公开(公告)号：US20080300381A1

公开(公告)日：2008-12-04

申请号：US11664281

申请日：2004-09-30

申请人： Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

发明人： Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

IPC分类号： C08G79/00

CPC分类号： H01M4/60 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/602 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/13

摘要： To provide an electrode material excellent in output characteristics and cycle property and an electrochemical device using the electrode material. The electrode material comprising polymer complex compound represented by the following graphical formula: and the electrochemical device using the electrode material. Even if such a large size ion is employed, enhanced output characteristics could be obtained in the present invention. Polymer complex compound is polarized due to an electron attracting substituent, or steric hindrance occurs due to a substituent having a branch structure so that interval of polymer complex compound formed on the electrode is increased and doping reaction. Therefore, even if using large size ions smooth and rapid doping and undoping reaction could take place.

摘要翻译： 提供输出特性和循环特性优异的电极材料和使用电极材料的电化学装置。 该电极材料包含由以下图示式表示的聚合物复合化合物：和使用电极材料的电化学装置。 即使采用这样大的离子，本发明也可以得到增强的输出特性。 聚合物复合化合物由于吸电子取代基而极化，或者由于具有分支结构的取代基而发生空间位阻，使得在电极上形成的聚合物络合物的间隔增加和掺杂反应。 因此，即使使用大尺寸离子，也可以进行平滑，快速的掺杂和非掺杂反应。

公开(公告)号：US20090026085A1

公开(公告)日：2009-01-29

申请号：US11917002

申请日：2005-06-10

申请人： Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

发明人： Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

IPC分类号： C25B3/00

CPC分类号： H01G11/48 ,  H01G11/24 ,  H01G11/28 ,  H01G11/30 ,  H01G11/32 ,  H01G11/86 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/60 ,  H01M4/602 ,  H01M4/606 ,  H01M10/052 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： A method for producing an electrode for an electrochemical element absorbs monomers for polymerization on a surface having a specific surface area of 100 to 3000 m2g−1 and having an average pore diameter in the range of 0.4 to 100 nm, performing electrolysis polymerization by applying pulse voltage, and forming a conductive polymer layer on the surface of the conductive porous material, forming a thin and uniform electrode film. In a method for producing an electrochemical element, a conductive polymer layer is formed on the conductive porous material by absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area and pore diameter as above forming a electrochemical cell by using the conductive porous material, the monomers are absorbed in the pores, putting the electrochemical cell and the electrolyte solution in an outer casing, and performing electrolysis polymerization of the monomers in the electrolyte solution.

摘要翻译： 一种电化学元件用电极的制造方法，在比表面积为100〜3000m 2 / g的表面吸收聚合用单体，平均孔径为0.4〜100nm，通过施加脉冲进行电解聚合 电压，并在导电性多孔材料的表面上形成导电聚合物层，形成薄而均匀的电极膜。 在电化学元件的制造方法中，通过在上述形成电化学电池的比表面积和孔径以上的导电性多孔质材料的表面上吸收用于聚合的单体，在导电性多孔质材料上形成导电性聚合物层， 导电多孔材料，单体被吸收在孔中，将电化学电池和电解质溶液放入外壳中，并进行电解液中单体的电解聚合。

公开(公告)号：US20080213500A1

公开(公告)日：2008-09-04

申请号：US11664286

申请日：2004-09-30

申请人： Hidenori Uchi ,  Kenji Tamamitsu ,  Satori Tsumeda ,  Alexander M. Timonov ,  Sergey Nikolay Shkolnik ,  Sam Kogan

发明人： Hidenori Uchi ,  Kenji Tamamitsu ,  Satori Tsumeda ,  Alexander M. Timonov ,  Sergey Nikolay Shkolnik ,  Sam Kogan

IPC分类号： C08F2/58

CPC分类号： H01G9/155 ,  H01M4/0438 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/602 ,  H01M10/0525 ,  Y02E60/13 ,  Y02T10/7022

摘要： To provide a method for producing an electrode material which is improved in energy density and is excellent in output characteristics. The present invention provides a manufacturing method for the electrode material comprising the steps of: 1) immersing a conductive material having a specific surface area of 200 to 3000 m2g−1 in a complex monomer solution of a transition metal having at least two different oxidation numbers, 2) performing electro polymerization by applying pulse voltage using the conductive material as an electrode to stack the complex monomer under the condition that electrolyzation time is 0.1 to 60 second and a downtime is 10 to 600 second, and 3) forming on the surface of the conductive material an energy accumulating redox polymer layer containing polymer complex compound of transition metal formed by the stacked complex monomer, thereby accumulating energy via a redox reaction: wherein a thin and uniform electrode film is formed, namely the electrode material which is excellent in output characteristics and improves energy density is manufactured according to the method.

摘要翻译： 提供能够提高能量密度且输出特性优异的电极材料的制造方法。 本发明提供一种电极材料的制造方法，包括以下步骤：1）将比表面积为200〜3000μm2〜 在具有至少两个不同氧化数的过渡金属的复合单体溶液中，2）通过使用导电材料作为电极施加脉冲电压来进行电聚合，以在电解时间为0.1至60秒的条件下堆叠复合单体，以及 停机时间为10〜600秒，3）在导电材料的表面上形成能量积聚的氧化还原聚合物层，其含有由层叠的复合单体形成的过渡金属的聚合物络合物，由此通过氧化还原反应积累能量：其中薄 形成均匀的电极膜，即根据该方法制造输出特性优异，能量密度提高的电极材料。

公开(公告)号：US6038124A

公开(公告)日：2000-03-14

申请号：US995967

申请日：1997-12-22

申请人： Hidenori Uchi ,  Masakazu Furukawa ,  Tadao Fujihira ,  Ichizo Tsukuda ,  Eizo Isoyama

发明人： Hidenori Uchi ,  Masakazu Furukawa ,  Tadao Fujihira ,  Ichizo Tsukuda ,  Eizo Isoyama

IPC分类号： H01G9/04 ,  H01G9/055

CPC分类号： H01G9/055

摘要： An aluminum electrode foil for an electrolytic capacitor has a sponge-like etching layer formed on at least one of the surfaces thereof, and the sponge-like etching layer is reduced in a direction of thickness. The aluminum density of the reduced sponge-like etching layer `d2` is set from 0.8 to 2.2 g/cm.sup.3.

摘要翻译： 用于电解电容器的铝电极箔具有形成在其至少一个表面上的海绵状蚀刻层，海绵状蚀刻层在厚度方向上减小。 还原的海绵状蚀刻层“d2”的铝密度设定为0.8〜2.2g / cm 3。