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公开(公告)号：US08987987B2
公开(公告)日：2015-03-24
申请号：US13879204
申请日：2011-10-05
CPC分类号： H05B33/12 , H01L51/5231 , H01L51/5271 , H05B33/10
摘要： The invention provides an OLED device with improved light out-coupling, which can be manufactured easy and reliable at low costs, which comprises an electroluminescent layer stack (2, 3, 4) on top of a substrate (1), where the electroluminescent layer stack (2, 3, 4) comprises an organic light-emitting layer stack (3) with one or more organic layers sandwiched between a first electrode (2) facing towards the substrate (1) and a 10 second electrode (4), where the second electrode (4) comprises a layer stack of at least a transparent conductive protection layer (41) on top of the organic light-emitting layer stack (3), a transparent organic conductive buckling layer (42) on top of the protection layer (41) having a glass transition temperature lower than the lowest glass transition temperature of the organic layers within the organic light-emitting layer stack (3) and a stress inducing layer 15 (43) on top of the buckling layer (42) to introduce stress to the buckling layer (42). The invention further relates to a method to manufacture such OLED devices with heating the electroluminescent layer (2, 3, 4) stack to a temperature, which is above the glass transition temperature of the buckling layer (42) and below the lowest glass transition temperature of the organic layers within the organic light-emitting layer stack (3) for a time period sufficient 20 to obtain buckles (B) within the buckling layer (42).
摘要翻译： 本发明提供了具有改进的光输出耦合的OLED器件，其可以以低成本制造得容易和可靠，其包括在衬底（1）的顶部上的电致发光层堆叠（2,3,4），其中电致发光层 叠层（2,3,4）包括有机层（3），其中一个或多个有机层夹在面向基板（1）的第一电极（2）和10第二电极（4）之间，其中 第二电极（4）包括在有机发光层堆叠（3）的顶部上的至少透明导电保护层（41）的层叠层，在保护层顶部的透明有机导电屈曲层（42） （41），其玻璃化转变温度低于有机发光层叠层（3）内的有机层的最低玻璃化转变温度和在屈曲层（42）的顶部的应力诱导层15（43），以引入 对屈曲层（42）的应力。 本发明还涉及通过将电致发光层（2,3,4）堆叠加热到高于屈曲层（42）的玻璃化转变温度并低于最低玻璃化转变温度的温度来制造这种OLED器件的方法 在有机发光层堆叠（3）内的有机层的时间间隔足够20以获得屈曲层（42）内的带扣（B）。
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公开(公告)号：US20130293095A1
公开(公告)日：2013-11-07
申请号：US13879204
申请日：2011-10-05
CPC分类号： H05B33/12 , H01L51/5231 , H01L51/5271 , H05B33/10
摘要： The invention provides an OLED device with improved light out-coupling, which can be manufactured easy and reliable at low costs, which comprises an electroluminescent layer stack (2, 3, 4) on top of a substrate (1), where the electroluminescent layer stack (2, 3, 4) comprises an organic light-emitting layer stack (3) with one or more organic layers sandwiched between a first electrode (2) facing towards the substrate (1) and a 10 second electrode (4), where the second electrode (4) comprises a layer stack of at least a transparent conductive protection layer (41) on top of the organic light-emitting layer stack (3), a transparent organic conductive buckling layer (42) on top of the protection layer (41) having a glass transition temperature lower than the lowest glass transition temperature of the organic layers within the organic light-emitting layer stack (3) and a stress inducing layer 15 (43) on top of the buckling layer (42) to introduce stress to the buckling layer (42). The invention further relates to a method to manufacture such OLED devices with heating the electroluminescent layer (2, 3, 4) stack to a temperature, which is above the glass transition temperature of the buckling layer (42) and below the lowest glass transition temperature of the organic layers within the organic light-emitting layer stack (3) for a time period sufficient 20 to obtain buckles (B) within the buckling layer (42).
摘要翻译： 本发明提供了具有改进的光输出耦合的OLED器件，其可以以低成本制造得容易和可靠，其包括在衬底（1）的顶部上的电致发光层堆叠（2,3,4），其中电致发光层 叠层（2,3,4）包括有机层（3），其中一个或多个有机层夹在面向基板（1）的第一电极（2）和10第二电极（4）之间，其中 第二电极（4）包括在有机发光层堆叠（3）的顶部上的至少透明导电保护层（41）的层叠层，在保护层顶部的透明有机导电屈曲层（42） （41），其玻璃化转变温度低于有机发光层叠层（3）内的有机层的最低玻璃化转变温度和在屈曲层（42）的顶部的应力诱导层15（43），以引入 对屈曲层（42）的应力。 本发明还涉及通过将电致发光层（2,3,4）堆叠加热到高于屈曲层（42）的玻璃化转变温度并低于最低玻璃化转变温度的温度来制造这种OLED器件的方法 在有机发光层堆叠（3）内的有机层的时间间隔足够20以获得屈曲层（42）内的带扣（B）。
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公开(公告)号：US08963143B2
公开(公告)日：2015-02-24
申请号：US13883797
申请日：2011-11-03
CPC分类号： H01L51/5203 , H01L51/0067 , H01L51/506 , H01L51/5064 , H01L51/5076 , H01L51/508 , H01L51/5084 , H01L51/56
摘要： The invention provides an OLED device with improved light out-coupling comprising an electroluminescent layer stack (2) on top of a substrate (1), where the electroluminescent layer stack (2) comprises an organic light-emitting layer stack (6) with one or more organic layers sandwiched between a first electrode (3) facing towards the substrate (1) and a second electrode (7) to apply a driving voltage to the organic light-emitting layer stack (6), and a first electron transport layer stack (4a) arranged between the organic light emitting layers stack (6) and the second electrode (7), wherein the electron transport layer stack (4a) comprises an electron transport layer (41) made of a first electron transport material having a low refractive index and at least one n-doped layer (40, 42). The invention further relates to a method to manufacture these OLED devices.
摘要翻译： 本发明提供了一种具有改进的光输出耦合的OLED器件，其包括在衬底（1）的顶部上的电致发光层堆叠（2），其中电致发光层堆叠（2）包括有机发光层堆叠（6） 或更多的夹在面向基板（1）的第一电极（3）和有机发光层叠层（6）之间施加驱动电压的第二电极（7）的有机层，以及第一电子传输层堆叠 （4a），其布置在有机发光层堆叠（6）和第二电极（7）之间，其中电子传输层堆叠（4a）包括由具有低折射率的第一电子传输材料制成的电子传输层（41） 指数和至少一个n掺杂层（40,42）。 本发明还涉及制造这些OLED器件的方法。
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公开(公告)号：US20130285027A1
公开(公告)日：2013-10-31
申请号：US13883797
申请日：2011-11-03
CPC分类号： H01L51/5203 , H01L51/0067 , H01L51/506 , H01L51/5064 , H01L51/5076 , H01L51/508 , H01L51/5084 , H01L51/56
摘要： The invention provides an OLED device with improved light out-coupling comprising an electroluminescent layer stack (2) on top of a substrate (1), where the electroluminescent layer stack (2) comprises an organic light-emitting layer stack (6) with one or more organic layers sandwiched between a first electrode (3) facing towards the substrate (1) and a second electrode (7) to apply a driving voltage to the organic light-emitting layer stack (6), and a first electron transport layer stack (4a) arranged between the organic light emitting layers stack (6) and the second electrode (7), wherein the electron transport layer stack (4a) comprises an electron transport layer (41) made of a first electron transport material having a low refractive index and at least one n-doped layer (40, 42). The invention further relates to a method to manufacture these OLED devices.
摘要翻译： 本发明提供了一种具有改进的光输出耦合的OLED器件，其包括在衬底（1）的顶部上的电致发光层堆叠（2），其中电致发光层堆叠（2）包括有机发光层堆叠（6） 或更多的夹在面向基板（1）的第一电极（3）和有机发光层叠层（6）之间施加驱动电压的第二电极（7）的有机层，以及第一电子传输层堆叠 （4a），其布置在有机发光层堆叠（6）和第二电极（7）之间，其中电子传输层堆叠（4a）包括由具有低折射率的第一电子传输材料制成的电子传输层（41） 指数和至少一个n掺杂层（40,42）。 本发明还涉及制造这些OLED器件的方法。
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公开(公告)号：US09157023B2
公开(公告)日：2015-10-13
申请号：US10579413
申请日：2004-11-08
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H01L51/5036
摘要： The invention relates to a light-emitting device comprising at least a substrate, an anode, a light-emitting layer and a cathode whereby the light-emitting layer contains an iridium complex IrL3 and whereby at least two ligands L are a dibenzoquinoline. The invention relates in particular to the complexes Ir(dibenzo[f,h]quinoline)2(pentane-2,4-dionate) and Ir(dibenzo[f,h]quinoline)3 which emit light with a wavelength of λmax=545 nm and λmax=595 nm respectively.
摘要翻译： 本发明涉及一种发光器件，其至少包括衬底，阳极，发光层和阴极，由此发光层含有铱络合物IrL 3，由此至少两个配体L是二苯并喹啉。 本发明特别涉及发射波长λmax= 545的光的络合物Ir（二苯并[f，h]喹啉）2（戊烷-2,4-二酸盐）和Ir（二苯并[f，h]喹啉） nm，λmax= 595nm。
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公开(公告)号：US20080030125A1
公开(公告)日：2008-02-07
申请号：US10579413
申请日：2004-11-08
IPC分类号： H01J1/62
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H01L51/5036
摘要： The invention relates to a light-emitting device comprising at least a substrate, an anode, a light-emitting layer and a cathode whereby the light-emitting layer contains an irndium complex IrL3 and whereby at least two ligands L are a dibenzoquinoline. The invention relates in particular to the complexes Ir(dibenzo[f,h]quinoline)2(pentane-2,4-dionate) and Ir(dibenzo[f,h]quinoline)3 which emit light with a wavelength of λmax=545 nm and λmax=595 nm respectively.
摘要翻译： 本发明涉及一种发光器件，其至少包括衬底，阳极，发光层和阴极，由此发光层含有铱络合物IrL 3 N 3，由此至少两个 配体L是二苯并喹啉。 本发明特别涉及络合物Ir（二苯并[f，h]喹啉）2（戊烷-2,4-二酸盐）和Ir（二苯并[f，h]喹啉）3 其分别发射波长λλmax = 545nm和λmax max = 595nm的光。
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7.发明授权Silyl- and heteroatom-substituted compounds selected from carbazoles, dibenzofurans, dibenzothiophenes and dibenzophospholes, and use thereof in organic electronics 有权选自咔唑，二苯并呋喃，二苯并噻吩和二苯并膦酸的硅烷基和杂原子取代的化合物及其在有机电子公开(公告)号：US09458182B2
公开(公告)日：2016-10-04
申请号：US13143651
申请日：2009-12-14
申请人： Nicolle Langer , Christian Schildknecht , Soichi Watanabe , Evelyn Fuchs , Gerhard Wagenblast , Christian Lennartz , Oliver Molt , Korinna Dormann , Chuanjie Loh , Arvid Hunze , Ralf Krause , Guenter Schmid , Karsten Heuser , Volker van Elsbergen , Herbert Friedrich Boerner , Stefan Kirsch
发明人： Nicolle Langer , Christian Schildknecht , Soichi Watanabe , Evelyn Fuchs , Gerhard Wagenblast , Christian Lennartz , Oliver Molt , Korinna Dormann , Chuanjie Loh , Arvid Hunze , Ralf Krause , Guenter Schmid , Karsten Heuser , Volker van Elsbergen , Herbert Friedrich Boerner , Stefan Kirsch
IPC分类号： H01L51/54 , C08G77/60 , C07D407/10 , C07F7/18 , C07F7/10 , C07F7/08 , C09K11/06 , C07F9/572 , C07F9/655 , C07F9/6553 , C07F9/6568 , H01L51/00 , H01L51/50
CPC分类号： C07F7/0814 , C07F7/0838 , C07F9/5728 , C07F9/65517 , C07F9/655354 , C07F9/65683 , C09K11/06 , H01L51/0072 , H01L51/0073 , H01L51/0074 , H01L51/0094 , H01L51/5016 , H01L51/5096
摘要： The present invention relates to silyl- and heteroatom-substituted compounds selected from carbazoles, dibenzofurans, dibenzothiophenes and disilylbenzophospholes of the formula (I) or (I*), to the use of the compounds of the formula (I) or (I*) in organic electronics applications, preferably in organic light-emitting diodes, to an organic light-emitting diode comprising at least one compound of the formula (I) or (I*), to a light-emitting layer comprising at least one compound of the formula (I) or (I*), to a blocking layer for holes/excitons comprising at least one compound of the formula (I) or (I*), and to an apparatus selected from the group consisting of stationary visual display units, mobile visual display units, illumination units, keyboards, items of clothing, furniture and wallpaper, comprising at least one inventive organic light-emitting diode.
摘要翻译： 本发明涉及式（I）或（I *）的选自咔唑，二苯并呋喃，二苯并噻吩和二甲苯基苯并荧蒽的甲硅烷基和杂原子取代的化合物，用于式（I）或（I *）的化合物， 在有机电子应用中，优选在有机发光二极管中，涉及包含至少一种式（I）或（I *）化合物的有机发光二极管，其包含至少一种化合物 式（I）或（I *）表示的化合物与包含至少一种式（I）或（I *）的化合物的空穴/激子的阻挡层，以及选自静止的视觉显示单元， 移动视觉显示单元，照明单元，键盘，衣物，家具和壁纸，包括至少一个本发明的有机发光二极管。
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公开(公告)号：US09392649B2
公开(公告)日：2016-07-12
申请号：US13805172
申请日：2011-06-15
申请人： Herbert Friedrich Boerner , Rainald Manfred Gierth , Stefan Peter Grabowski , Petrus Cornelis Paulus Bouten , Peter Van de Weijer
发明人： Herbert Friedrich Boerner , Rainald Manfred Gierth , Stefan Peter Grabowski , Petrus Cornelis Paulus Bouten , Peter Van de Weijer
CPC分类号： H01L51/525 , H01L51/524 , H01L51/5246 , H01L51/5259 , H01L2251/55 , H05B33/04 , H05B33/14
摘要： An organic electroluminescence device (OLED) has a substrate, a first electrode layer, a layer of organic electroluminescence material, a second electrode layer, a cover layer, a moisture-absorber and a separating foil of resilient material. The separating foil is positioned between the second electrode layer and the moisture-absorber. Spacer structures such as dots are applied on the separating foil between the foil and the cover.
摘要翻译： 有机电致发光器件（OLED）具有衬底，第一电极层，有机电致发光材料层，第二电极层，覆盖层，吸湿剂和弹性材料的分离箔。 分离箔位于第二电极层和吸湿剂之间。 诸如点之类的间隔结构被施加在箔和盖之间的分离箔上。
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9.发明授权Organometallic complexes which emit in the red to green spectral region and their use in OLEDs 有权在红色到绿色光谱区域发射的有机金属配合物及其在OLED中的应用公开(公告)号：US08455112B2
公开(公告)日：2013-06-04
申请号：US12594429
申请日：2008-04-04
CPC分类号： C07D277/66 , C07D231/12 , C07D249/08 , C07D261/08 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016
摘要： Organometallic complexes which bear at least one ligand which has a unit having a triplet energy of at least 22 000 cm−1, a process for preparing the organometallic complexes, a mixture comprising at least one of these organometallic complexes, the use of the organometallic complexes or of the mixture in organic light-emitting diodes, the organometallic complexes preferably being used as emitter materials, and specific nitrogen- or phosphorus-substituted triphenylene derivatives and a process for their preparation, the organometallic complex including a monoanionic bidentate ligand of formula (IIa)
摘要翻译： 具有至少一个具有至少22000cm -1的三线态能量的单元的配体的有机金属络合物，制备有机金属络合物的方法，包含这些有机金属络合物中的至少一种的混合物，使用有机金属络合物 或有机发光二极管中的混合物，有机金属络合物优选用作发射体材料，以及特定的氮或磷取代的三亚苯衍生物及其制备方法，所述有机金属络合物包括式（IIa）的单阴离子二齿配体 ）
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公开(公告)号：US08334651B2
公开(公告)日：2012-12-18
申请号：US13146945
申请日：2010-01-27
IPC分类号： H05B33/14
CPC分类号： H01L51/5203 , H01L51/5212
摘要： The invention relates to an electroluminescent device (10) comprising a substrate (40) and on top of the substrate (40) a substrate electrode (20), a counter electrode (30) and an electroluminescent layer stack with at least one organic electroluminescent layer (50) arranged between the substrate electrode (20) and the counter electrode (30), and at least one electrical shunt means (122) applied on top of the substrate electrode (20) to improve the current distribution over the substrate electrode (20), wherein the at least one electrical shunt means (122) is at least one element of the group of a wire, a metallic stripe or foil, said electrical shunt means (122) fixed to the substrate electrode (20) by a protective means (70) fully covering the electrical shunt means (122) with a shape suitable to prevent the emergence of a shadowing edge on the substrate electrode (20). The invention further relates to a method to manufacture such a device.
摘要翻译： 本发明涉及一种电致发光器件（10），其包括衬底（40），并且在衬底（40）的顶部上具有衬底电极（20），对电极（30）和具有至少一个有机电致发光层 （50），布置在基板电极（20）和对电极（30）之间，以及至少一个电分路装置（122），其施加在基板电极（20）的顶部上，以改善基板电极（20）上的电流分布 ），其中所述至少一个电分路装置（122）是所述一组电线，金属条或箔的至少一个元件，所述电分路装置（122）通过保护装置固定到所述基板电极（20） （70）以适于防止在基板电极（20）上出现阴影边缘的形状完全覆盖电分路装置（122）。 本发明还涉及制造这种装置的方法。
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