摘要:
Process for scrubbing out ammonia nitrogen and/or ammonium nitrogen and/or urea nitrogen from exhaust gases enriched with these nitrogen compounds in plants for producing ammonia or urea, wherein the nitrogen compounds first form with a hypochlorite-containing solution in a scrubber an intermediate which under acidic or neutral reaction conditions is reacted to form elemental nitrogen and salt, and the reaction of the nitrogen compounds to form elemental nitrogen and salt proceeds in a pH range of 4 to 6.
摘要:
Process for scrubbing out ammonia nitrogen and/or ammonium nitrogen and/or urea nitrogen from exhaust gases enriched with these nitrogen compounds in plants for producing ammonia or urea, wherein the nitrogen compounds first form with a hypochlorite-containing solution in a scrubber an intermediate which under acidic or neutral reaction conditions is reacted to form elemental nitrogen and salt, and the reaction of the nitrogen compounds to form elemental nitrogen and salt proceeds in a pH range of 4 to 6.
摘要:
A process for utilizing synthesis gas heat for the generation of supercritical steam in a low energy ammonia or methanol plant is disclosed. The process involves a reforming or partial oxidation stage, at least one supercritical steam generator having a shell side and a tube side, at least one superheater, at least one back pressure turbine, at least one extraction and condensing turbine, and at least one boiler feedwater pump. The synthesized synthesis gas is sent to the shell side of the supercritical steam generator, and the supercritical steam generator is fed with pressurized feedwater. The feedwater flow is adjusted to maintain the steam temperature at the exit of the supercritical steam generator in the range of 375-500° C. The supercritical steam is generated in the supercritical steam generator at a pressure of 225-450 bar, the supercritical steam is further heated in a superheater to a temperature of 500-750° C., and the supercritical steam generated in the superheater is fed to a back pressure turbine.
摘要:
An axial thin-film reactor for carrying out catalytic reactions in the gas phase, comprising a cylindrical pressure casing, a device for letting in a gaseous reactant stream, a device for letting out a gaseous product stream, a device for receiving a catalyst bed arranged vertically in the reaction chamber and isolated from the reactor wall at the sides and at the ends so as to produce two separate chambers for the gaseous reactant stream and the gaseous product stream that are sealed with respect to one another and have two gas-permeable bounding walls arranged plane-parallel to one another. The device is designed in such a way that it has a height-to-thickness ratio greater than 1 and the catalyst bed has a height-to-thickness ratio greater than 1.
摘要:
The invention relates to a process for the production of ammonia from synthesis gas, the synthesis of ammonia from synthesis gas taking place in several lined-up synthesis systems, whereby ammonia is produced from a portion of the synthesis gas in each system with a part-stream being withdrawn and the respective downstream synthesis system being operated at a higher pressure than the respective upstream synthesis system.