摘要:
A process for producing polychlorobenzonitrile having chlorine atoms at the 2,6-position by ammoxidation of toluene derivative having chlorine atoms at the 2,6-position with a gas containing ammonia and oxygen in vapor phase in the presence of a catalyst, characterized in that bromine and/or a bromine-containing compound is added to the reaction system.
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1 and R.sub.2 are each a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1 and R.sub.2 are each a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group of a group represented by ##STR3## wherein m is 1 or 2.
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1 and R.sub.2 are each a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].
摘要:
A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].
摘要:
Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.
摘要:
This invention relates to a process for simultaneously preparing methacrylonitrile and 1,3-butadiene from a mixture of butanes and butenes (hereinafter referred to as a mixed butane-butene) consisting of isobutane, n-butane, isobutylene, 1-butene, cis-2-butene and trans-2-butene, in excellent selectivity and single pass yield. More particularly, this invention relates to a process for the simultaneous preparation of methacrylonitrile and 1,3-butadiene which comprises subjecting the mixed butane-butene, at high temperatures and in vapor phase, to ammoxidation and oxidative dehydrogenation with a gas containing ammonia and either air or oxygen, using a catalyst of the general formula:CO.sub.a Fe.sub.b Bi.sub.c Mg.sub.d Q.sub.h Mo.sub.f O.sub.gwherein Co is cobalt, Fe is iron, Bi is bismuth, Mg is magnesium, Mo is molybdenum, Q is at least one element selected from the group consisting of potassium, rubidium and cesium, O is oxygen, and a, b, c, d, f, g, and h are the number of atoms of Co, Fe, Bi, Mg, Mo, O and Q respectively, with a being a value of from 1 to 15, b from 0.5 to 7, c from 0.1 to 4, d from 0 to 4, f being 12, g being a value of from 39 to 72 determined naturally from the valences of other metal atoms and h from 0.01 to 1.0.