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公开(公告)号：US07183705B2
公开(公告)日：2007-02-27
申请号：US10485148
申请日：2003-05-15
申请人： Masaki Aoki , Hiroyuki Kawamura , Kazuhiko Sugimoto , Mitsuhiro Otani , Hiroshi Setoguchi , Junichi Hibino
发明人： Masaki Aoki , Hiroyuki Kawamura , Kazuhiko Sugimoto , Mitsuhiro Otani , Hiroshi Setoguchi , Junichi Hibino
CPC分类号： H01J11/12 , C09K11/7734 , H01J11/42
摘要： A plasma display device comprises blue phosphor which restricts adsorption of water and hydrocarbon gases to a surface thereof, reduces degradation of luminance and chromaticity change, and improves discharge characteristic. Among phosphor layers used for a plasma display, a blue phosphor layer comprises one of compounds symbolized by Ba1-xMgAl10O17:Eux and Ba1-x-ySryMgAl10O17:Eux, of which phosphor contains 0.2 to 0.8 in number x of Eu atoms, and the Eu atoms comprises 25% to 85% concentration of bivalent Eu ions, and 15% to 75% concentration of trivalent Eu ions.
摘要翻译： 等离子体显示装置包括蓝色荧光体，其限制水和烃气体吸附到其表面，降低亮度劣化和色度变化，并且改善放电特性。 在用于等离子体显示器的荧光体层中，蓝色磷光体层包括由Ba 1-x M Al 10 O 17：Eu表示的化合物之一 其中x 1和x 2独立地表示1至8个碳原子， 其中磷光体在Eu原子数量x含有0.2至0.8，Eu原子包含25％至85％的二价Eu离子浓度，15％至75％浓度的三价Eu离子。
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公开(公告)号：US07161298B2
公开(公告)日：2007-01-09
申请号：US10489326
申请日：2003-05-15
申请人： Hiroyuki Kawamura , Kazuhiko Sugimoto , Masaki Aoki , Mitsuhiro Otani , Hiroshi Setoguchi , Junichi Hibino
发明人： Hiroyuki Kawamura , Kazuhiko Sugimoto , Masaki Aoki , Mitsuhiro Otani , Hiroshi Setoguchi , Junichi Hibino
CPC分类号： C09K11/7734 , H01J2211/42
摘要： A plasma display device includes a blue phosphor composed of a compound represented by Me3MgSi2O8:Eu (where, Me is at least calcium (Ca), strontium (Sr), or barium (Ba)). Concentration of bivalent Eu ions is 45 to 95% and concentration of trivalent Eu ions is 5 to 55%, of the europium (Eu) atoms contained in the blue phosphor layer. The plasma display device has less luminance degradation in a panel manufacturing process, high luminance, and long lifetime.
摘要翻译： 等离子体显示装置包括由Me 3 N 2 SiO 2·O 8：Eu表示的化合物构成的蓝色荧光体（其中，Me至少为 钙（Ca），锶（Sr）或钡（Ba））。 二价Eu离子的浓度为蓝色荧光体层所含的铕（Eu）原子的45〜95％，三价Eu离子的浓度为5〜55％。 等离子体显示装置在面板制造工艺中具有较少的亮度劣化，高亮度和长寿命。
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3.发明授权公开(公告)号：US07067969B2
公开(公告)日：2006-06-27
申请号：US10485149
申请日：2003-05-15
申请人： Masaki Aoki , Hiroyuki Kawamura , Kazuhiko Sugimoto , Mitsuhiro Otani , Hiroshi Setoguchi , Junichi Hibino
发明人： Masaki Aoki , Hiroyuki Kawamura , Kazuhiko Sugimoto , Mitsuhiro Otani , Hiroshi Setoguchi , Junichi Hibino
CPC分类号： H01J11/42 , C09K11/7734 , C09K11/7792 , H01J11/12
摘要： A blue phosphor composing a blue phosphor player in a plasma display device has a crystal structure of Ba(1-x)EuxMgAl10O17 or Ba(1-x-y)EuxSryMgAl10O17. In this blue phosphor, La substitutes for a proportion of Ba or Sr so as to achieve a high-luminance plasma display device with less luminance deterioration in panel manufacturing processes.
摘要翻译： 构成等离子体显示装置中的蓝色荧光体的蓝色荧光体具有Ba（1-x）Eu x MgAl 10 O O的晶体结构 或（Ba）（1-xy）Eu x x Sr x Y y O x O 17 。 在该蓝色荧光体中，La代替Ba或Sr的一部分，以实现面板制造工艺中亮度劣化较少的高亮度等离子体显示装置。
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公开(公告)号：US06939480B2
公开(公告)日：2005-09-06
申请号：US10468727
申请日：2002-10-23
CPC分类号： C09K11/7734 , H01J9/223 , H01J2211/42
摘要： Disclosed is a plasma display device that provides high luminance and minimal degradation in luminance under panel operations. A blue phosphor in a phosphor layer has a crystal structure of MeMgSi2O6:Eu or Me3MgSi2O8:Eu (where, Me contains at least one of Ca, Sr, and Ba) produced with a precursor that is obtained by any one of methods: an aqueous solution synthesis method, a spray synthesis method, a hydrothermal synthesis method, and a hydrolysis method. The phosphor has an average particle diameter ranging from 0.1 to 3.0 μm.
摘要翻译： 公开了一种在面板操作下提供高亮度和最小亮度劣化的等离子体显示装置。 荧光体层中的蓝色荧光体具有MeMgSi 2 O 6：Eu或Me 3 M 2 Si 2 N 2的晶体结构 Eu（其中，Me含有Ca，Sr和Ba中的至少一种），其通过以下任一方法获得的前体制备：水溶液合成法，喷雾合成法 方法，水热合成法和水解法。 荧光体的平均粒径为0.1〜3.0μm。
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公开(公告)号：US07147802B2
公开(公告)日：2006-12-12
申请号：US10478857
申请日：2002-12-20
CPC分类号： C09K11/595 , H01J1/63 , H01J2211/42
摘要： The present invention relates to a plasma display device apt to increase luminance of a phosphor layer and prevent degradation of a discharge characteristic, and to a phosphor used for the device. This plasma display device has a green phosphor having a crystal structure of Zn2SiO4:Mn, and a monovalent oxide is substituted for part of the green phosphor. The monovalent oxide is one or more of lithium oxide (Li2O), sodium oxide (Na2O), potassium oxide (K2O), cesium oxide (Cs2O), rubidium oxide (Rb2O), copper oxide (Cu2O), and silver oxide (Ag2O). This structure allows reduction of oxygen defects occurring in the green phosphor, suppression of the luminance decrease of the green phosphor, and improvement of a discharge characteristic.
摘要翻译： 本发明涉及一种能够增加荧光体层的亮度并防止放电特性劣化的等离子体显示装置以及用于该装置的荧光体。 该等离子体显示装置具有具有Zn 2+ SiO 4·Mn的晶体结构的绿色荧光体，并且一价氧化物被一部分绿色荧光体所代替。 一价氧化物是氧化锂（Li 2 O 2），氧化钠（Na 2 O 2），氧化钾（K 2 O 3） O），氧化铯（Cs 2 O），氧化铷（Rb 2 O），氧化铜（Cu 2 O 2）和银 氧化物（Ag 2 O）。 这种结构可以减少在绿色荧光体中发生的氧缺陷，抑制绿色荧光体的亮度降低和放电特性的改善。
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公开(公告)号：US07208102B2
公开(公告)日：2007-04-24
申请号：US10485305
申请日：2003-05-15
CPC分类号： C09K11/595 , C09K11/7734 , C09K11/7792 , C09K11/7797 , H01J2211/42
摘要： A plasma display device exhibits suppressed luminance degradation of a phosphor, a suppressed change in chromaticity and improved discharge characteristics as a result of suppression of adsorption of water or hydrocarbon-containing gas on a surface of a blue phosphor. A blue phosphor layer used in the plasma display device is formed of a compound expressed by Ba1−XMgAl10O17:EuX or Ba1−x−ySryMgAl10O17:EuX and includes at least one element that is selected from Nb, Ta, Pr, P, As, Sb, Bi and Tm which substitutes for a part of its Al or Mg element.
摘要翻译： 等离子体显示装置由于抑制水或含烃气体在蓝色荧光体的表面上的吸附而表现出抑制荧光体的亮度劣化，抑制的色度变化和改善的放电特性。 在等离子体显示装置中使用的蓝色荧光体层由由Ba 1-X 5 Al 10 O 17 O 12：Eu
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7.发明授权Plasma display apparatus, fluorescent material, and fluorescent material manufacturing method 有权等离子体显示装置，荧光材料和荧光体制造方法公开(公告)号：US07204939B2
公开(公告)日：2007-04-17
申请号：US10250577
申请日：2002-09-11
CPC分类号： C09K11/7734 , H01J2211/42
摘要： The present invention aims to inhibit water adsorption onto the surface of a blue phosphor(blue fluorescent material), decrease luminance degradation and chromaticity shift of a phosphor, or improve discharge characteristics thereof. Used in a phosphor for a plasma display is a blue phosphor in which trivalent Eu ions substitute for part of divalent Eu ions. This substitution eliminates oxygen vacancy in the vicinity of layers containing Ba atoms (Ba—O layers) in the blue phosphor, and thus inhibits water adsorption onto the surface of the blue phosphor, decreases luminance degradation and chromaticity shift of the phosphor, or improves discharge characteristics thereof.
摘要翻译： 本发明旨在抑制蓝色荧光体（蓝色荧光体）表面的吸水，降低荧光体的亮度劣化和色度偏移，或改善其放电特性。 用于等离子体显示器的荧光体是其中三价Eu离子代替部分二价Eu离子的蓝色荧光体。 该替代物消除蓝色荧光体中含有Ba原子（Ba-O层）的层附近的氧空位，因此抑制了在蓝色荧光体的表面上的水吸附，降低了荧光体的亮度劣化和色度偏移，或改善了放电 的特点。
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8.发明授权Plasma display apparatus, fluorescent material, and fluorescent material manufacturing method 失效等离子体显示装置，荧光材料和荧光体制造方法公开(公告)号：US06960309B2
公开(公告)日：2005-11-01
申请号：US10432334
申请日：2002-09-11
IPC分类号： C09K11/64 , C09K11/08 , C09K11/66 , C09K11/67 , C09K11/77 , C09K11/80 , H01J1/63 , H01J11/12 , H01J11/22 , H01J11/24 , H01J11/26 , H01J11/34 , H01J11/42 , H01F17/16
CPC分类号： H01J11/42 , C09K11/7734 , H01J1/63 , H01J11/12
摘要： The present invention inhibits water adsorption onto the surface of a blue phosphor, decreases luminance degradation and chromaticity shift of a phosphor, or improves discharge characteristics thereof. The blue phosphor is a compound represented by Ba1-xMgAl10O17:Eux or Ba1-x-ySryMgAl10O17:Eux, wherein 0.03≦x≦0.25 and 0.1≦y≦0.5, and containing at least one of Ti, Zr, Hf, Si, Ge, Sn, and Ce substituting for part of one of elements Al and Mg.
摘要翻译： 本发明抑制了对蓝色荧光体的表面的吸水，降低了荧光体的亮度劣化和色度偏移，或者提高了其荧光体的放电特性。 蓝色荧光体是由Ba 1-x M Al 10 O 17 O 15：Eu x Ba或Ba x O表示的化合物， 其中0.03
= x <= 0.25和0.1 <= y <= 0.5，并且包含Ti，Zr，Hf，Si，Ge，Sn和Ce中的至少一种替代元素Al和Mg中的一种元素。 -
公开(公告)号：US07232530B2
公开(公告)日：2007-06-19
申请号：US10476691
申请日：2002-12-20
CPC分类号： C09K11/7734 , C09D11/30 , C09D11/322 , C09D11/50 , C09K11/02 , C09K11/025 , C09K11/595 , C09K11/7787 , C09K11/7797 , H01J9/227 , H01J2211/42
摘要： A method of manufacturing a plasma display device which prevents the brightness of a phosphor layer from lowering is disclosed, and the method can form the phosphor layer in a stable manner because a nozzle is free from clogging. At least one of the phosphor layers has a green phosphor layer containing green phosphor having zero or positive charges and a crystal structure of Zn2SiO4:Mn. Green phosphor ink, whose major ingredient is the green phosphor, is applied through the nozzle to discharging cells, thereby forming the green phosphor layer. The green phosphor ink is formed of green phosphor powder coated with an oxide having positive charges, or the ink is formed by crushing the green phosphor powder originally having negative charges and a crystal structure of Zn2SiO4:Mn such that the powder changes to have positive charges.
摘要翻译： 公开了一种防止荧光体层的亮度降低的等离子体显示装置的制造方法，由于喷嘴没有堵塞，所以能够稳定地形成荧光体层。 荧光体层中的至少一个具有包含绿色荧光体的绿色荧光体层，该绿色荧光体具有正电荷和Zn 2 SiO 4·Mn的结晶结构。 其主要成分是绿色荧光体的绿色荧光体墨水通过喷嘴施加到放电单元，从而形成绿色荧光体层。 绿色荧光体墨水由涂覆有正电荷的氧化物的绿色荧光体粉末形成，或者通过粉碎最初具有负电荷的绿色荧光体粉末和Zn 2 SiO 2的结晶结构形成墨水 > 4 ：使得粉末变成具有正电荷的Mn。
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10.发明授权公开(公告)号：US07531961B2
公开(公告)日：2009-05-12
申请号：US10503301
申请日：2003-09-26
申请人： Masaki Aoki , Hiroyuki Kawamura , Kazuhiko Sugimoto , Hiroshi Setoguchi , Junichi Hibino , Yoshinori Tanaka
发明人： Masaki Aoki , Hiroyuki Kawamura , Kazuhiko Sugimoto , Hiroshi Setoguchi , Junichi Hibino , Yoshinori Tanaka
IPC分类号： H01J17/49
CPC分类号： H01J29/26 , C09K11/643 , C09K11/7734 , C09K11/778 , C09K11/7787 , C09K11/7797 , H01J1/63 , H01J11/12 , H01J11/42
摘要： Phosphor layers (110G, 110B, and 110R) are made of a combination of: blue and green phosphors that are positively charged on their surfaces and baked in an oxygen-nitrogen atmosphere to reduce oxygen vacancy, and that have a β-alumina crystal structure; and a red phosphor made of an yttrium oxide compound. Uniformly forming such phosphor layers on the wall surfaces of barrier ribs (109) provides equal charge characteristics of the phosphors of respective colors, reduces oxygen vacancy in the phosphors, and inhibits adsorption of various gases in the panel production process. This can stabilize the discharge characteristics and prevent luminance degradation at driving the panel.
摘要翻译： 荧光体层（110G，110B和110R）由以下组合制成：蓝色和绿色荧光体在其表面上带正电并在氧 - 氮气氛中烘烤以减少氧空位，并且具有β-氧化铝晶体结构 ; 和由氧化钇化合物制成的红色荧光体。 在隔壁（109）的壁表面上均匀地形成这样的荧光体层，提供相应颜色的荧光体的相同的电荷特性，减少荧光体中的氧空位，并且在面板生产过程中抑制各种气体的吸附。 这可以稳定放电特性并防止在驱动面板时的亮度劣化。
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