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1.发明授权Method for processing silver halide color photographic materials containing sensitizing dyes and two-equivalent magenta polymer couplers 失效用于处理含有敏化染料和二等效品红色聚合物成色剂的卤化银彩色照相材料的方法
公开(公告)号：US4789626A
公开(公告)日：1988-12-06
申请号：US940839
申请日：1986-12-12
申请人： Kei Sakanoue , Shinzo Kishimoto , Tadashi Ikeda
发明人： Kei Sakanoue , Shinzo Kishimoto , Tadashi Ikeda
CPC分类号： G03C1/18 , G03C7/3275
摘要： A method for processing a silver halide color photographic material by fixing or bleach-fixing the material and immediately thereafter subjecting it to washing or stabilization, wherein (A) the silver halide color photographic material contains at least one of sensitizing dyes represented by the formulae (I) and (II) specified in the specification and at least one two-equivalent magenta polymer coupler which is derived from a specified monomer coupler, and (B) the amount of a replenisher in the washing step and/or the stabilization step falls within the range of 3 to 50 times, based on unit area of the material after being processed, the amount of each processing solution having been carried over from the preceding bath.
摘要翻译： 一种通过固定或漂白固定材料并立即进行洗涤或稳定处理卤化银彩色照相材料的方法，其中（A）卤化银彩色照相材料含有至少一种由式 I）和（II）和由特定单体成色剂衍生的至少一种二等价品红色聚合物成色剂，和（B）洗涤步骤和/或稳定步骤中补充剂的量落入 基于处理后的材料的单位面积的3〜50倍的范围，从前一个浴中移出的各处理液的量。
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2.发明授权Silver halide color photographic material containing disulfide type bleach accelerator 失效含有二硫化物型漂白促进剂的卤化银彩色照相材料
公开(公告)号：US4780403A
公开(公告)日：1988-10-25
申请号：US940375
申请日：1986-12-11
申请人： Shinzo Kishimoto , Keiji Mihayashi
发明人： Shinzo Kishimoto , Keiji Mihayashi
CPC分类号： G03C7/39236
摘要： A silver halide color photographic material comprising a support having thereon at least one photographic emulsion layer containing tabular silver halide grains having an average aspect ratio of 5 or more and the silver halide color photographic material containing at least one compound represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group or an acyl group provided that both R.sub.1 and R.sub.2 do not represent hydrogen atoms at the same time, or R.sub.1 and R.sub.2 form a ring; and r represents an integer of from 1 to 3.The silver halide color photographic material can be bleached in a short period of time using a bleaching agent having a weak bleaching ability which meets requirements of preventing environmental pollution.A method for processing the silver halide color photographic material by subjecting to color development, then to treatment with a bath having a bleaching ability is also disclosed.
摘要翻译： 一种卤化银彩色照相材料，包括其上具有至少一个含有平均长径比为5或更大的片状卤化银颗粒的摄影乳剂层和含有至少一种由式（I）表示的化合物的卤化银彩色照相材料的载体， （I）其中R1和R2各自表示氢原子，烷基或酰基，条件是R1和R2不同时表示氢原子，或R1和R2形成环; 并且r表示1〜3的整数。可以在短时间内使用具有弱漂白能力的漂白剂来漂白卤化银彩色照相材料，该漂白剂满足防止环境污染的要求。 还公开了通过显色处理卤化银彩色照相材料，然后用具有漂白能力的浴进行处理的方法。
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3.发明授权Image forming method utilizing accelerated desilverization of color photographic material containing magneta coupler 失效使用含有磁性耦合器的彩色照相材料的加速脱色的图像形成方法
公开(公告)号：US4769313A
公开(公告)日：1988-09-06
申请号：US933517
申请日：1986-11-21
申请人： Hiroshi Fujimoto , Shinzo Kishimoto , Akira Abe , Junya Nakajima
发明人： Hiroshi Fujimoto , Shinzo Kishimoto , Akira Abe , Junya Nakajima
CPC分类号： G03C7/42 , G03C7/3825 , G03C7/38
摘要： A method of forming an image comprising, after color developmenmt of an exposed silver halide color photographic material, processing the developed silver halide color photographic material with a bath having a bleaching ability and subsequently with a bath having a bleach-fixing ability, wherein the silver halide color photographic material comprises a support having coated thereon at least one silver halide emulsion layer and at least one pyrazoloazole type magenta coupler represented by the following general formula (A): ##STR1## wherein R.sub.22 represents a hydrogen atom of a substituent; X represents a group capable of being split off upon a coupling reaction with an oxidation product of an aromatic primary amine developing agent; Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--, one of the Za--Zb bond and the Zb--ZC bond being a double bond and the other being a single bond; when the Zb--Zc bond is a carbon-carbon double bond, the Zb--Zc bond may be a part of a condensed aromatic ring; R.sub.22 or X may also form a polymer including a dimer or more; and when Za, Zb or Zc is a substituted methine group, the substituted methine group may form a polymer including a dimer or more. In accordance with the method of forming an image, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained without the formation of magenta stain.
摘要翻译： 一种形成图像的方法，包括在曝光的卤化银彩色照相材料的显影后，用具有漂白能力的浴处理显影的卤化银彩色照相材料，随后用具有漂白定影能力的浴，其中银 卤化物彩色照相材料包括其上涂覆有至少一种卤化银乳剂层和至少一种由以下通式（A）表示的吡唑并唑型品红成色剂的载体：其中R22表示取代基的氢原子 ; X表示与芳族伯胺显影剂的氧化产物偶联反应时能够分离的基团; Za，Zb和Zc各自表示次甲基，取代的次甲基，= N-或-NH-，Za-Zb键和Zb-ZC键之一为双键，另一个为单键; 当Zb-Zc键为碳 - 碳双键时，Zb-Zc键可以是稠合芳环的一部分; R 22或X也可以形成包含二聚体或更多的聚合物; 当Za，Zb或Zc为取代的次甲基时，取代的次甲基可以形成包含二聚体或更多的聚合物。 根据形成图像的方法，在短时间内完成脱银，并且在没有形成品红色污点的情况下获得具有优异色彩再现性和牢度的彩色照相图像。
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4.发明授权Method of processing silver halide color photographic material including the use of a two bath desilvering system comprising two baths 失效一种处理卤化银彩色照相材料的方法，包括使用包含两个浴的两个浴洗脱系统
公开(公告)号：US4769312A
公开(公告)日：1988-09-06
申请号：US918260
申请日：1986-10-14
申请人： Shinzo Kishimoto , Akira Abe , Junya Nakajima
发明人： Shinzo Kishimoto , Akira Abe , Junya Nakajima
CPC分类号： G03C7/42
摘要： A method of processing silver halide color photographic materials which comprises image-wise exposing said silver halide color photographic materials, color developing and then desilvering them in a bath having bleaching ability, characterized in that the bath having bleaching ability comprises two baths, the oxidation-reduction potential of the first bath being higher than that of the second bath, the oxidation-reduction potential of the second bath falling in the range of +60 mV to -60 mV, the first bath containing a water-soluble bromide in an amount of 0.5 to 1.3 mole/l, and the second bath containing a water-soluble bromide in an amount of 0 to 0.5 mole/l.
摘要翻译： 一种处理卤化银彩色照相材料的方法，其包括使所述卤化银彩色照相材料成像曝光，着色显影，然后在具有漂白能力的浴中将其脱色，其特征在于具有漂白能力的浴液包括两个浴， 第一浴的还原电位高于第二浴，第二浴的氧化还原电位在+60mV至-60mV的范围内，第一浴含有一定量的水溶性溴化物 0.5至1.3摩尔/升，第二浴含有0至0.5摩尔/升的水溶性溴化物。
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公开(公告)号：US4752556A
公开(公告)日：1988-06-21
申请号：US31189
申请日：1987-03-27
申请人： Shinzo Kishimoto
发明人： Shinzo Kishimoto
CPC分类号： G03C7/3046
摘要： A method for processing of a silver halide color photographic material for photography, which comprises a fixing or bleach-fixing step, followed by a water washing or stabilizing step, characterized in that:(i) said water washing or stabilizing step comprises multistage countercurrent baths which are countercurrently replenished with a washing water or stabilizing solution,(ii) the amount of the replenishing material is 3 to 50 times the volume of the solution taken by the photographic material into said water washing or stabilizing bath from the preceding bath and,(iii) said photographic material comprises at least one 2-equivalent magenta coupler represented by the formula (I): ##STR1## wherein R.sub.1 represents hydrogen atom or a substituent, X represents a split-off group, Za, Zb and Zc represent individually methine, substituted methine, .dbd.N-- or --NH--, one of the Za-Zb and Zb-Zc linkages is a double bond and the other is a single bond,or the formula (II): ##STR2## wherein R.sub.1 represents a carbonamido, anilino or ureido group, R.sub.2 represents a phenyl group and X represents a split-off group. This process provides a color image having good storage property and reduces the amount of waste liquid.
摘要翻译： 一种用于摄影的卤化银彩色照相材料的处理方法，其包括固定或漂白固定步骤，随后进行水洗或稳定步骤，其特征在于：（i）所述水洗或稳定步骤包括多级逆流浴 它们用洗涤水或稳定溶液逆流补充，（ii）补充材料的量是由照相材料摄取的溶液的体积的3至50倍，进入前述浴中的所述水洗或稳定浴，和（ iii）所述照相材料包含至少一种由式（I）表示的2-当量品红成色剂：其中R 1表示氢原子或取代基，X表示分离基，Za，Zb和Zc 代表单独次甲基，取代的次甲基，= N-或-NH-，Za-Zb和Zb-Zc键之一是双键，另一个是单键，或式（II）： ）其中R1 表示碳酰氨基，苯胺基或脲基，R2表示苯基，X表示分离基。 该方法提供具有良好储存性能并减少废液量的彩色图像。
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6.发明授权Silver halide photographic materials containing gelatin reactive antistatic agents 失效含有明胶反应性抗静电剂的卤化银照相材料
公开(公告)号：US4251626A
公开(公告)日：1981-02-17
申请号：US115314
申请日：1980-01-25
IPC分类号： C07D207/40 , C07D207/404 , C07D207/44 , C07D207/456 , C07D251/44 , C07D303/24 , C07D303/36 , C08G65/26 , C08G65/32 , C08G85/00 , G03C1/89 , G03C1/02 , G03C1/78
CPC分类号： C07D207/404 , C07D207/456 , C07D251/44 , C07D303/24 , C07D303/36 , C08G65/26 , C08G65/32 , C08G85/00 , G03C1/895
摘要： A silver halide photographic material having on a support at least one gelatin-containing layer containing as an antistatic agent a gelatin reactive surface active agent having at least one long chain hydrophobic group, at least one of a hydrophilic group selected from a cationic group, an anionic group, an amphoteric and a nonionic group, and at least one group reactive with gelatin in the molecule.
摘要翻译： 一种卤化银照相材料，其在载体上至少含有一种含抗静电剂的含明胶的层，具有至少一个长链疏水基团的明胶反应性表面活性剂，至少一种选自阳离子基团的亲水基团， 阴离子基团，两性和非离子基团，以及至少一个在分子中与明胶反应的基团。
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公开(公告)号：US4229524A
公开(公告)日：1980-10-21
申请号：US45482
申请日：1979-06-04
CPC分类号： G03C1/89
摘要： A photographic light sensitive material which contains, in at least one layer, a copolymer having a repeating unit represented by the following general formula (I): ##STR1## wherein R.sub.f represents a perfluoroalkyl group having 2 to 12 carbon atoms which may contain one hydrogen atom at the .omega.-position or a perfluoroalkenyl group; R represents a hydrogen atom or a methyl group; p represents an integer of 1 to 5; m represents an integer of 5 to 50; n represents zero or an integer of 1 to 20; and Y represents a hydrogen atom, an alkyl group having 1 to 24 carbon atoms, an alkenyl group, a phenyl group, an alkylphenyl group or one of the groups represented by R.sub.f ; whereby antistatic property (even under low humidity) and adhesion resisting property are improved without adversely affecting photographic characteristics.
摘要翻译： 在至少一层中含有具有由下列通式（I）表示的重复单元的共聚物的照相感光材料：其中Rf表示具有2至12个碳原子的全氟烷基，其可以 在ω-位或全氟链烯基上含有一个氢原子; R表示氢原子或甲基; p表示1〜5的整数， m表示5〜50的整数， n表示0或1〜20的整数， Y表示氢原子，碳原子数1〜24的烷基，烯基，苯基，烷基苯基或Rf表示的基团之一。 由此抗静电性（即使在低湿度下）和耐粘附性也得到改善，而不会不利地影响照相特性。
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公开(公告)号：US3953212A
公开(公告)日：1976-04-27
申请号：US412517
申请日：1973-11-02
申请人： Shizuo Miyano , Asaji Kondo , Shinzo Kishimoto , Kenichiro Yazawa
发明人： Shizuo Miyano , Asaji Kondo , Shinzo Kishimoto , Kenichiro Yazawa
CPC分类号： G03F7/0752 , G03F7/0757 , Y10S528/901
摘要： A presensitized lithoprinting plate which needs no fountain solution on printing comprising a support and a coating layer of a mixture of a photosensitive material and a silicone rubber.
摘要翻译： 在印刷时不需要润版液的预感印刷板，其包括载体和感光材料和硅橡胶的混合物的涂层。
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9.发明授权Process for processing silver halide color photographic material containing DIR coupler having a group functioning as a development inhibitor 失效用于处理具有用作显影抑制剂的基团的具有DIR成色剂的卤化银彩色照相材料的方法
公开(公告)号：US4812389A
公开(公告)日：1989-03-14
申请号：US911619
申请日：1986-09-25
申请人： Kei Sakanoue , Seiji Ichijima , Shinzo Kishimoto
发明人： Kei Sakanoue , Seiji Ichijima , Shinzo Kishimoto
CPC分类号： G03C7/305 , G03C7/44 , Y10S430/158
摘要： A process for processing a DIR coupler-containing silver halide color photographic material for photographing use in a continuous manner with replenishment of a developer is disclosed in which said DIR coupler is a coupler which has in a coupling site a group that functions as a development inhibitor or a development inhibitor precursor upon being eliminated from the coupling active site by color development processing and that will be decomposed to a compound exerting substantially no influences on photographic properties after flowing into a color developing solution, said development inhibitor having a half-value period of 4 hours or shorter than that at a pH of 10.0, and in which the developing solution is replenished in an amount of 700 ml or less per m.sup.2 of developed light-sensitive materials.
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公开(公告)号：US4605611A
公开(公告)日：1986-08-12
申请号：US767536
申请日：1985-08-20
申请人： Shigeru Ohno , Shinzo Kishimoto
发明人： Shigeru Ohno , Shinzo Kishimoto
CPC分类号： G03C7/421
摘要： A method for processing a silver halide color photographic material by subjecting a light-exposed silver halide color photographic material to a color development and then subjecting it to bleach processing and fix processing or to blix processing, which comprises performing said bleach processing or blix processing using a bleach bath or a blix bath containing a ferric ion complex salt as a bleaching agent, said bleach bath or blix bath, or a prebath for said bath containing at least one of compounds represented by the following general formula (I) or (II); ##STR1## wherein, X represents a hydrogen atom, ##STR2## Y.sup..crclbar. represents an anion; Q represents an atomic group necessary for forming a quaternary nitrogen-containing unsaturated heterocyclic ring; n represents an integer of 1 to 5; R.sup.1, R.sup.2, R.sup.6 and R.sup.8, which may be the same or different, each represents a hydrogen atom or a lower alkyl group; R.sup.3, R.sup.4 and R.sup.5, which may be the same or different, each represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group; any two of said R.sup.3, R.sup.4 and R.sup.5 may combine with each other to form a ring; said R.sup.3, R.sup.4 or R.sup.5 and said R.sup.1 or R.sup.2 may combine with each other to form a ring; and R.sup.7 represents --NR.sup.9 R.sup.10 --OR.sup.11, or --SR.sup.11 (wherein, R.sup.9 and R.sup.10, which may be the same or different, each represents a hydrogen atom or a lower alkyl group; R.sup.11 represents an atomic group necessary for forming a ring by combining with R.sup.6 ; and said R.sup.9 or R.sup.10 and said R.sup.6 may combine with each other to form a ring).The method of the present invention does not produce poisonous materials which are harmful to the environment and provides an excellent high speed bleaching process without harming other photographic properties.
摘要翻译： 一种通过对曝光的卤化银彩色照相材料进行显色处理并随后对其进行漂白处理和固定处理或混合处理来处理卤化银彩色照相材料的方法，其包括用漂白处理或混合处理 漂白浴或含有铁离子络合盐作为漂白剂的漂白浴，所述漂白浴或混合浴，或含有至少一种下述通式（I）或（II）表示的化合物的所述浴的预浴， ; （Ⅰ）其中X表示氢原子，Y（ - ）表示阴离子; Q表示形成季氮含不饱和杂环所必需的原子团; n表示1〜5的整数， R 1，R 2，R 6和R 8可以相同或不同，表示氢原子或低级烷基; R 3，R 4和R 5可以相同或不同，表示取代或未取代的烷基或取代或未取代的芳基; 所述R3，R4和R5中的任意两个可以彼此结合形成环; 所述R 3，R 4或R 5，并且所述R 1或R 2可以彼此结合形成环; 并且R 7表示-NR 9 R 10 + L，-OR 11或-SR 11（其中，R 9和R 10可相同或不同，表示氢原子或低级烷基; R 11表示形成环所需的原子团 通过与R6结合;所述R9或R10和所述R6可以相互结合形成环）。 本发明的方法不产生对环境有害的有毒材料，并提供优异的高速漂白工艺而不损害其它照相性能。
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