction. Alternatively, the low vapor pressure compound can be added directly to the separation unit.

    摘要翻译: 一种制备聚碳酸酯的方法包括在熔融聚合反应中,在聚合催化剂存在下聚合芳族二羟基化合物和碳酸二芳基酯,并产生包含二羟基化合物,碳酸二芳基酯和碳酸二芳基酯的副产物蒸气流 产物,向副产物蒸汽流中加入低蒸汽压化合物以产生改性副产物蒸气流,将改性副产物蒸汽流引入分离单元,从经修饰的蒸汽流中除去挥发性碳酸二芳酯副产物 在分离单元中产生副产物蒸汽流以形成经处理的副产物流并将处理的副产物流返回到聚合反应中。 或者,低蒸气压化合物可以直接添加到分离单元。

    SYSTEM AND PROCESS FOR THE CONTINUOUS VACUUM COATING OF A MATERIAL IN WEB FORM
    6.
    发明申请
    SYSTEM AND PROCESS FOR THE CONTINUOUS VACUUM COATING OF A MATERIAL IN WEB FORM 审中-公开
    网页形式的材料的连续真空涂料的系统和工艺

    公开(公告)号:US20110274838A1

    公开(公告)日:2011-11-10

    申请号:US12674233

    申请日:2008-08-05

    CPC分类号: C23C14/562 C23C16/545

    摘要: The system (1) for the continuous vacuum coating of a continuously suppliable material in web form (2) provided with feed means; at least one inlet chamber (4), wherein the transition between the inlet atmospheric pressure and the vacuum pressure of a coating chamber (5) incorporating at least one vacuum deposition module (6) for depositing metallic and/or dielectric components on the material in web form is carried out; at least one outlet chamber (7); and collecting means (8) which collect the coated material in web form. The system further comprises drive and support means (9), on which the material in web form is fixed for its transport and by one of its faces, which material follows a preferably straight path at least through the coating chamber.

    摘要翻译: 用于连续提供真空涂料的系统(1),所述系统包括具有进料装置的网状(2)的连续供应材料; 至少一个入口室(4),其中入口大气压力和涂覆室(5)的真空压力之间的过渡结合有至少一个用于在所述材料上沉积金属和/或电介质成分的真空沉积模块(6) 网页形式进行; 至少一个出口室(7); 以及收集装置(8),其收集网状的涂覆材料。 该系统还包括驱动和支撑装置(9),在其上以网状形式的材料被固定以便运输,并且通过其一个表面,该材料至少穿过涂覆室遵循优选的直线路径。

    Process for obtaining a catalytic system for the polymerization of       .
.alpha-olefins in suspension in gas phase at low and high temperature
or in a mass at high pressure and high or low temperatures
    8.
    发明授权
    Process for obtaining a catalytic system for the polymerization of . .alpha-olefins in suspension in gas phase at low and high temperature or in a mass at high pressure and high or low temperatures 失效
    获得用于在低温高温或高压和高温或低温下在气相中悬浮液中的α-烯烃聚合的催化体系的方法

    公开(公告)号:US6143685A

    公开(公告)日:2000-11-07

    申请号:US844012

    申请日:1997-04-18

    摘要: Catalytic systems particularly suitable for the polymerization of .alpha.-olefins containing from two to 20 carbon atoms, as well as for the copolymerization of ethylene with .alpha.-olefins containing from three to 20 carbon atoms, dienes, and cycloalkenes in processes wherein the catalyst is suspended in a solvent, in processes in gas phase, as well as in mass polymerization processes at high temperatures and pressures, are disclosed. The catalytic system is a mixture of a catalyst component A and a co-catalyst component B. The catalyst component A is formed by a functionalized inorganic porous oxide, by an organoaluminium compound and by an organometallic compound of a metal of the groups 3, 4, 5, or 6 of the periodic table. Functionalization of the inorganic oxide is by introduction of functional groups to be used to strongly fix the organoaluminium compound and the organometallic compound. The co-catalyst component B, which is used for the activation of the catalyst, is formed of organoaluminium compounds, perfluorinated derivatives of boron, or a mixture thereof.

    摘要翻译: 在催化剂悬浮的方法中,特别适用于含有2至20个碳原子的α-烯烃的聚合以及乙烯与含有3至20个碳原子的α-烯烃的二烯和环烯烃的共聚反应的催化体系 在溶剂中,在气相的方法中以及在高温和高压下的大量聚合方法中都有公开。 催化剂体系是催化剂组分A和助催化剂组分B的混合物。催化剂组分A由官能化的无机多孔氧化物,有机铝化合物和第3,4族金属的有机金属化合物形成 ,5或6。 无机氧化物的官能化是通过引入用于强力固定有机铝化合物和有机金属化合物的官能团。 用于活化催化剂的助催化剂组分B由有机铝化合物,硼的全氟化衍生物或其混合物形成。

    Hetergeneous metallocene catalysts and use thereof in olefin
polymerization process
    9.
    发明授权
    Hetergeneous metallocene catalysts and use thereof in olefin polymerization process 失效
    过氧化氢茂金属催化剂及其在烯烃聚合方法中的应用

    公开(公告)号:US6133187A

    公开(公告)日:2000-10-17

    申请号:US174997

    申请日:1998-10-19

    摘要: A catalyst comprising a cocatalyst and a catalyst component obtained by contacting a silicon-containing metallocene compound with an inorganic support to chemically bond the metallocene compound to the inorganic support, wherein the silicon-containing metallocene compound has a formula (I): ##STR1## wherein: M is a metal selected from [the group consisting of] group 4, 5, or 6 of the periodic table;each X is independently selected from the group consisting of hydrogen, halogen, C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.10 alkoxy, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aryloxy, C.sub.2 -C.sub.10 alkenyl, C.sub.7 -C.sub.40 arylalkyl, C.sub.7 -C.sub.40 alkylaryl, and C.sub.8 -C.sub.40 arylalkenyl;A.sub.1 and A.sub.2 are independently selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, fluorenyl, substituted indenyl, and substituted fluorenyl, wherein the substituents are independently C.sub.1 -C.sub.10 linear or branched alkyl, C.sub.5 -C.sub.7 cycloalkyl, optionally substituted by an alkyl group, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aryloxy, C.sub.2 -C.sub.10 alkenyl, C.sub.7 -C.sub.40 arylalkyl, C.sub.7 -C.sub.40 alkylaryl, or C.sub.8 -C.sub.40 arylalkenyl.

    摘要翻译: 1.一种催化剂,其特征在于,含有助催化剂和催化剂成分,所述催化剂组分通过使含硅金属茂化合物与无机载体接触以将所述茂金属化合物与所述无机载体化学键合,其中所述含硅金属茂化合物具有式(I):其中:M 是选自元素周期表第4,5或6族的[金属基团]的金属; 每个X独立地选自氢,卤素,C 1 -C 10烷基,C 1 -C 10烷氧基,C 6 -C 10芳基,C 6 -C 10芳氧基,C 2 -C 10烯基,C 7 -C 40芳基烷基,C 7 -C 40烷基芳基和 C8-C40芳基烯基; A1和A2独立地选自环戊二烯基,取代的环戊二烯基,茚基,芴基,取代的茚基和取代的芴基,其中取代基独立地为C 1 -C 10直链或支链烷基,任选被烷基取代的C 5 -C 7环烷基 基团,C 6 -C 10芳基,C 6 -C 10芳氧基,C 2 -C 10烯基,C 7 -C 40芳基烷基,C 7 -C 40烷基芳基或C 8 -C 40芳基烯基。

    Process for obtaining polyolefins
    10.
    发明授权
    Process for obtaining polyolefins 失效
    获得聚烯烃的方法

    公开(公告)号:US06388029B1

    公开(公告)日:2002-05-14

    申请号:US09584518

    申请日:2000-05-31

    IPC分类号: C08F442

    摘要: Catalytic systems particularly suitable for the polymerization of &agr;-olefins containing from two to 20 carbon atoms, as well as for the copolymerization of ethylene with &agr;-olefins containing from three to 20 carbon atoms, dienes, and cycloalkenes in processes wherein the catalyst is suspended in a solvent, in processes in gas phase, as well as in mass polymerization processes at high temperatures and pressures, are disclosed. The catalytic system is a mixture of a catalyst component A and a co-catalyst component B. The catalyst component A is formed by a functionalized inorganic porous oxide, by an organoaluminium compound and by an organometallic compound of a metal of the groups 3, 4, 5, or 6 of the periodic table. Functionalization of the inorganic oxide is by introduction of functional groups to be used to strongly fix the organoaluminium compound and the organometallic compound. The co-catalyst component B, which is used for the activation of the catalyst, is formed of organoaluminium compounds, perfluorinated derivatives of boron, or a mixture thereof.

    摘要翻译: 在催化剂悬浮的方法中,特别适用于含有2至20个碳原子的α-烯烃的聚合以及乙烯与含有3至20个碳原子的α-烯烃的二烯和环烯烃的共聚反应的催化体系 在溶剂中,在气相的方法中以及在高温和高压下的大量聚合方法中都有公开。 催化剂体系是催化剂组分A和助催化剂组分B的混合物。催化剂组分A由官能化的无机多孔氧化物,有机铝化合物和第3,4族金属的有机金属化合物形成 ,5或6。 无机氧化物的官能化是通过引入用于强力固定有机铝化合物和有机金属化合物的官能团。 用于活化催化剂的助催化剂组分B由有机铝化合物,硼的全氟化衍生物或其混合物形成。