公开(公告)号：US08993127B2

公开(公告)日：2015-03-31

申请号：US13227022

申请日：2011-09-07

申请人： Harue Osaka ,  Takako Takasu ,  Hiromi Nowatari ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki

发明人： Harue Osaka ,  Takako Takasu ,  Hiromi Nowatari ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07D333/76 ,  C07D307/91 ,  C07C25/02 ,  C07C25/22 ,  C07C33/50 ,  C07C49/80 ,  C07D409/10 ,  H01L51/00 ,  H05B33/10 ,  H01L51/50

CPC分类号： H01L51/0058 ,  C07C25/02 ,  C07C25/22 ,  C07C31/36 ,  C07C33/46 ,  C07C33/50 ,  C07C49/163 ,  C07C49/333 ,  C07C49/80 ,  C07C2603/18 ,  C07C2603/24 ,  C07C2603/50 ,  C07D307/91 ,  C07D333/76 ,  C07D409/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5004 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/508 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5206 ,  H01L51/5221 ,  H01L2251/301 ,  H01L2251/308 ,  H01L2251/552 ,  H05B33/10 ,  Y10S428/917

摘要： A substance having a hole-transport property and a wide band gap is provided. A fluorene compound represented by a general formula (G1) is provided. In the general formula (G1), α1 and α2 separately represent a substituted or unsubstituted arylene group having 6 to 13 carbon atoms; Ar1 represents a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, a substituted or unsubstituted 4-dibenzothiophenyl group, or a substituted or unsubstituted 4-dibenzofuranyl group; n and k separately represent 0 or 1; Q1 represents sulfur or oxygen; and R1 to R15 separately represent hydrogen, an alkyl group having 1 to 12 carbon atoms, or an aryl group having 6 to 14 carbon atoms.

摘要翻译： 提供具有空穴传输性和宽带隙的物质。 提供由通式（G1）表示的芴化合物。 在通式（G1）中，α1和α2分别表示取代或未取代的碳原子数为6〜13的亚芳基。 Ar1表示取代或未取代的碳原子数为6〜18的芳基，取代或未取代的4-二苯并噻吩基或取代或未取代的4-二苯并呋喃基; n和k分别表示0或1; Q1表示硫或氧; R1〜R15分别表示氢，碳原子数1〜12的烷基或碳原子数6〜14的芳基。

公开(公告)号：US20120061714A1

公开(公告)日：2012-03-15

申请号：US13227022

申请日：2011-09-07

申请人： Harue Osaka ,  Takako Takasu ,  Hiromi Nowatari ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki

发明人： Harue Osaka ,  Takako Takasu ,  Hiromi Nowatari ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki

IPC分类号： H01L33/62 ,  C07C25/22 ,  C07C49/303 ,  C07C31/36 ,  C07D333/76 ,  C07D307/91

CPC分类号： H01L51/0058 ,  C07C25/02 ,  C07C25/22 ,  C07C31/36 ,  C07C33/46 ,  C07C33/50 ,  C07C49/163 ,  C07C49/333 ,  C07C49/80 ,  C07C2603/18 ,  C07C2603/24 ,  C07C2603/50 ,  C07D307/91 ,  C07D333/76 ,  C07D409/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5004 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/508 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5206 ,  H01L51/5221 ,  H01L2251/301 ,  H01L2251/308 ,  H01L2251/552 ,  H05B33/10 ,  Y10S428/917

摘要： A substance having a hole-transport property and a wide band gap is provided. A fluorene compound represented by a general formula (G1) is provided. In the general formula (G1), α1 and α2 separately represent a substituted or unsubstituted arylene group having 6 to 13 carbon atoms; Ar1 represents a substituted or unsubstituted aryl group having 6 to 18 carbon atoms, a substituted or unsubstituted 4-dibenzothiophenyl group, or a substituted or unsubstituted 4-dibenzofuranyl group; n and k separately represent 0 or 1; Q1 represents sulfur or oxygen; and R1 to R15 separately represent hydrogen, an alkyl group having 1 to 12 carbon atoms, or an aryl group having 6 to 14 carbon atoms.

摘要翻译： 提供具有空穴传输性和宽带隙的物质。 提供由通式（G1）表示的芴化合物。 在通式（G1）中，α1和α2分别表示取代或未取代的碳原子数为6〜13的亚芳基。 Ar1表示取代或未取代的碳原子数为6〜18的芳基，取代或未取代的4-二苯并噻吩基或取代或未取代的4-二苯并呋喃基; n和k分别表示0或1; Q1表示硫或氧; R1〜R15分别表示氢，碳原子数1〜12的烷基或碳原子数6〜14的芳基。

公开(公告)号：US20120074390A1

公开(公告)日：2012-03-29

申请号：US13228644

申请日：2011-09-09

申请人： Satoshi Seo ,  Harue Osaka ,  Sachiko Kawakami ,  Nobuharu Ohsawa ,  Tsunenori Suzuki ,  Hiromi Nowatari ,  Hiroki Suzuki ,  Kyoko Takeda

发明人： Satoshi Seo ,  Harue Osaka ,  Sachiko Kawakami ,  Nobuharu Ohsawa ,  Tsunenori Suzuki ,  Hiromi Nowatari ,  Hiroki Suzuki ,  Kyoko Takeda

IPC分类号： H01L51/54

CPC分类号： H01L51/0074 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07D409/14 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5056

摘要： An object is to provide a light-emitting element with high emission efficiency which includes a novel carbazole derivative that has a wide energy gap and can be used for a transport layer or a host material in a light-emitting element. A carbazole derivative in which the 4-position of dibenzothiophene or dibenzofuran is bonded to the 2- or 3-position of carbazole has been able to be provided by use of the carbazole derivative. Further, a light-emitting element having high emission efficiency has been able to be provided by use of the carbazole derivative.

摘要翻译： 本发明的目的是提供一种具有高发光效率的发光元件，其包括具有宽能隙的新型咔唑衍生物，可用于发光元件中的输送层或主体材料。 通过使用咔唑衍生物，能够使二苯并噻吩或二苯并呋喃的4-位与咔唑的2-或3-位相连的咔唑衍生物。 此外，通过使用咔唑衍生物，能够提供发光效率高的发光元件。

公开(公告)号：US08673459B2

公开(公告)日：2014-03-18

申请号：US13228644

申请日：2011-09-09

申请人： Satoshi Seo ,  Harue Osaka ,  Sachiko Kawakami ,  Nobuharu Ohsawa ,  Tsunenori Suzuki ,  Hiromi Nowatari ,  Hiroki Suzuki ,  Kyoko Takeda

发明人： Satoshi Seo ,  Harue Osaka ,  Sachiko Kawakami ,  Nobuharu Ohsawa ,  Tsunenori Suzuki ,  Hiromi Nowatari ,  Hiroki Suzuki ,  Kyoko Takeda

IPC分类号： H01L51/54

CPC分类号： H01L51/0074 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07D409/14 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5056

摘要： An object is to provide a light-emitting element with high emission efficiency which includes a novel carbazole derivative that has a wide energy gap and can be used for a transport layer or a host material in a light-emitting element. A carbazole derivative in which the 4-position of dibenzothiophene or dibenzofuran is bonded to the 2- or 3-position of carbazole has been able to be provided by use of the carbazole derivative. Further, a light-emitting element having high emission efficiency has been able to be provided by use of the carbazole derivative.

摘要翻译： 本发明的目的是提供一种具有高发光效率的发光元件，其包括具有宽能隙的新型咔唑衍生物，可用于发光元件中的输送层或主体材料。 通过使用咔唑衍生物，能够使二苯并噻吩或二苯并呋喃的4-位与咔唑的2-或3-位相连的咔唑衍生物。 此外，通过使用咔唑衍生物，能够提供发光效率高的发光元件。

公开(公告)号：US20130048964A1

公开(公告)日：2013-02-28

申请号：US13590388

申请日：2012-08-21

申请人： Kyoko Takeda ,  Harue Osaka ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Hiromi Seo

发明人： Kyoko Takeda ,  Harue Osaka ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Hiromi Seo

IPC分类号： C07D239/26 ,  C07D409/14 ,  C07D405/14 ,  H01L51/54

CPC分类号： C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/1096 ,  C09K2211/185 ,  H01L51/0058 ,  H01L51/0067 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5072 ,  H01L2251/552

摘要： A light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a LUMO level of greater than or equal to −3.5 eV and less than or equal to −2.5 eV, and the second compound is an organic compound having a pyrimidine skeleton. The light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a diazine skeleton, and the second compound is an organic compound having a pyrimidine skeleton.

摘要翻译： 发光元件包括一对电极之间的EL层。 EL层包含第一化合物和第二化合物。 第一化合物是具有大于或等于-3.5eV且小于或等于-2.5eV的LUMO水平的磷光铱金属络合物，第二化合物是具有嘧啶骨架的有机化合物。 发光元件包括一对电极之间的EL层。 EL层包含第一化合物和第二化合物。 第一化合物是具有二嗪骨架的磷光铱金属络合物，第二化合物是具有嘧啶骨架的有机化合物。

公开(公告)号：US09663711B2

公开(公告)日：2017-05-30

申请号：US13590388

申请日：2012-08-21

申请人： Kyoko Takeda ,  Harue Osaka ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Hiromi Seo

发明人： Kyoko Takeda ,  Harue Osaka ,  Satoko Shitagaki ,  Nobuharu Ohsawa ,  Satoshi Seo ,  Hiromi Seo

IPC分类号： H01L51/50 ,  C09K11/06 ,  H01L51/00

CPC分类号： C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/1096 ,  C09K2211/185 ,  H01L51/0058 ,  H01L51/0067 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5072 ,  H01L2251/552

摘要： A light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a LUMO level of greater than or equal to −3.5 eV and less than or equal to −2.5 eV, and the second compound is an organic compound having a pyrimidine skeleton. The light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a diazine skeleton, and the second compound is an organic compound having a pyrimidine skeleton.

公开(公告)号：US08642782B2

公开(公告)日：2014-02-04

申请号：US13228672

申请日：2011-09-09

申请人： Hiroki Suzuki ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki ,  Satoshi Seo ,  Nobuharu Ohsawa

发明人： Hiroki Suzuki ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC分类号： C07D209/82 ,  C07D209/86

CPC分类号： H01L51/0072 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07D409/14 ,  C09K11/025 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0566 ,  H01L51/5012 ,  H01L51/5056 ,  H01L51/5072

摘要： An object is to provide a novel carbazole derivative that has an excellent carrier-transport property and can be suitably used for a transport layer or as a host material of a light-emitting element. Another object is to provide an organic semiconductor material and a light-emitting element material each using the carbazole derivative. As the carbazole derivative that can achieve the above objects, a carbazole derivative in which a carbazolyl group whose either 2- or 3-position of carbazole is substituted by the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is bonded to aromatic hydrocarbon that has 14 to 70 carbon atoms and includes a condensed tricyclic ring, a condensed tetracyclic ring, a condensed pentacyclic ring, a condensed hexacyclic ring, or a condensed heptacyclic ring has been able to be synthesized.

摘要翻译： 本发明的目的是提供一种具有优异载流子传输性能的新型咔唑衍生物，可适用于传输层或作为发光元件的主体材料。 另一个目的是提供各自使用咔唑衍生物的有机半导体材料和发光元件材料。 作为能够实现上述目的的咔唑衍生物，可以举出二苯并噻吩骨架或二苯并呋喃骨架的4-位取代咔唑的2-或3-位的咔唑基与咔唑衍生物， 具有14至70个碳原子，并且可以合成包括稠合的三环，缩合的四环，缩合的五环，缩合的六环或缩合的七环。

公开(公告)号：US20120071668A1

公开(公告)日：2012-03-22

申请号：US13228672

申请日：2011-09-09

申请人： Hiroki Suzuki ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki ,  Satoshi Seo ,  Nobuharu Ohsawa

发明人： Hiroki Suzuki ,  Kyoko Takeda ,  Sachiko Kawakami ,  Tsunenori Suzuki ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC分类号： C07D409/10

CPC分类号： H01L51/0072 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07D409/14 ,  C09K11/025 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0566 ,  H01L51/5012 ,  H01L51/5056 ,  H01L51/5072

摘要： An object is to provide a novel carbazole derivative that has an excellent carrier-transport property and can be suitably used for a transport layer or as a host material of a light-emitting element. Another object is to provide an organic semiconductor material and a light-emitting element material each using the carbazole derivative. As the carbazole derivative that can achieve the above objects, a carbazole derivative in which a carbazolyl group whose either 2- or 3-position of carbazole is substituted by the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is bonded to aromatic hydrocarbon that has 14 to 70 carbon atoms and includes a condensed tricyclic ring, a condensed tetracyclic ring, a condensed pentacyclic ring, a condensed hexacyclic ring, or a condensed heptacyclic ring has been able to be synthesized.

摘要翻译： 本发明的目的是提供一种具有优异载流子传输性能的新型咔唑衍生物，可适用于传输层或作为发光元件的主体材料。 另一个目的是提供各自使用咔唑衍生物的有机半导体材料和发光元件材料。 作为能够实现上述目的的咔唑衍生物，可以举出二苯并噻吩骨架或二苯并呋喃骨架的4-位取代咔唑的2-或3-位的咔唑基与咔唑衍生物， 具有14至70个碳原子，并且可以合成包括稠合的三环，缩合的四环，缩合的五环，缩合的六环或缩合的七环。

公开(公告)号：US20130082591A1

公开(公告)日：2013-04-04

申请号：US13598253

申请日：2012-08-29

申请人： Satoshi Seo ,  Satoko Shitagaki ,  Miyako Morikubo ,  Naoaki Hashimoto ,  Takahiro Ishisone ,  Kyoko Takeda ,  Hiromi Seo

发明人： Satoshi Seo ,  Satoko Shitagaki ,  Miyako Morikubo ,  Naoaki Hashimoto ,  Takahiro Ishisone ,  Kyoko Takeda ,  Hiromi Seo

IPC分类号： C07D403/14 ,  C07D409/14 ,  H05B33/14

CPC分类号： H01L51/0072 ,  C07D403/14 ,  C07D409/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/006 ,  H01L51/0071 ,  H01L51/0074 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5076 ,  H05B33/14

摘要： To provide a novel heterocyclic compound that can be used as a host material in which a light-emitting substance of a light-emitting layer is dispersed. A heterocyclic compound comprising a dibenzo[f,h]quinoxaline ring and two hole-transport skeletons, where the dibenzo[f,h]quinoxaline ring and the two hole-transport skeletons are bonded to an aromatic hydrocarbon group. A heterocyclic compound represented by the following general formula (G1) is provided. Note that in the formula, A1 and A2 each independently represent any of a substituted or unsubstituted carbazole skeleton, a substituted or unsubstituted dibenzofuran skeleton, and a substituted or unsubstituted dibenzothiophen skeleton; B represents a substituted or unsubstituted dibenzo[f,h]quinoxaline skeleton; and Ar represents an arene skeleton having 6 to 13 carbon atoms. A light-emitting element including the heterocyclic compound is provided.

摘要翻译： 提供可用作分散发光层的发光物质的主体材料的新型杂环化合物。 包含二苯并[f，h]喹喔啉环和两个空穴传输骨架的杂环化合物，其中二苯并[f，h]喹喔啉环和两个空穴传输骨架与芳族烃基键合。 提供由以下通式（G1）表示的杂环化合物。 注意，在该式中，A1和A2各自独立地表示取代或未取代的咔唑骨架，取代或未取代的二苯并呋喃骨架和取代或未取代的二苯并噻吩骨架中的任意一种; B代表取代或未取代的二苯并[f，h]喹喔啉骨架; Ar表示碳原子数6〜13的芳烃骨架。 提供了包含杂环化合物的发光元件。

公开(公告)号：US09394280B2

公开(公告)日：2016-07-19

申请号：US13598253

申请日：2012-08-29

申请人： Satoshi Seo ,  Satoko Shitagaki ,  Miyako Morikubo ,  Naoaki Hashimoto ,  Takahiro Ishisone ,  Kyoko Takeda ,  Hiromi Seo

发明人： Satoshi Seo ,  Satoko Shitagaki ,  Miyako Morikubo ,  Naoaki Hashimoto ,  Takahiro Ishisone ,  Kyoko Takeda ,  Hiromi Seo

IPC分类号： H01L51/50 ,  C07D403/14 ,  C07D409/14 ,  H05B33/14 ,  C09K11/06 ,  H01L51/00

CPC分类号： H01L51/0072 ,  C07D403/14 ,  C07D409/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/006 ,  H01L51/0071 ,  H01L51/0074 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5076 ,  H05B33/14

摘要： To provide a novel heterocyclic compound that can be used as a host material in which a light-emitting substance of a light-emitting layer is dispersed. A heterocyclic compound comprising a dibenzo[f,h]quinoxaline ring and two hole-transport skeletons, where the dibenzo[f,h]quinoxaline ring and the two hole-transport skeletons are bonded to an aromatic hydrocarbon group. A heterocyclic compound represented by the following general formula (G1) is provided. Note that in the formula, A1 and A2 each independently represent any of a substituted or unsubstituted carbazole skeleton, a substituted or unsubstituted dibenzofuran skeleton, and a substituted or unsubstituted dibenzothiophen skeleton; B represents a substituted or unsubstituted dibenzo[f,h]quinoxaline skeleton; and Ar represents an arene skeleton having 6 to 13 carbon atoms. A light-emitting element including the heterocyclic compound is provided.

摘要翻译： 提供可用作分散发光层的发光物质的主体材料的新型杂环化合物。 包含二苯并[f，h]喹喔啉环和两个空穴传输骨架的杂环化合物，其中二苯并[f，h]喹喔啉环和两个空穴传输骨架与芳族烃基键合。 提供由以下通式（G1）表示的杂环化合物。 注意，在该式中，A1和A2各自独立地表示取代或未取代的咔唑骨架，取代或未取代的二苯并呋喃骨架和取代或未取代的二苯并噻吩骨架中的任意一种; B代表取代或未取代的二苯并[f，h]喹喔啉骨架; Ar表示碳原子数6〜13的芳烃骨架。 提供了包含杂环化合物的发光元件。