MESH-ADJUSTABLE MOLECULAR SIEVE
    1.
    发明申请
    MESH-ADJUSTABLE MOLECULAR SIEVE 有权
    MESH可调分子筛

    公开(公告)号:US20080184881A1

    公开(公告)日:2008-08-07

    申请号:US12025167

    申请日:2008-02-04

    摘要: Metal-organic framework-based molecular sieves comprising pores with a temperature-adjustable pore opening. The temperature-adjustable pore size molecular sieves comprise a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a functionalized hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are held in proximity with each other to form at least one hydrophobic chamber. The hydrophobic moieties form temperature-adjustable pore size hydrophobic pores. When adjusted to a pre-selected temperature the temperature-adjustable pore openings allow for the passage of molecules having a size less than the size of the pre-selected temperature-adjustable pore opening.

    摘要翻译: 基于金属 - 有机骨架的分子筛包括具有温度可调开孔的孔。 温度可调的孔径分子筛包括与多个两亲性配体结合的多个金属簇,每个配体包含官能化的疏水部分和官能化的亲水部分,并且其中金属簇和两亲性配位体亲水部分形成金属簇层 形成至少一个亲水孔的金属簇层。 在金属簇层的每一侧上,多个相关联的两亲性配体疏水部分与金属簇层配合形成三层,并且多个三层保持彼此接近以形成至少一个疏水室 。 疏水部分形成温度可调孔径的疏水孔。 当调节到预先选定的温度时,温度可调节的孔隙允许具有小于预先选择的温度可调开孔的尺寸的分子通过。

    Mesh-adjustable molecular sieve
    2.
    发明授权
    Mesh-adjustable molecular sieve 有权
    可调式分子筛

    公开(公告)号:US08337591B2

    公开(公告)日:2012-12-25

    申请号:US12728299

    申请日:2010-03-22

    IPC分类号: B01D53/02 B01J20/22

    摘要: A metal-organic framework-based mesh-adjustable molecular sieve (MAMS) exhibiting a temperature-dependent mesh size. The MAMS comprises a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand functionalized hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are packed in a facing-spaced apart relationship to form at least one hydrophobic pore.

    摘要翻译: 基于金属 - 有机骨架的可调网格分子筛(MAMS)显示温度依赖的网孔尺寸。 MAMS包括与多个两亲配体结合的多个金属簇,每个配体包含疏水部分和官能化的亲水部分,并且其中金属簇和两亲配体官能化的亲水部分形成金属簇层,形成金属簇层 至少一个亲水孔。 在金属簇层的每一侧上,多个相关联的两亲性配位体疏水部分与金属簇层配合形成三层,并且以面对间隔的关系填充多个三层以形成至少一个 疏水孔。

    Mesh-Adjustable Molecular Sieve
    3.
    发明申请
    Mesh-Adjustable Molecular Sieve 有权
    网可调分子筛

    公开(公告)号:US20080184883A1

    公开(公告)日:2008-08-07

    申请号:US11738730

    申请日:2007-04-23

    IPC分类号: B01D53/02 B01D59/26

    摘要: A metal-organic framework-based mesh-adjustable molecular sieve (MAMS) exhibiting a temperature-dependent mesh size. The MAMS comprises a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand functionalized hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are packed in a facing-spaced apart relationship to form at least one hydrophobic pore.

    摘要翻译: 基于金属 - 有机骨架的可调网格分子筛(MAMS)显示温度依赖的网孔尺寸。 MAMS包括与多个两亲配体结合的多个金属簇,每个配体包含疏水部分和官能化的亲水部分,并且其中金属簇和两亲配体官能化的亲水部分形成金属簇层,形成金属簇层 至少一个亲水孔。 在金属簇层的每一侧上,多个相关联的两亲性配位体疏水部分与金属簇层配合形成三层,并且以面对间隔的关系填充多个三层以形成至少一个 疏水孔。

    Mesh-adjustable molecular sieve
    4.
    发明授权
    Mesh-adjustable molecular sieve 有权
    可调式分子筛

    公开(公告)号:US07687432B2

    公开(公告)日:2010-03-30

    申请号:US11738730

    申请日:2007-04-23

    IPC分类号: B01D53/02 B01J20/22

    摘要: A metal-organic framework-based mesh-adjustable molecular sieve (MAMS) exhibiting a temperature-dependent mesh size. The MAMS comprises a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand functionalized hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are packed in a facing-spaced apart relationship to form at least one hydrophobic pore.

    摘要翻译: 基于金属 - 有机骨架的可调网格分子筛(MAMS)显示温度依赖的网孔尺寸。 MAMS包括与多个两亲配体结合的多个金属簇,每个配体包含疏水部分和官能化的亲水部分,并且其中金属簇和两亲配体官能化的亲水部分形成金属簇层,形成金属簇层 至少一个亲水孔。 在金属簇层的每一侧上,多个相关联的两亲性配位体疏水部分与金属簇层配合形成三层,并且以面对间隔的关系填充多个三层以形成至少一个 疏水孔。

    Mesh-adjustable molecular sieve
    5.
    发明授权
    Mesh-adjustable molecular sieve 有权
    可调式分子筛

    公开(公告)号:US07789943B2

    公开(公告)日:2010-09-07

    申请号:US12025167

    申请日:2008-02-04

    IPC分类号: B01D53/02 B01J20/22

    摘要: Temperature-adjustable pore size molecular sieves comprise a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a functionalized hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are held in proximity with each other to form at least one hydrophobic chamber.

    摘要翻译: 温度可调的孔径分子筛包括与多个两亲性配体结合的多个金属簇,每个配体包含官能化的疏水部分和官能化的亲水部分,并且其中金属簇和两亲配位体亲水部分形成金属簇层, 所述金属簇层形成至少一个亲水孔。 在金属簇层的每一侧上,多个相关联的两亲性配体疏水部分与金属簇层配合形成三层,并且多个三层保持彼此接近以形成至少一个疏水室 。

    MESH-ADJUSTABLE MOLECULAR SIEVE
    6.
    发明申请
    MESH-ADJUSTABLE MOLECULAR SIEVE 有权
    MESH可调分子筛

    公开(公告)号:US20100170393A1

    公开(公告)日:2010-07-08

    申请号:US12728299

    申请日:2010-03-22

    IPC分类号: B01D53/02 B01J20/22

    摘要: A metal-organic framework-based mesh-adjustable molecular sieve (MAMS) exhibiting a temperature-dependent mesh size. The MAMS comprises a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand functionalized hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are packed in a facing-spaced apart relationship to form at least one hydrophobic pore.

    摘要翻译: 基于金属 - 有机骨架的可调网格分子筛(MAMS)显示温度依赖的网孔尺寸。 MAMS包括与多个两亲配体结合的多个金属簇,每个配体包含疏水部分和官能化的亲水部分,并且其中金属簇和两亲配体官能化的亲水部分形成金属簇层,形成金属簇层 至少一个亲水孔。 在金属簇层的每一侧上,多个相关联的两亲性配位体疏水部分与金属簇层配合形成三层,并且以面对间隔的关系填充多个三层以形成至少一个 疏水孔。