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公开(公告)号：US07674929B2
公开(公告)日：2010-03-09
申请号：US12066681
申请日：2006-09-13
IPC分类号： C07C255/00
CPC分类号： C07C253/30 , C07B43/04 , C07C227/06 , C07C2601/14 , C07C255/24
摘要： The invention relates to a process for preparing β-aminopropionic acid derivatives by reacting a primary or secondary amine with an acrylic acid derivative, wherein comprises (i) a first primary or secondary amine is provided as an amine of value and reacted with the acrylic acid derivative, to obtain a reaction mixture comprising a first β-aminopropionic acid derivative as a product of value and additionally unconverted acrylic acid derivative, (ii) the unconverted acrylic acid derivative present in the reaction mixture is reacted with a second secondary amine as a scavenger amine virtually fully to give a second β-aminopropionic acid derivative to obtain a reaction mixture comprising the first β-aminopropionic acid derivative as a product of value, the second β-aminopropionic acid derivative and unconverted secondary amine.
摘要翻译： 本发明涉及一种通过使伯胺或仲胺与丙烯酸衍生物反应来制备β-氨基丙酸衍生物的方法，其中包括（i）第一伯胺或仲胺作为有价值的胺并与丙烯酸反应 酸衍生物，得到包含第一和次氨基丙酸衍生物作为值的产物和另外未转化的丙烯酸衍生物的反应混合物，（ii）将存在于反应混合物中的未转化的丙烯酸衍生物与第二仲胺反应， 一种清除剂胺实际上完全可以得到第二种 - 氨基丙酸衍生物，以获得包含第一种和第二种 - 氨基丙酸衍生物和未转化的仲胺的第一种 - 氨基丙酸衍生物的反应混合物。
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公开(公告)号：US20080249333A1
公开(公告)日：2008-10-09
申请号：US12066681
申请日：2006-09-13
IPC分类号： C07C229/02
CPC分类号： C07C253/30 , C07B43/04 , C07C227/06 , C07C2601/14 , C07C255/24
摘要： The invention relates to a process for preparing β-aminopropionic acid derivatives by reacting a primary or secondary amine with an acrylic acid derivative, wherein comprises (i) a first primary or secondary amine is provided as an amine of value and reacted with the acrylic acid derivative, to obtain a reaction mixture comprising a first β-aminopropionic acid derivative as a product of value and additionally unconverted acrylic acid derivative, (ii) the unconverted acrylic acid derivative present in the reaction mixture is reacted with a second secondary amine as a scavenger amine virtually fully to give a second β-aminopropionic acid derivative to obtain a reaction mixture comprising the first β-aminopropionic acid derivative as a product of value, the second β-aminopropionic acid derivative and unconverted secondary amine.
摘要翻译： 本发明涉及通过使伯胺或仲胺与丙烯酸衍生物反应来制备β-氨基丙酸衍生物的方法，其中包括（i）第一伯胺或仲胺作为有价值的胺并与丙烯酸反应 衍生物，以获得包含作为有价值的产物的第一β-氨基丙酸衍生物和另外未转化的丙烯酸衍生物的反应混合物，（ii）反应混合物中存在的未转化的丙烯酸衍生物与作为清除剂的第二仲胺反应 胺实际上完全提供第二β-氨基丙酸衍生物以获得包含第一β-氨基丙酸衍生物作为有价值的产物，第二β-氨基丙酸衍生物和未转化的仲胺的反应混合物。
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公开(公告)号：US20080306299A1
公开(公告)日：2008-12-11
申请号：US12158200
申请日：2006-12-15
申请人： Martin Ernst , Andreas Kusche , Gunnar Heydrich , Horst Grafmans , Holger Evers , Johann-Peter Melder , Harald Meissner , Torsten Freund
发明人： Martin Ernst , Andreas Kusche , Gunnar Heydrich , Horst Grafmans , Holger Evers , Johann-Peter Melder , Harald Meissner , Torsten Freund
IPC分类号： C07C231/14
CPC分类号： C07C231/14 , Y02P20/582 , C07C237/06
摘要： The invention relates to a process for preparing aminoalkanamides by reacting cyanoalkanoic esters with a) ammonia or an amine and b) hydrogen in the presence of a catalyst, the reaction with component b) being started simultaneously or not later than a maximum of 100 minutes after commencement of the reaction of the cyanoalkanoic ester with component a).
摘要翻译： 本发明涉及一种通过氰基链烷酸酯与a）氨或胺反应制备氨基烷酰胺的方法，和b）在催化剂存在下使氢气反应，与组分b）的反应同时或不迟于最多100分钟开始 开始氰基链烷酸酯与组分a）的反应。
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公开(公告)号：US20100267948A1
公开(公告)日：2010-10-21
申请号：US12301811
申请日：2007-05-24
IPC分类号： C07D265/30 , C07C209/02
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/07 , C07C211/08 , C07C211/35
摘要： Process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the reaction is carried out using a suspended catalyst as heterogeneous catalyst and is carried out in the semibatch mode in which the nitrogen compound as one reactant is placed in the reaction vessel and the aldehyde and/or the ketone as the other reactant is added during the course of the reaction and the aldehyde and/or the ketone is added in portions or continuously to the reaction mixture during the course of the reaction as a function of the achieved conversion of the nitrogen compound until a conversion of the nitrogen compound of at least 95% results, and all or part of the catalyst remains in the reaction vessel after the reaction batch and is reused for the next reaction batch.
摘要翻译： 在非均相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中反应使用悬浮催化剂作为非均相催化剂进行 并且以半反应模式进行，其中作为一种反应物的氮化合物被放置在反应容器中，并且在反应过程中加入作为其它反应物的醛和/或酮，醛和/或酮 在反应过程中以部分或连续的方式加入到反应混合物中，作为实现氮化合物转化的函数，直至氮化合物的转化率至少为95％，并且全部或部分催化剂保持在 反应容器在反应批次后再次用于下一反应批次。
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5.发明授权Process for preparing unsymmetric secondary tert-butylamines in the liquid phase 失效在液相中制备不对称的仲叔丁胺的方法公开(公告)号：US08445726B2
公开(公告)日：2013-05-21
申请号：US13080080
申请日：2011-04-05
申请人： Christof Wilhelm Wigbers , Christoph Mueller , Johann-Peter Melder , Bernd Stein , Harald Meissner , Gerd Haderlein , Norbert Gutfrucht
发明人： Christof Wilhelm Wigbers , Christoph Mueller , Johann-Peter Melder , Bernd Stein , Harald Meissner , Gerd Haderlein , Norbert Gutfrucht
IPC分类号： C07C209/26
CPC分类号： C07C209/26 , Y02P20/582 , C07C211/17 , C07C211/08
摘要： The present application relates to a process for preparing unsymmetric secondary tert-butylamines which, as well as the tert-butyl radical, also comprise an alkyl, cycloalkyl or benzyl radical. They are prepared by reacting corresponding aldehydes with tert-butylamine and hydrogen in the presence of hydrogenation catalysts (reductive amination) in the liquid phase.
摘要翻译： 本申请涉及一种制备不对称仲叔丁胺的方法，其中叔丁基以及叔丁基也包括烷基，环烷基或苄基。 它们通过在液相中的氢化催化剂（还原胺化）存在下，使相应的醛与叔丁胺和氢反应来制备。
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6.发明授权Removal of water from mixtures with alcohols and/or carboxylic acids and/or carboxylic esters 失效从与醇和/或羧酸和/或羧酸酯的混合物中除去水
公开(公告)号：US5248427A
公开(公告)日：1993-09-28
申请号：US905188
申请日：1992-06-26
申请人： Luise Spiske , Harald Meissner , Werner Hefner , Andreas Huebner , Hermann Steinhauser , Guido Ellinghorst
发明人： Luise Spiske , Harald Meissner , Werner Hefner , Andreas Huebner , Hermann Steinhauser , Guido Ellinghorst
摘要： In a process for removing water by pervaporation or vapor permeation from mixtures with alcohols and/or carboxylic acids and/or carboxylic esters by bringing the mixture into contact with one side of a membrane and removing the water-containing permeate in vapor form from the other side of the membrane, the membrane used has been obtained by plasma polymerization.
摘要翻译： 在通过使混合物与膜的一侧接触并从蒸汽形式从另一侧除去含水渗透物的方法中，通过与醇和/或羧酸和/或羧酸酯的混合物的渗透蒸发或蒸汽渗透来除去水 膜的一面，使用的膜已经通过等离子体聚合获得。
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