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公开(公告)号：US5281358A
公开(公告)日：1994-01-25
申请号：US752620
申请日：1991-08-20
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： A deinking agent comprising an ester mixture as the active ingredient, wherein the ester mixture is obtained by adding ethylene oxide and propylene oxide to a mixture obtained by reacting a natural fat or a reaction product, obtained by preliminarily reacting a natural fat with glycerol, with a monohydric or dihydric alcohol in such a manner as to give a molar ratio of the alcohol to the glycerol in the natural fat of from 0.02/1 to 1/1. By using the deinking agent of the present invention, a less sticky deinked pulp can be obtained without any foaming troubles or dulling.
摘要翻译： PCT No.PCT / JP90 / 01367 Sec。 371日期1991年8月20日 102（e）1991年8月20日PCT PCT 1990年10月24日PCT公布。 公开号WO92 / 07996 日本专利公开日199一月12日。一种脱酯剂，其包含酯混合物作为活性成分，其中酯混合物通过将环氧乙烷和环氧丙烷加入到通过使天然脂肪或反应产物反应获得的混合物中获得， 具有甘油的天然脂肪与一元醇或二元醇以使得天然脂肪中醇与甘油的摩尔比为0.02 / 1至1/1的方式。 通过使用本发明的脱墨剂，可以获得较少粘性的脱墨纸浆，而没有任何发泡问题或钝化。
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公开(公告)号：US5120397A
公开(公告)日：1992-06-09
申请号：US515612
申请日：1990-04-27
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： A deinking composition comprising a deinking agent which is a reaction product obtained by:(a) reacting (i) a natural oil or a fat or a reaction product of a natural oil or a fat with glycerine, with (ii) a hexahydric alcohol, wherein the molar ratio of said hexahydric alcohol and glycerine moiety in said natural oil and fat is in the range of between 0.05/1-0.48/1, to obtain an ester mixture having a hydroxyl group value (OHV) of 18-220; and(b) reacting said ester mixture with ethylene oxide and propylene oxide wherein the molar ratio of ethylene oxide to propylene oxide is in the range of between 1.8 and 2.2, and the average mole number of added ethylene oxide is in the range of between 30 and 300, based on the mole number of glycerides present.
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公开(公告)号：US5100574A
公开(公告)日：1992-03-31
申请号：US431187
申请日：1989-11-03
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： A deinking composition comprising a reaction product of a glyceride mixture, derived from natural oil and fat with ethylene oxide and propylene oxide. The glyceride mixture comprises 5 to 10 percent by weight of monoglycerides, 30 to 45 percent by weight of diglycerides and 50 to 70 percent by weight of triglycerides. The reaction product has a molar ratio of ethylene oxide to propylene oxide in the range of 1.8 to 2.2 and has, on average, from 30 to 80 moles of added ethylene oxide per mole of glycerides.
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公开(公告)号：US5288369A
公开(公告)日：1994-02-22
申请号：US796608
申请日：1991-11-22
申请人： Yoichi Ishibashi , Yoshitaka Miyauchi , Koji Hamaguchi , Hideaki Urushibata , Hiromichi Takahashi , Takanobu Shiroishi
发明人： Yoichi Ishibashi , Yoshitaka Miyauchi , Koji Hamaguchi , Hideaki Urushibata , Hiromichi Takahashi , Takanobu Shiroishi
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： A deinking composition for use in the reclamation of waste paper consisting essentially of a mixture of higher fatty acids having 8 to 24 carbon atoms, or salts thereof, wherein the average carbon atom number of said fatty acids in said mixture ranges from 12.7 to 21.5, and wherein the content of higher fatty acids having 20 to 24 carbon atoms or salts thereof, ranges from 9.6 to 70.6% by weight, said mixture having an iodine value (IV) of not greater than 45.
摘要翻译： 用于回收基本上由具有8至24个碳原子的高级脂肪酸的混合物或其盐组成的废纸的脱墨组合物，其中所述混合物中所述脂肪酸的平均碳原子数为12.7至21.5， 并且其中具有20-24个碳原子的高级脂肪酸或其盐的含量为9.6至70.6重量％，所述混合物的碘值（IV）不大于45。
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5.发明授权Deinking composition comprising a fatty acid mixture and a nonionic surfactant 失效包含脂肪酸混合物和非离子表面活性剂的脱墨组合物
公开(公告)号：US5801135A
公开(公告)日：1998-09-01
申请号：US542419
申请日：1995-10-12
CPC分类号： D21C5/027 , Y02W30/648
摘要： A liquid deinking composition comprising (a) a fatty acid mixture containing 40 to 90 weight % of saturated fatty acids having 12 to 14 carbon atoms and less than 60 weight % of saturated fatty acids having 16 to 18 carbon atoms, (b) a nonionic surfactant with HLB of 2 to 12 in a proportion of (a)/(b)=5/95 to 40/60 (weight ratio), and (c) 0 to 20 weight % (based on the composition) of water. No crystals of fatty acids are precipitated at ambient temperatures, and the separation, solidification or precipitation of crystals due to a temperature change is not caused. Further, the handling property is improved because of the liquid form.
摘要翻译： 一种液体脱墨组合物，其包含（a）含有40至90重量％的具有12至14个碳原子且小于60重量％的具有16至18个碳原子的饱和脂肪酸的饱和脂肪酸的脂肪酸混合物，（b）非离子表面活性剂 （a）/（b）= 5/95〜40/60（重量比）和（c）0〜20重量％（基于组成）的HLB为2〜12的表面活性剂。 没有脂肪酸晶体在环境温度下沉淀，并且不会引起由于温度变化引起的晶体的分离，固化或沉淀。 此外，由于液体形式，处理性能得到改善。
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公开(公告)号：US4964949A
公开(公告)日：1990-10-23
申请号：US211172
申请日：1988-06-22
CPC分类号： D21C5/027 , C08G65/2615 , C08L71/02 , Y02W30/648
摘要： A deinking composition is used for reclamation of waste paper and comprises (a) an alkylene oxide adduct to a mixture of a natural oil or fat and a polyhydric alcohol and (b-1) an alkylene oxide adduct of a higher alcohol, (b-2) a sulfate of (b-1) or (b-3) a higher fatty acid.
摘要翻译： 脱墨组合物用于回收废纸，并且包括（a）与天然油或脂肪和多元醇的混合物的烯化氧加合物和（b-1）高级醇的烯化氧加成物，（b- 2）（b-1）或（b-3）硫酸高级脂肪酸。
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公开(公告)号：US06179957B2
公开(公告)日：2001-01-30
申请号：US09101017
申请日：1998-06-29
IPC分类号： D21B108
CPC分类号： D21C5/025 , Y02W30/648
摘要： In a deinking process at least comprising the step of stripping ink from wastepaper as the starting material and the step of removing the stripped ink from a flotation system, the contact angle of the aqueous solution portion of a slurry containing the stripped ink with the interfaces of ink particles in the flotation step is controlled to be at least 70°.
摘要翻译： 在脱墨方法中，至少包括从废纸中除去油墨作为起始原料的步骤和从浮选系统中除去汽提的油墨的步骤，含有汽提油墨的浆料的水溶液部分的接触角与 浮选步骤中的油墨颗粒被控制在至少70°。
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公开(公告)号：US06312559B1
公开(公告)日：2001-11-06
申请号：US08940811
申请日：1997-09-30
IPC分类号： D21C502
CPC分类号： D21C5/027 , Y02W30/648
摘要： There is provided a deinking process carried out using white water according to which an excellent whiteness and an excellent areal ratio of residual ink fines can be secured while maintaining a proper pulp yield. In the deinking process comprising a flotation step wherein use is made of treatment water containing white water, at least part of the flotation step is effected in the presence of at least one compound selected from the group consisting of cationic compounds, amine compounds, acid salts of amine compounds, and ampholytic compounds.
摘要翻译： 提供了使用白水进行脱墨处理，根据该脱墨方法，可以在保持适当的纸浆产率的同时确保残留油墨细粉的优异的白度和优异的面积比。 在包括浮选步骤的脱墨方法中，其中使用含有白水的处理水，至少部分浮选步骤在至少一种选自阳离子化合物，胺化合物，酸盐的化合物存在下进行 的胺化合物和两性化合物。
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公开(公告)号：US5302243A
公开(公告)日：1994-04-12
申请号：US880087
申请日：1992-05-05
申请人： Yoichi Ishibashi , Yoshinao Kono , Yoshitaka Miyauchi , Takanobu Shiroishi , Hiromichi Takahashi
发明人： Yoichi Ishibashi , Yoshinao Kono , Yoshitaka Miyauchi , Takanobu Shiroishi , Hiromichi Takahashi
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： The present invention aims at developing a deinking method applicable to the deinking of, for example, waste OA (office automation) paper and telephone directories, whereby a deinked pulp having a high whiteness and little contamination with large ink spots and unliberated ink can be obtained. The object of the present invention can be achieved by deinking, for example, waste OA paper or telephone directories by using a deinking composition containing as an effective component a reaction mixture (III) obtained by conducting the addition reaction of ethylene oxide and propylene oxide with a mixture (I) comprising a fat and oil (a) and a mono- to hexahydric alcohol (b) and/or with a transesterification mixture (II) obtained by conducting the transesterification reaction of a fat and oil (a) with a mono- to hexahydric alcohol (b), in such a manner that the molar ratio of ethylene oxide to propylene oxide which are used as starting materials ranges from 0.8 to 1.2 and that the molar number of ethylene oxide which is used for the addition reaction ranges from 50 to 100 mol per mole of the fat and oil (a).
摘要翻译： 本发明旨在开发适用于例如废弃OA（办公室自动化）纸和电话簿的脱墨的脱墨方法，由此可以获得具有高白度和少量污染的脱墨纸浆，并且可以获得大的墨点和未起泡的油墨 。 本发明的目的可以通过使用含有作为有效成分的脱墨组合物来脱墨，例如废纸OA或电话簿，通过进行环氧乙烷和环氧丙烷的加成反应获得的反应混合物（III） 包含脂肪和油（a）和一至六元醇（b）的混合物（I）和/或通过脂肪和油（a）与单体（a）进行酯交换反应而获得的酯交换混合物（II） - 以六元醇（b）的形式，使用作为原料的环氧乙烷与环氧丙烷的摩尔比为0.8〜1.2，加成反应所用的环氧乙烷的摩尔数为 每摩尔脂肪和油（a）为50-100摩尔。
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10.发明授权Wastepaper deinking method using amine or acid salt of amine in the flotation stage 失效在浮选阶段使用胺或胺的酸盐进行废纸脱墨方法公开(公告)号：US06251220B1
公开(公告)日：2001-06-26
申请号：US08894715
申请日：1997-08-26
IPC分类号： D21C502
CPC分类号： D21C5/027 , D21C5/025 , Y02W30/648
摘要： A deinking method comprising the steps of liberating ink from waste paper as a raw material and removing the liberated ink from a flotation system, wherein a nonionic surfactant, e.g., a reaction product obtained by adding an alkylene oxide to a mixture of an oil & fat and an alcohol, an alkylene oxide adduct of a fatty acid, or an alkylene oxide adduct of a higher alcohol, is used for the liberation of ink, and the flotation step is effected in the presence of a cationic compound, an amine, an acid salt of an amine or an amphoteric compound at a pH of from 4 to 9, provides a high quality deinked pulp having a high whiteness and a little residual ink spots.
摘要翻译： 一种脱墨方法，包括以下步骤：从作为原料的废纸中释放墨水，并从浮选系统中除去所释放的油墨，其中非离子表面活性剂，例如通过将烯化氧加入到油和油的混合物中获得的反应产物 并且使用醇，脂肪酸的烯化氧加合物或高级醇的烯化氧加成物，用于释放油墨，并且浮选步骤在阳离子化合物，胺，酸的存在下进行 胺或两性化合物的盐在pH为4至9时提供高质量脱墨纸浆，其具有高白度和少量残留油墨斑点。
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