摘要:
Process for dyeing hydrophobic fibre materials, preferably polyester fibres, using dyestuffs of the formula ##STR1## wherein THE AROMATIC RINGS A and B can be further substituted,The azo group is in the meta-position or para-position relative to the amino group of the diphenylamine and the phenolic hydroxyl group is in the ortho-position or para-position relative to the azo group.These dyestuffs are distinguished by high drawing power and good building up and fastness properties.
摘要:
The reduction of azoxybenzene, azobenzenes and mixtures of azoxybenzenes and azobenzene to the hydrazobenzenes is possible under mild conditions, with high yields and without any great excess of reducing agents in the presence of raney-nickel and compounds which have an alkaline action with hydrogen or hydrazine hydrate.
摘要:
Azo dyestuffs free of sulphonic acid groups and carboxylic acid groups are prepared by coupling a diazo compound with a coupler which is prepared by reacting an organic amine with a pyridinium salt having the formula ##STR1## IN WHICH R is substituted or unsubstituted alkyl, cycloalkyl, aralkyl or aryl; andR.sub.1 is substituted or unsubstituted alkyl or aralkyl. The dyestuffs are suitable for dyeing and printing synthetic materials such as polyolefines, polyvinyl compounds, cellulose acetate and triacetate and polyesters to give yellow to blue dyeings and prints with good fastness properties especially to light and sublimation.
摘要:
Process for the preparation of diaryl compounds of the formula ##STR1## by reacting of acylamino-aryl-compounds of the formula ##STR2## WITH ARYL COMPOUNDS OF THE FORMULA ##STR3## IN THE PRESENCE OF METALLIC COPPER OR ITS MIXTURE WITH COPPER SALTS, OPTIONALLY IN THE PRESENCE OF CATALYSTS, IN A SOLVENT WHICH IS INERT UNDER THE REACTION CONDITIONS, AT TEMPERATURES OF 20.degree. TO 200.degree. C. In the formulae A and B represent an aromatic ring system, R represents acyl and X represents a nitro, nitrile, carboxylic ester, acyl or --NH--R group.
摘要:
Azo pigments which are free from groups which confer solubility in water and correspond to the formula ##STR1## wherein A represents the radical of a diazo component, X represents a hydroxy, cyanamino, ureido, acylamino or guanidino group and Y and Z independently of one another denote a hydroxyl group or an optionally substituted amino group with the proviso that at most 2 of the 3 radicals X, Y and Z represent a hydroxyl group, are suitable for pigmenting lacquers, for the preparation of printing inks, distempers or paints containing binders and for the bulk dyeing of synthetic, semi-synthetic or natural macromolecular substances.