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1.发明授权Image forming method utilizing accelerated desilverization of color photographic material containing magneta coupler 失效使用含有磁性耦合器的彩色照相材料的加速脱色的图像形成方法
公开(公告)号：US4769313A
公开(公告)日：1988-09-06
申请号：US933517
申请日：1986-11-21
申请人： Hiroshi Fujimoto , Shinzo Kishimoto , Akira Abe , Junya Nakajima
发明人： Hiroshi Fujimoto , Shinzo Kishimoto , Akira Abe , Junya Nakajima
CPC分类号： G03C7/42 , G03C7/3825 , G03C7/38
摘要： A method of forming an image comprising, after color developmenmt of an exposed silver halide color photographic material, processing the developed silver halide color photographic material with a bath having a bleaching ability and subsequently with a bath having a bleach-fixing ability, wherein the silver halide color photographic material comprises a support having coated thereon at least one silver halide emulsion layer and at least one pyrazoloazole type magenta coupler represented by the following general formula (A): ##STR1## wherein R.sub.22 represents a hydrogen atom of a substituent; X represents a group capable of being split off upon a coupling reaction with an oxidation product of an aromatic primary amine developing agent; Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--, one of the Za--Zb bond and the Zb--ZC bond being a double bond and the other being a single bond; when the Zb--Zc bond is a carbon-carbon double bond, the Zb--Zc bond may be a part of a condensed aromatic ring; R.sub.22 or X may also form a polymer including a dimer or more; and when Za, Zb or Zc is a substituted methine group, the substituted methine group may form a polymer including a dimer or more. In accordance with the method of forming an image, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained without the formation of magenta stain.
摘要翻译： 一种形成图像的方法，包括在曝光的卤化银彩色照相材料的显影后，用具有漂白能力的浴处理显影的卤化银彩色照相材料，随后用具有漂白定影能力的浴，其中银 卤化物彩色照相材料包括其上涂覆有至少一种卤化银乳剂层和至少一种由以下通式（A）表示的吡唑并唑型品红成色剂的载体：其中R22表示取代基的氢原子 ; X表示与芳族伯胺显影剂的氧化产物偶联反应时能够分离的基团; Za，Zb和Zc各自表示次甲基，取代的次甲基，= N-或-NH-，Za-Zb键和Zb-ZC键之一为双键，另一个为单键; 当Zb-Zc键为碳 - 碳双键时，Zb-Zc键可以是稠合芳环的一部分; R 22或X也可以形成包含二聚体或更多的聚合物; 当Za，Zb或Zc为取代的次甲基时，取代的次甲基可以形成包含二聚体或更多的聚合物。 根据形成图像的方法，在短时间内完成脱银，并且在没有形成品红色污点的情况下获得具有优异色彩再现性和牢度的彩色照相图像。
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2.发明授权Method for processing a silver halide color photographic material including a hydrolyzable type dir coupler including bleaching and bleach-fixing processing 失效包括含有漂白漂白定影处理的可水解型连接器的卤化银彩色照相材料的处理方法
公开(公告)号：US4798784A
公开(公告)日：1989-01-17
申请号：US935494
申请日：1986-11-26
CPC分类号： G03C7/30529 , G03C7/30541 , Y10S430/158
摘要： A method for processing a silver halide color photographic material which comprises, after color development of an exposed silver halide color photographic material containing a hydrolyzable type DIR coupler, rapidly processing the developed silver halide color photographic material with a liquid having a bleaching ability and subsequently with a liquid having a bleach-fixing ability, to thereby form a color image.In accordance with the method for processing a silver halide color photographic material, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained.
摘要翻译： 一种用于处理卤化银彩色照相材料的方法，其包括在含有可水解型DIR成色剂的曝光的卤化银彩色照相材料显色后，用具有漂白能力的液体快速处理显影的卤化银彩色照相材料， 具有漂白定影能力的液体，从而形成彩色图像。 根据卤化银彩色照相材料的处理方法，在短时间内完成脱色，得到色彩再现性和色牢度优异的彩色摄影图像。
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3.发明授权Method of processing silver halide color photographic material including the use of a two bath desilvering system comprising two baths 失效一种处理卤化银彩色照相材料的方法，包括使用包含两个浴的两个浴洗脱系统
公开(公告)号：US4769312A
公开(公告)日：1988-09-06
申请号：US918260
申请日：1986-10-14
申请人： Shinzo Kishimoto , Akira Abe , Junya Nakajima
发明人： Shinzo Kishimoto , Akira Abe , Junya Nakajima
CPC分类号： G03C7/42
摘要： A method of processing silver halide color photographic materials which comprises image-wise exposing said silver halide color photographic materials, color developing and then desilvering them in a bath having bleaching ability, characterized in that the bath having bleaching ability comprises two baths, the oxidation-reduction potential of the first bath being higher than that of the second bath, the oxidation-reduction potential of the second bath falling in the range of +60 mV to -60 mV, the first bath containing a water-soluble bromide in an amount of 0.5 to 1.3 mole/l, and the second bath containing a water-soluble bromide in an amount of 0 to 0.5 mole/l.
摘要翻译： 一种处理卤化银彩色照相材料的方法，其包括使所述卤化银彩色照相材料成像曝光，着色显影，然后在具有漂白能力的浴中将其脱色，其特征在于具有漂白能力的浴液包括两个浴， 第一浴的还原电位高于第二浴，第二浴的氧化还原电位在+60mV至-60mV的范围内，第一浴含有一定量的水溶性溴化物 0.5至1.3摩尔/升，第二浴含有0至0.5摩尔/升的水溶性溴化物。
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4.发明授权
公开(公告)号：US4762774A
公开(公告)日：1988-08-09
申请号：US920138
申请日：1986-10-17
CPC分类号： G03C7/42
摘要： A method for color image formation is disclosed, comprising imagewise exposing to light a silver halide color photographic material having a silver halide emulsion layer containing monodispersed silver halide grains, subjecting the exposed material to color development, and processing the material with a bath primarily having bleaching capacity and then with a bath having bleach-fixing capacity. The method realizes acceleration of desilvering to reduce the processing time.
摘要翻译： 公开了一种用于彩色图像形成的方法，包括将具有含有单分散卤化银颗粒的卤化银乳剂层的卤化银彩色照相材料成像曝光于光，曝光材料进行着色显影，并用主要具有漂白色彩的浴来处理该材料 然后用具有漂白固定能力的浴缸。 该方法实现了脱银加速，缩短了处理时间。
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5.发明授权
公开(公告)号：US4853318A
公开(公告)日：1989-08-01
申请号：US15647
申请日：1987-02-17
IPC分类号： G03C7/413
CPC分类号： G03C7/413
摘要： A process for processing color photographic papers using a color developer substantially free from benzyl alcohol and containing a compound represented by formula (I) ##STR1## wherein Z represents an atomic group forming an aromatic nucleus is disclosed. In the process, the formation of color stains is greatly reduced even in the case of shortening the processing times for the blix step and the wash and/or stabilization step after color development.
摘要翻译： 公开了一种使用基本上不含苄醇并含有式（I）表示的化合物的成像处理彩色相纸的方法，其中Z表示形成芳香核的原子团。 在该过程中，即使在缩短彩色显影之后的双色步骤和洗涤和/或稳定步骤的处理时间的情况下，颜色斑的形成也大大降低。
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公开(公告)号：US4621047A
公开(公告)日：1986-11-04
申请号：US736625
申请日：1985-05-21
申请人： Shinzo Kishimoto , Akira Abe , Shigeru Ohno
发明人： Shinzo Kishimoto , Akira Abe , Shigeru Ohno
摘要： A method for processing a color photographic light-sensitive material comprising subjecting an imagewise exposed silver halide color photographic light-sensitive material to color development processing, then to processing with a bleaching solution and thereafter to separately, fixing processing wherein the silver halide color photographic light-sensitive material contains a cyan dye forming coupler represented by the general formula (I-a) or (I-b) described below, the bleaching solution contains a compound represented by the general formula (II-a) or (II-b) described below and the processing time for the bleaching solution is substantially not more than 2 minutes and 30 seconds, ##STR1## wherein R.sup.1, R.sup.2 and R.sup.4 each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sup.3 and R.sup.6 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aryl group or an acylamino group, or R.sup.3 represents a non-metallic atomic group necessary to form a nitrogen-containing 5-membered or 6-membered ring together with R.sup.2, R.sup.5 presents a substituted or unsubstituted alkyl group; Z.sup.1 and Z.sup.2 each represents a hydrogen atom or a group capable of being released upon the oxidative coupling reaction with a developing agent; and n represents 0 or 1, ##STR2## wherein R.sup.7, R.sup.8, R.sup.9 and R.sup.10, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted lower alkyl group or an acyl group, or R.sup.7, R.sup.8, R.sup.9 and R.sup.10 may connect to each other to form a ring; and m and each represents an integer of 1 to 3.
摘要翻译： 一种用于处理彩色照相感光材料的方法，包括对成像曝光的卤化银彩色照相感光材料进行着色显影处理，然后用漂白溶液处理，然后分别进行定影处理，其中卤化银彩色照相光 感光材料包含由下述通式（Ia）或（Ib）表示的青色染料形成成色剂，漂白溶液含有下述通式（II-a）或（II-b）表示的化合物和 漂白溶液的处理时间基本上不超过2分30秒，其中R 1，R 2和R 4各自表示取代或未取代的脂族基团，取代或未取代的芳基 或取代或未取代的杂环基; R 3和R 6各自表示氢原子，卤素原子，取代或未取代的脂族基团，取代或未取代的芳基或酰基氨基，或R 3表示形成含氮5元素所必需的非金属原子团 或6元环与R2一起，R5表示取代或未取代的烷基; Z1和Z2各自表示氢原子或能够与显影剂进行氧化偶联反应时释放的基团; （II-a）其中R 7，R 8，R 9和R 10可以相同或不同，表示氢原子，取代或未取代的 低级烷基或酰基，或者R 7，R 8，R 9和R 10可以彼此连接形成环; m，m表示1〜3的整数。
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公开(公告)号：US4546070A
公开(公告)日：1985-10-08
申请号：US680115
申请日：1984-12-10
申请人： Shinzo Kishimoto , Shigeru Ohno , Akira Abe
发明人： Shinzo Kishimoto , Shigeru Ohno , Akira Abe
CPC分类号： G03C7/421
摘要： A method for processing a color photographic light-sensitive material comprising subjecting an exposed silver halide color photographic light-sensitive material to color development processing then to bleach processing and fixing processing separately, wherein a bath of the bleach processing contains (a) at least one bleach accelerating agent selected from a compound having a mercapto group or a disulfide bond, a thiazolidine derivative and an isothiourea derivative and (b) at least one compound represented by the following general formula (I-a) or (I-b): ##STR1## wherein M represents a hydrogen atom, an alkali metal atom or an ammonium ion; R represents a hydrogen atom, a substituted or unsubstituted alkyl group, --SO.sub.3 M.sup.1 or --COOM.sup.1 ; R.sup.1 represents --SO.sub.3 M.sup.1 or --COOM.sup.1 ; M.sup.1 represents a hydrogen atom, an alkali metal atom or an ammonium ion; and n represents an integer of 1 to 6 and when n is 2 or more, R's may be the same or different.According to the method of the present invention, color photographic images having good quality can be obtained without the formation of precipitate in a bleaching bath containing the bleach accelerating agent, even when color photographic light-sensitive materials are continuously processed.
摘要翻译： 一种用于处理彩色照相感光材料的方法，包括使暴露的卤化银彩色照相感光材料进行着色显影处理，然后分别漂白处理和定影处理，其中漂白处理浴中含有（a）至少一种 选自具有巯基或二硫键的化合物的漂白促进剂，噻唑烷衍生物和异硫脲衍生物，和（b）至少一种由以下通式（Ia）或（Ib）表示的化合物： （Ib）其中M表示氢原子，碱金属原子或铵离子; R表示氢原子，取代或未取代的烷基，-SO 3 M 1或-COOM 1; R1表示-SO3M1或-COOM1; M1表示氢原子，碱金属原子或铵离子; n表示1〜6的整数，n为2以上时，R可以相同也可以不同。 根据本发明的方法，即使连续处理彩色照相感光材料，也可以在含有漂白促进剂的漂白浴中形成沉淀物而获得质量好的彩色摄影图像。
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8.发明授权Method of processing silver halide color photographic material using a reduced amount of replenisher 失效使用减少量的补充液处理卤化银彩色照相材料的方法
公开(公告)号：US5278032A
公开(公告)日：1994-01-11
申请号：US983629
申请日：1992-11-20
CPC分类号： G03C7/44 , G03C7/3924
摘要： A process for the continuous treatment of silver halide color photographic light-sensitive materials comprising the developing of the material while supplying a replenisher to a developing bath, where the amount of the replenisher is 900 m or less per m.sup.2 of the light-sensitive materials, and an average ratio of silver iodide to the whole silver halide included in the light-sensitive material is 8 mol % or less.
摘要翻译： 一种用于连续处理卤化银彩色照相感光材料的方法，包括在将补充液供应到显影浴的同时显影材料，其中补充剂的量为每平方米感光材料900微米或更少， 包含在感光材料中的碘化银与全部卤化银的平均比为8摩尔％以下。
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9.发明授权Method of processing silver halide color photographic material using a reduced amount of replenisher 失效使用减少量的补充液处理卤化银彩色照相材料的方法
公开(公告)号：US4849324A
公开(公告)日：1989-07-18
申请号：US188142
申请日：1988-04-21
CPC分类号： G03C7/44 , G03C7/3924
摘要： In a process for the continuous treatment of silver halide color photographic light-sensitive materials with supplying a replenisher to a developing bath, the amount of the replenisher is 900 m or less per m.sup.2 of the light-sensitive materials, and the light-sensitive materials contain a certain type of mercapto heterocyclic compounds. Constant results in finished development and lower fog are attained and fogging during storage of raw light-sensitive materials is suppressed even when the amount of the replenisher is very small.
摘要翻译： 在通过向显影浴供应补充剂的情况下连续处理卤化银彩色照相感光材料的方法中，补充剂的量相对于每平方米的感光材料为900μm以下，光敏材料 含有一定类型的巯基杂环化合物。 达到完成显影和降低雾度的恒定结果，即使补充剂的量非常小，也抑制原料感光材料的储存期间的雾化。
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公开(公告)号：US4822725A
公开(公告)日：1989-04-18
申请号：US248288
申请日：1988-09-22
申请人： Akira Abe , Shinzo Kishimoto , Yasuhisa Ogawa
发明人： Akira Abe , Shinzo Kishimoto , Yasuhisa Ogawa
CPC分类号： G03C7/42
摘要： A method for processing a silver halide color photographic material is described which comprises subjecting an imagewise exposed silver halide color photographic material to color development and then bleaching the developed color photographic material with a bleaching solution containing a ferric salt of an aminopolycarboxylic acid, wherein the bleaching solution additionally contains at least one compound represented by the following general formula (I) or (II) ##STR1## wherein R.sub.1 and R.sub.2 are identical or different and each represents a hydrogen atom or a methyl or ethyl group, and n represents an integer of 1 to 3, and wherein the oxidation reduction potential of the bleaching solution is adjusted to not more than 100 mV.
摘要翻译： 描述了一种处理卤化银彩色照相材料的方法，该方法包括使成像曝光的卤化银彩色照相材料进行着色显影，然后用含有氨基多羧酸的铁盐的漂白溶液漂白显影的彩色照相材料，其中漂白 溶液另外含有至少一种由以下通式（I）或（II）表示的化合物：其中R 1和R 2相同或不同，并且各自表示氢原子或甲基或 乙基，n表示1〜3的整数，并且将漂白溶液的氧化还原电位调节至100mV以下。
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