Modified polyolefin resin composition and uses thereof
    1.
    发明申请
    Modified polyolefin resin composition and uses thereof 有权
    改性聚烯烃树脂组合物及其用途

    公开(公告)号:US20010036997A1

    公开(公告)日:2001-11-01

    申请号:US09805999

    申请日:2001-03-15

    Abstract: The invention provides a novel chlorine-free modified polyolefin resin composition with excellent adherence to nonpolar substrates, with excellent solubility into solvent and compatibility with other resins, and with no tack after painting and drying. It relates to a modified polyolefin resin composition obtainable by graft modifying a mixed resin comprising 40 to 99 parts by weight of polyolefin resin (A) and 1 to 60 parts by weight of ethylenic compound-unsaturated carboxylic acid copolymer (B) that contains 0.1 to 50% by weight of unsaturated carboxylic acid derivative, with unsaturated carboxylic acid derivative and/or its anhydride (C), the modified polyolefin resin composition having weight average molecular weight of 20,000 to 150,000 and the grafting weight of (C) being 0.1 to 20% by weight.

    Abstract translation: 本发明提供了一种对非极性基材具有优异粘附性,对溶剂具有优异溶解性和与其它树脂相容性的新型无氯改性聚烯烃树脂组合物,并且在涂漆和干燥后无粘性。 本发明涉及一种改性聚烯烃树脂组合物,其通过将包含40〜99重量份的聚烯烃树脂(A)和1〜60重量份含有0.1〜10重量份的烯属化合物 - 不饱和羧酸共聚物(B)的混合树脂 50重量%的不饱和羧酸衍生物与不饱和羧酸衍生物和/或其酸酐(C)的重均分子量为20,000〜150,000的改性聚烯烃树脂组合物,(C)的接枝重量为0.1〜20 重量%。

    Graft copolymers of unsaturated monomers and polyhydroxy compounds, a
process for their production and their use
    2.
    发明授权
    Graft copolymers of unsaturated monomers and polyhydroxy compounds, a process for their production and their use 失效
    不饱和单体和多羟基化合物的接枝共聚物,其生产方法及其用途

    公开(公告)号:US5760154A

    公开(公告)日:1998-06-02

    申请号:US392791

    申请日:1995-02-28

    Abstract: The present invention relates to water-soluble, acid groups-containing graft copolymers which are at least partially biodegradable and are based on polyhydroxy compounds and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing said graft copolymers at temperatures of up to 200.degree. C. by means of radical polymerization initiators, in that a total mixture is polymerized which consists of 1-60%-wt. of polyhydroxy compounds, their derivatives or their mixtures, and 95-40%-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers. The present invention further relates to the use of the graft copolymers in aqueous systems, for binding multivalent metal ions, inhibiting the water hardness, as additive in detergents and cleaning agents, as textile auxiliary, dispersing agent, in particular for pigments, and as auxiliary agent in the production of paper and leather.

    Abstract translation: PCT No.PCT / EP94 / 04187 Sec。 371日期1995年2月28日 102(e)1995年2月28日PCT PCT 1994年12月16日PCT公布。 公开号WO95 / 17444 日期:1995年6月29日本发明涉及至少部分可生物降解且基于多羟基化合物和单烯键式不饱和羧酸,磺酸和/或膦酸或所述盐酸的盐的水溶性含酸基接枝共聚物 酸以及任选的其它单体。 本发明还涉及一种通过自由基聚合引发剂在高达200℃的温度下生产所述接枝共聚物的方法,因为总共混合物由1-60重量% 的多羟基化合物,其衍生物或其混合物,和95-40重量% 包含至少一种单烯属不饱和羧酸,至少一种单烯属不饱和磺酸,一个单烯属不饱和硫酸酯和/或乙烯基膦酸或所述酸与一价阳离子的盐的单体混合物,以及任选的其它单体。 本发明还涉及在水系统中用于结合多价金属离子,抑制水硬度,作为洗涤剂和清洁剂中的添加剂的用途,作为纺织助剂,分散剂,特别是颜料和助剂 代理生产纸和皮革。

    Methods of making reversible crosslinked polymers and related methods
    5.
    发明申请
    Methods of making reversible crosslinked polymers and related methods 有权
    制备可逆交联聚合物的方法及相关方法

    公开(公告)号:US20110015350A1

    公开(公告)日:2011-01-20

    申请号:US12460350

    申请日:2009-07-17

    Abstract: Methods are provided for making reversible crosslinked polymers. Exemplary methods comprise reacting first and second thermoplastic polymers having non-hindered olefins in the presence of a metathesis catalyst under conditions sufficient to form a crosslinked polymer. In certain embodiments, the methods comprise providing a crosslink promoting additive to improve the strength of the crosslinked polymer. In some embodiments, the methods comprise decrosslinking a crosslinked polymer through a metathesis or an ozonolysis reaction.

    Abstract translation: 提供了制备可逆交联聚合物的方法。 示例性方法包括在易位形成催化剂存在下,在足以形成交联聚合物的条件下使具有非阻碍烯烃的第一和第二热塑性聚合物反应。 在某些实施方案中,所述方法包括提供交联促进添加剂以改善交联聚合物的强度。 在一些实施方案中,所述方法包括通过复分解或臭氧分解反应将交联的聚合物交联。

    Near-net-shape polymerization process and materials suitable for use therewith
    6.
    发明授权
    Near-net-shape polymerization process and materials suitable for use therewith 失效
    近网状聚合方法和适合与其一起使用的材料

    公开(公告)号:US07173089B2

    公开(公告)日:2007-02-06

    申请号:US10083316

    申请日:2002-02-25

    Abstract: This invention is directed to a processing approach for the rapid and efficient in-situ polymerization of specially prepared precursor mixtures to achieve near-net-shape production of objects/articles with exact dimensions. The process relies on the use of polymerizable compositions comprised of a mixture of a dead polymer, a reactive plasticizer and, optionally, an initiator, which compositions are semi-solid-like prior to curing and induce low shrinkage upon curing as a result of their partially polymerized nature prior to processing. The partially polymerized nature of the precursor mixtures also allows extremely impact-resistant objects/articles to be fabricated. Other desirable engineering property attributes can similarly be achieved via the judicious blending of starting ingredients in formulating the polymerizable (curable) mixtures.

    Abstract translation: 本发明涉及用于快速和有效地原位聚合特殊制备的前体混合物以实现具有精确尺寸的物体/制品的近净形状的处理方法。 该方法依赖于使用由固化聚合物,反应性增塑剂和任选的引发剂组成的可聚合组合物,该组合物在固化之前是半固体状的,并且由于它们的固化而在固化时诱导低收缩率 在加工前部分聚合的性质。 前体混合物的部分聚合性质还允许制造极其耐冲击的物体/制品。 可以通过在配制可聚合(可固化)混合物中明智地混合起始成分来实现其它所需的工程特性属性。

    Method of making a polymer blend composition by reactive extrusion
    9.
    发明申请
    Method of making a polymer blend composition by reactive extrusion 有权
    通过反应性挤出制备聚合物共混物组合物的方法

    公开(公告)号:US20020128384A1

    公开(公告)日:2002-09-12

    申请号:US09753223

    申请日:2000-12-29

    Abstract: The present invention is a hydrolytically modified, biodegradable polymer and a method of making a hydrolytically modifiable a biodegradable polymer. In a preferred embodiment, the invention is a method of grafting polar groups onto biodegradable polymers and modified biodegradable polymer compositions produced by the method. The polymer compositions are useful as components in flushable and degradable articles. Water-sensitive polymer blends and method of making those polymer blends are also disclosed.

    Abstract translation: 本发明是一种水解改性的可生物降解的聚合物和一种可水解改性的可生物降解的聚合物的方法。 在优选的实施方案中,本发明是将极性基团接枝到可生物降解的聚合物上的方法,以及通过该方法制备的改性的可生物降解的聚合物组合物 聚合物组合物可用作可冲洗和可降解制品中的组分。 还公开了水敏聚合物共混物和制备这些聚合物共混物的方法。

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