摘要:
There is provided a hydrogen-absorbing alloy comprising, as a principal phase, at least one kind of phase selected from the group consisting of a first phase having a hexagonal crystal system (excluding a phase having a CaCu5 type crystal structure) and a second phase having a rhombohedral crystal system, the hydrogen-absorbing alloy having a composition represented by the following general formula (1): R1-a-bMgaTbNiZ-X-Y-&agr;M1XM2YMn&agr; (1) wherein R is at least one kind of element selected from rare earth elements (which include Y), T is at least one element selected from the group consisting of Ca, Ti, Zr and Hf, M1 is at least one element selected from the group consisting of Co and Fe, M2 is at least one element selected from the group consisting of Al, Ga, Zn, Sn, Cu, Si, B, Nb, W, Mo, V, Cr, Ta, Li, P and S, and the atomic ratios of a, b, X, Y, &agr; and Z are respectively a number satisfying the conditions of: 0.15≦a≦0.37, 0≦b≦0.3, 0≦X≦1.3, 0≦Y≦0.5, 0≦&agr;
摘要翻译:提供一种吸氢合金,其包含作为主相的至少一种相,其选自具有六方晶系的第一相(不包括具有CaCu 5型晶体结构的相)和第二相 具有菱方晶系的吸氢合金具有由以下通式(1)表示的组成:其中R是选自稀土元素(包括Y)中的至少一种元素,T是至少一种元素 选自由Ca,Ti,Zr和Hf组成的组,M1是选自Co和Fe中的至少一种元素,M2是选自Al,Ga,Zn,Sn, Cu,Si,B,Nb,W,Mo,V,Cr,Ta,Li,P和S,a,b,X,Y,α和Z的原子比分别为满足以下条件的数:0.15 <= a <= 0.37,0 <= b <= 0.3,0 <= X <= 1.3,0 <= Y <= 0.5,0 <=α<0.135和2.5 <= Z&LE; 4.2。
摘要:
There is provided a nickel-hydrogen secondary battery which comprises a negative electrode comprising a hydrogen-absorbing alloy represented by the following general formula (A), a positive electrode, and an alkaline electrolyte, and which meets the conditions represented by the formulas (1) and (2), (R1-xMgx)NiyAz (A) wherein R is at least one element selected from rare earth elements (including yttrium), Ca, Zr and Ti, A is at least one element selected from Co, Mn, Fe, V, Cr, Nb, Al, Ga, Zn, Sn, Cu, Si, P and B, and x, y and z are atomic ratio individually defined as 0
摘要:
There is provided a hydrogen-absorbing alloy comprising, as a principal phase, at least one kind of phase selected from the group consisting of a first phase having a hexagonal crystal system (excluding a phase having a CaCu5 type crystal structure) and a second phase having a rhombohedral crystal system, the hydrogen-absorbing alloy having a composition represented by the following general formula (1): R1−a−bMgaTbNiZ−X−Y−&agr;M1XM2YMn60 (1) wherein R is at least one kind of element selected from rare earth elements (which include Y), T is at least one element selected from the group consisting of Ca, Ti, Zr and Hf, M1 is at least one element selected from the group consisting of Co and Fe, M2 is at least one element selected from the group consisting of Al, Ga, Zn, Sn, Cu, Si, B, Nb, W, Mo, V, Cr, Ta, Li, P and S, and the atomic ratios of a, b, X, Y, &agr; and Z are respectively a number satisfying the conditions of: 0.15≦a≦0.37, 0≦b≦0.3, 0≦X≦1.3, 0≦Y≦0.5, 0≦&agr;≦0.135, and 2.5≦Z≦4.2.
摘要翻译:提供一种吸氢合金,其包含作为主相的至少一种相,其选自具有六方晶系的第一相(不包括具有CaCu 5型晶体结构的相)和第二相 具有菱方晶系的吸氢合金具有由以下通式(1)表示的组成:其中R是选自稀土元素(包括Y)中的至少一种元素,T是至少一种元素 选自由Ca,Ti,Zr和Hf组成的组,M1是选自Co和Fe中的至少一种元素,M2是选自Al,Ga,Zn,Sn, Cu,Si,B,Nb,W,Mo,V,Cr,Ta,Li,P和S,a,b,X,Y,α和Z的原子比分别为满足以下条件的数:0.15 <= a <= 0.37,0 <= b <= 0.3,0 <= X <= 1.3,0 <= Y <= 0.5,0 <=α<= 0.135和2.5 <= Z <= 4.2。
摘要:
A nickel-hydrogen secondary battery having a negative electrode comprising a hydrogen-absorbing alloy containing magnesium, a rare earth element and nickel as essential elements, which is capable of suppressing the self-discharge being occurred under the condition of high temperature storage, or the like. This secondary battery comprises a negative electrode containing a hydrogen-absorbing alloy, a positive electrode containing nickel hydroxide, a separator comprising a non-woven fabric, and an alkaline electrolyte. The hydrogen-absorbing alloy is represented by (R1−xMgx)NiyAz (wherein R is at least one element selected from rare earth elements (including yttrium), Ca, Zr and Ti, A is at least one element selected from Co, Mn, Fe, V, Cr, Nb, Al, Ga, Zn, Sn, Cu, Si, P and B), and x, y and z are atomic ratio individually defined as 0
摘要:
The present invention provides a hydrogen absorbing alloy containing as a principal phase at least one phase selected from the group consisting of a second phase having a rhombohedral crystal structure and a first phase having a crystal structure of a hexagonal system excluding a phase having a CaCu5 type structure, wherein a content of a phase having a crystal structure of AB2 type is not higher than 10% by volume including 0% by volume and the hydrogen absorbing alloy has a composition represented by general formula (1) given below: R1-a-bMgaTbNiZ-X-Y-αM1XM2YMnα. (1)
摘要翻译:本发明提供一种吸氢合金,其含有选自具有菱方晶体结构的第二相和除了具有CaCu的相的六方晶系晶体结构的第一相的至少一相的主相, 其中,具有AB 2型晶体结构的相的含量不高于包含0体积%的10体积%,并且所述吸氢合金具有 由下式给出的通式(1)表示的组成:<?in-line-formula description =“In-line formula”end =“lead”?> R 1-ab u> B 2 N 2 Z x Y-αM 1 M 2 M 2 M 1 N 2 N 2 >。 (1)<?in-line-formula description =“In-line Formulas”end =“tail”?>
摘要:
The present invention provides a hydrogen absorbing alloy containing as a principal phase at least one phase selected from the group consisting of a second phase having a rhombohedral crystal structure and a first phase having a crystal structure of a hexagonal system excluding a phase having a CaCu5 type structure, wherein a content of a phase having a crystal structure of AB2 type is not higher than 10% by volume including 0% by volume and the hydrogen absorbing alloy has a composition represented by general formula (1) given below: R1-a-bMgaTbNiZ-X-Y-αM1XM2YMnα. (1)
摘要:
The present invention provides a hydrogen absorbing alloy containing as a principal phase at least one phase selected from the group consisting of a second phase having a rhombohedral crystal structure and a first phase having a crystal structure of a hexagonal system excluding a phase having a CaCu5 type structure, wherein a content of a phase having a crystal structure of AB2 type is not higher than 10% by volume including 0% by volume and the hydrogen absorbing alloy has a composition represented by general formula (1) given below: R1-a-bMgaTbNiZ-X-Y-αM1XM2YMnα (1)
摘要:
The present invention provides a hydrogen absorbing alloy containing as a principal phase at least one phase selected from the group consisting of a second phase having a rhombohedral crystal structure and a first phase having a crystal structure of a hexagonal system excluding a phase having a CaCu5 type structure, wherein a content of a phase having a crystal structure of AB2 type is not higher than 10% by volume including 0% by volume and the hydrogen absorbing alloy has a composition represented by general formula (1) given below: R1-a-bMgaTbNiZ-X-Y-αM1XM2YMnα (1)
摘要翻译:本发明提供一种吸氢合金,其含有选自具有菱方晶体结构的第二相和除了具有CaCu的相的六方晶系晶体结构的第一相的至少一相的主相, 其中,具有AB 2型晶体结构的相的含量不高于包含0体积%的10体积%,并且所述吸氢合金具有 由下式给出的通式(1)表示的组成:<?in-line-formula description =“In-line formula”end =“lead”?> R 1-ab u> B 2 N 2 Z x Y-αM 1 M 2 M 2 M 1 N 2 N 2 >(1)<?in-line-formula description =“In-line Formulas”end =“tail”?>
摘要:
The present invention provides a hydrogen absorbing alloy containing as a principal phase at least one phase selected from the group consisting of a second phase having a rhombohedral crystal structure and a first phase having a crystal structure of a hexagonal system excluding a phase having a CaCu5 type structure, wherein a content of a phase having a crystal structure of AB2 type is not higher than 10% by volume including 0% by volume and the hydrogen absorbing alloy has a composition represented by general formula (1) given below: R1-a-bMgaTbNiZ-X-Y-αM1XM2YMnα (1)
摘要翻译:本发明提供一种吸氢合金,其含有选自具有菱方晶体结构的第二相和除了具有CaCu的相的六方晶系晶体结构的第一相的至少一相的主相, 其中,具有AB 2型晶体结构的相的含量不高于包含0体积%的10体积%,并且所述吸氢合金具有 由下式给出的通式(1)表示的组成:<?in-line-formula description =“In-line formula”end =“lead”?> R 1-ab u> B 2 N 2 Z x Y-αM 1 M 2 M 2 M 1 N 2 N 2 >(1)<?in-line-formula description =“In-line Formulas”end =“tail”?>
摘要:
The present invention provides a hydrogen absorbing alloy containing as a principal phase at least one phase selected from the group consisting of a second phase having a rhombohedral crystal structure and a first phase having a crystal structure of a hexagonal system excluding a phase having a CaCu5 type structure, wherein a content of a phase having a crystal structure of AB2 type is not higher than 10% by volume including 0% by volume and the hydrogen absorbing alloy has a composition represented by general formula (1) given below: R1-a-bMgaTbNiZ-X-Y-αM1XM2YMnα (1).