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公开(公告)号：US5274031A
公开(公告)日：1993-12-28
申请号：US435057
申请日：1989-11-13
CPC分类号： C08L51/04 , C08L51/085
摘要： Molding compounds ofA) 5 to 95 parts by weight of a graft product of resin-forming monomers on a particulate silicone rubber having a total rubber content of from 30 to 90% by weight andB) 95 to 5 parts by weight of resin-forming monomers on a particulate EPDM rubber having a total rubber content of 10 to 50% by weight andC) 10 to 200 parts by weight (based on 100 parts by weight A+B) of a graft product of resin-forming monomers on a particulate acrylate rubber having a total rubber content of from 30 to 80% by weight.
摘要翻译： A）成型化合物A）5至95重量份的树脂形成单体的接枝产物在总橡胶含量为30至90重量％的颗粒状硅橡胶上，B）95至5重量份树脂 - 在总橡胶含量为10至50重量％的颗粒状EPDM橡胶上形成单体，C）10至200重量份（基于100重量份A + B）的树脂形成单体的接枝产物 总橡胶含量为30至80重量％的颗粒状丙烯酸酯橡胶。
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公开(公告)号：US5272205A
公开(公告)日：1993-12-21
申请号：US435056
申请日：1989-11-13
CPC分类号： C08L51/04 , C08L51/085
摘要： Molding compounds of(A) 5 to 95% by weight of a graft product of a mixture of 50 to 100 parts by weight styrene, .alpha.-methyl styrene, vinyl toluene, methyl methacrylate or mixtures thereof and 0 to 50 parts by weight acrylonitrile on a particulate silicone rubber with a mean particle diameter (d.sub.50) of from 0.10 to 0.50 .mu.m having a total rubber content of from 30 to 90% by weight and(B) 95 to 5% by weight of a graft product of a mixture of 50 to 100 parts by weight styrene, .alpha.-methyl styrene, vinyl toluene, methyl methacrylate or mixtures thereof and 0 to 50 parts by weight acrylonitrile on a particulate acrylate rubber with a mean particle diameter (d.sub.50) of from 0.05 to 1.00 .mu.m having a total rubber content of 30 to 80% by weight.
摘要翻译： （A）5至95重量％的50至100重量份苯乙烯，α-甲基苯乙烯，乙烯基甲苯，甲基丙烯酸甲酯或其混合物和0至50重量份丙烯腈的混合物的接枝产物的成型化合物 平均粒径（d50）为0.10〜0.50μm，总橡胶含量为30〜90重量％的颗粒状硅橡胶，（B）95〜5重量％的 50至100重量份的苯乙烯，α-甲基苯乙烯，乙烯基甲苯，甲基丙烯酸甲酯或其混合物，以及0至50重量份的丙烯腈在平均粒径（d50）为0.05至1.00微米的丙烯酸甲酯橡胶上具有 总橡胶含量为30〜80重量％。
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公开(公告)号：US5274032A
公开(公告)日：1993-12-28
申请号：US435058
申请日：1989-11-13
CPC分类号： C08L51/04 , C08L51/085
摘要： Moulding compositions comprisingA) from 5 to 95% by weight of a graft product of a mixture of from 50 to 100 parts by weight of styrene, .alpha.-methylstyrene, vinyl toluene, methyl methacrylate or mixtures thereof and from 0 to 50 parts by weight of acrylonitrile on a particulate silicone rubber having an average particle diameter (d.sub.50) of from 0.10 to 0.50 .mu.m with a total rubber content of from 30 to 90% by weight andB) from 95 to 5% by weight of a graft product of a mixture of from 50 to 100 parts by weight of styrene, .alpha.-methylstyrene, vinyl toluene, methyl methacrylate or mixtures thereof and from 0 to 50 parts by weight of acrylonitrile on a particulate EPDM rubber having an average particle diameter (d.sub.50) of from 0.20 to 1.00 .mu.m with a total rubber content of from 10 to 50% by weight.
摘要翻译： 包含A）5至95重量％的50至100重量份苯乙烯，α-甲基苯乙烯，乙烯基甲苯，甲基丙烯酸甲酯或其混合物的混合物的接枝产物和0至50重量份的成型组合物 丙烯腈在平均粒径（d50）为0.10〜0.50μm，总橡胶含量为30〜90重量％的粒状硅橡胶上的丙烯腈，B）95〜5重量％的 50至100重量份苯乙烯，α-甲基苯乙烯，乙烯基甲苯，甲基丙烯酸甲酯或其混合物和0至50重量份丙烯腈的混合物，其平均粒径（d50）为 0.20〜1.00μm，总橡胶含量为10〜50重量％。
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4.发明授权High-notched-impact core-shell polymers having improved weather resistance 失效具有改进的耐候性的高切口冲击的核 - 壳聚合物
公开(公告)号：US4393172A
公开(公告)日：1983-07-12
申请号：US309569
申请日：1981-10-08
IPC分类号： C08F279/00 , C08F279/02 , C08F285/00 , C08L51/04 , C08F265/04
CPC分类号： C08F279/02 , Y10S525/902
摘要： A particulate graft polymer comprising (a) a core formed by a crosslinked homopolymer of a conjugated diene or a copolymer thereof with up to 10% by weight of styrene or acrylonitrile; (b) a first shell formed by a crosslinked homopolymer of an acrylic acid alkyl ester or a copolymer thereof with up to 30% by weight of vinyl monomers; (c) a second shell formed by a polymer of resin-forming monomers, a process for manufacturing these graft polymers by means of a multi-stage emulsion polymerization, and their application as molding compositions, optionally together with rigid thermoplastic resins.
摘要翻译： 一种颗粒状接枝聚合物，其包含（a）由共轭二烯的交联均聚物或其共聚物与至多10重量％的苯乙烯或丙烯腈的交联均聚物形成的芯; （b）由丙烯酸烷基酯的交联均聚物或其共聚物与至多30重量％的乙烯基单体形成的第一壳; （c）由树脂形成单体的聚合物形成的第二壳，通过多阶段乳液聚合制造这些接枝聚合物的方法，以及它们作为模塑组合物，任选地与刚性热塑性树脂一起使用。
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公开(公告)号：US5183850A
公开(公告)日：1993-02-02
申请号：US633028
申请日：1990-12-24
IPC分类号： C08F261/06 , C08F261/00 , C08F265/00 , C08F265/04 , C08F271/02 , C08L51/00 , C08L51/06 , C08L101/00
CPC分类号： C08L51/003 , C08F271/02 , C08L101/00 , C08L2201/02
摘要： Graft polymers ofa) 5 to 95% by weight of a copolymer of 20 to 60% by weight of a 1,3,5-triazine derivative corresponding to formula (I) ##STR1## in which R=H, C.sub.1-2 alkyl, and 40 to 80% by weight of other vinyl monomers as the graft base andb) 5 to 95% by weight of a thermoplastic polymer as the graft shell,their use as thermoplastic molding compounds and as flame-proofing agents for other synthetic materials.
摘要翻译： 接枝聚合物，a）5至95重量％的20至60重量％的对应于式（I）的1,3,5-三嗪衍生物的共聚物，其中R = H，C1-2 烷基和40〜80重量％的其它乙烯基单体作为接枝基，b）5〜95重量％的作为接枝壳的热塑性聚合物，它们作为热塑性成型化合物的用途和用于其它合成的阻燃剂 材料
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公开(公告)号：US5071921A
公开(公告)日：1991-12-10
申请号：US426460
申请日：1989-10-20
申请人： Herbert Eichenauer , Christian Lindner , Edgar Leitz , Karl-Heinz Ott , Hans-Josef Buysch , Peter Mues , Hartwig Hocker , Helmut Keul
发明人： Herbert Eichenauer , Christian Lindner , Edgar Leitz , Karl-Heinz Ott , Hans-Josef Buysch , Peter Mues , Hartwig Hocker , Helmut Keul
摘要： Thermoplastic block copolymers of the idealized formulae (I)A--B--A; B--A--B or (A--B).sub.x (I)in whichx=1 to 40,and whereinA is the radical of a homopolymer of styrene, vinylnaphthalene, butadiene and isoprene, andB the radical of a homopolymer of a cyclic polycarbonate or lactone,the average molecular weight of blocks A and B being greater than 800, and a process for the preparation of these blocks copolymers in several reaction stages.
摘要翻译： 理想化的式（I）A-B-A的热塑性嵌段共聚物; BAB或（AB）x（I），其中x = 1-40，并且其中A是苯乙烯，乙烯基萘，丁二烯和异戊二烯的均聚物的基团，B是环状聚碳酸酯或内酯的均聚物的基团， 嵌段A和B的平均分子量大于800，以及在几个反应阶段制备这些嵌段共聚物的方法。
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公开(公告)号：US4968750A
公开(公告)日：1990-11-06
申请号：US427935
申请日：1989-10-25
IPC分类号： C08G77/442
CPC分类号： C08G77/442
摘要： Block copolymers composed of recurrent structural units belonging to the series comprising polysiloxanes and recurring structural units belonging to the series comprising homopolymers, copolymers or terpolymers of vinyl-aromatic compounds and acrylic monomers of mixtures thereof.
摘要翻译： 由属于包含聚硅氧烷的系列的复发结构单元和属于该系列的重复结构单元组成的嵌段共聚物包括乙烯基芳族化合物的均聚物，共聚物或三元共聚物和其混合物的丙烯酸单体。
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公开(公告)号：US4865917A
公开(公告)日：1989-09-12
申请号：US203988
申请日：1988-06-08
IPC分类号： C08F283/12 , C08F285/00
CPC分类号： C08F285/00 , Y10S525/902 , Y10T428/2998 , Y10T428/31536
摘要： Thermoplastic particulate graft polymers comprising particles of a core (A) of an organic resin-like polymer of olefinically unsaturated monomers having softening temperatures (glass temperatures) above 30.degree. C., a shell polymer (B) or ogranopolysiloxane and a polymer (C) of at least one .alpha.,.beta.-unsaturated olefinic monomer grafted onto the particles consisting of A and B and their use as thermoplastic molding compositions.
摘要翻译： 包含软化温度（玻璃温度）高于30℃的烯属不饱和单体的有机树脂状聚合物的芯（A），壳聚合物（B）或聚异氰酸聚硅氧烷和聚合物（C））的颗粒的热塑性颗粒接枝聚合物， 的至少一种接枝到由A和B组成的颗粒上的α，β-不饱和烯烃单体及其作为热塑性模塑组合物的用途。
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公开(公告)号：US4771109A
公开(公告)日：1988-09-13
申请号：US17729
申请日：1987-02-24
IPC分类号： C08F285/00 , C08F287/00 , C08L51/08
CPC分类号： C08F287/00
摘要： Graft polymers of vinyl monomers or vinyl monomer mixtures on block copolymers of recurring structural units from the polysiloxane series and recurring structural units from the series comprising homo- and copolymers of conjugated dienes as grafting bases.
摘要翻译： 乙烯基单体或乙烯基单体混合物的接枝聚合物与来自聚硅氧烷系列的重复结构单元的嵌段共聚物和包含共轭二烯作为接枝基的均聚物和共聚物的重复结构单元的接枝聚合物。
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公开(公告)号：US4699967A
公开(公告)日：1987-10-13
申请号：US820067
申请日：1986-01-21
CPC分类号： C08G77/445 , C08G77/46
摘要： Block copolymers of recurring structural units of the series of polysiloxanes and recurring structural units of the series of aliphatic polyesters, polyethers or polyetheresters with rubber properties, the polymeric block-forming polymers in each case producing rubber-type products with glass transition temperatures below practical temperatures of use and a process for the production thereof.
摘要翻译： 一系列聚硅氧烷的重复结构单元和具有橡胶性能的脂族聚酯，聚醚或聚醚酯系列的重复结构单元的嵌段共聚物，每种情况下的聚合物嵌段形成聚合物生产玻璃化转变温度低于实际温度的橡胶类产品 的用途及其生产方法。
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