公开(公告)号：US5932671A

公开(公告)日：1999-08-03

申请号：US868728

申请日：1997-06-04

申请人： Howard F. Efner ,  Earl Clark, Jr. ,  Michael L. Stephens

发明人： Howard F. Efner ,  Earl Clark, Jr. ,  Michael L. Stephens

IPC分类号： C08F2/10 ,  C08F2/38

CPC分类号： C08F2/10

摘要： A process for producing a water-soluble polymer which can be useful in a subterranean formation is provided. The process comprises contacting a an olefinic compound and a thiol under a solution polymerization process for producing the water-soluble polymer.

摘要翻译： 提供了可用于地下地层的水溶性聚合物的制造方法。 该方法包括在溶液聚合方法下使烯属化合物和硫醇接触以制备水溶性聚合物。

公开(公告)号：US5347018A

公开(公告)日：1994-09-13

申请号：US127615

申请日：1993-09-28

申请人： Earl Clark, Jr. ,  Howard F. Efner ,  Jimmie J. Straw

发明人： Earl Clark, Jr. ,  Howard F. Efner ,  Jimmie J. Straw

IPC分类号： C07D333/48 ,  C07D333/08

CPC分类号： C07D333/48

摘要： A process for producing sulfolane compounds is provided which comprises: (1) contacting a conjugated diene with sulfur dioxide under conditions sufficient to synthesize a sulfolene compound whereby a mixture of the sulfolene compound and impurities comprising unreacted sulfur dioxide is produced; (2) transferring the mixture to an impurities removal vessel containing a freezing point depressant which comprises an aromatic compound; (3) removing the impurities; (4) transferring the impurities-reduced sulfolene compound to a hydrogenation reactor; (5) contacting the impurities-reduced sulfolene compound with hydrogen, in the presence of a hydrogenation catalyst, under conditions sufficient to produce a sulfolane compound; and (6) optionally recovering the sulfolane compound.

摘要翻译： 提供了一种生产环丁砜化合物的方法，其包括：（1）在足以合成环丁烯化合物的条件下使共轭二烯与二氧化硫接触，由此产生包含未反应的二氧化硫的环丁烯化合物和杂质的混合物; （2）将混合物转移到含有含有芳族化合物的凝固点抑制剂的杂质去除容器中; （3）去除杂质; （4）将杂质减少的环丁烯化合物转移到氢化反应器中; （5）在氢化催化剂存在下，在足以产生环丁砜化合物的条件下使杂质减少的环丁烯化合物与氢接触; 和（6）任选地回收环丁砜化合物。

公开(公告)号：US4906701A

公开(公告)日：1990-03-06

申请号：US251425

申请日：1988-09-30

申请人： Earl Clark, Jr.

发明人： Earl Clark, Jr.

IPC分类号： C08F2/32

CPC分类号： C08F2/32

摘要： In an inverse emulsion polymerization system for producing water-soluble polymers from a monomer system comprising an N-vinyl lactam and/or a vinyl-containing sulfonic acid or salt thereof utilizing a surfactant system having (1) a surfactant with a bulky lipophilic portion and a hydrophilic portion and (2) a generally straight-chain nonionic surfactant having a lipophilic hydrocarbon group and an OH-terminated hydrophilic group, i.e. an alcohol. Such a system having both the right HLB and the right chemical cobination results in a stable emulsion for the polymerization of these particular water-soluble monomers.

摘要翻译： 在由包含N-乙烯基内酰胺和/或含乙烯基的磺酸或其盐的单体体系制备水溶性聚合物的反相乳液聚合体系中，所述表面活性剂体系具有（1）具有大体积亲油部分的表面活性剂和 亲水部分和（2）具有亲油性烃基和OH-封端的亲水基团（即醇）的通常为直链的非离子表面活性剂。 具有正确的HLB和正确的化学嵌段的这种体系导致用于这些特定的水溶性单体的聚合的稳定的乳液。

公开(公告)号：US4808698A

公开(公告)日：1989-02-28

申请号：US103480

申请日：1987-09-30

申请人： Rex L. Bobsein ,  Earl Clark, Jr.

发明人： Rex L. Bobsein ,  Earl Clark, Jr.

IPC分类号： C08G75/00 ,  C08G75/02 ,  C08G75/06 ,  C08G75/20

CPC分类号： C08G75/20 ,  C08G75/0236 ,  C08G75/025

摘要： An improved process for the production of high molecular weight aromatic sulfide/sulfone polymer comprising contacting under suitable polymerization conditions: (a) an organic amide, (b) an alkali metal sulfide or hydrosulfide, (c) water, and (d) a dihaloaromatic sulfone wherein the molar ratio of (a) to (b) is about 2:1 to about 24:1, the improvement comprising employing a molar ratio of (a) to (c) of about 0.4:1 to about 1.3:1.

公开(公告)号：US4548982A

公开(公告)日：1985-10-22

申请号：US528922

申请日：1983-09-02

申请人： Earl Clark, Jr. ,  Howard B. Irvin

发明人： Earl Clark, Jr. ,  Howard B. Irvin

IPC分类号： C08F8/44 ,  C09K8/24 ,  C08L33/02

CPC分类号： C08F8/44 ,  C09K8/24 ,  Y10S507/903 ,  Y10S507/904

摘要： Polymers derived by copolymerizing a hydrophilic vinyl monomer, such as acrylic acid or methacrylic acid, with at least one hydrophobic vinyl monomer, such as an acrylic acid ester, a methacrylic acid ester, a vinyl ester of a saturated monocarboxylic acid having from 1 to 3 carbon atoms, and the like, prepared in a suitable inert, low chain transfer, organic liquid medium, such as n-pentane, n-hexane, cyclohexane, and chlorofluorocarbons such as 1,1,2-trichloro-1,2,2-trifluoroethane, and neutralized by anhydrous ammonia while still slurried in the inert low chain transfer organic liquid medium, perform effectively as water loss additives for drilling fluids under high temperature conditions. Such water loss control additives are especially effective when employed in drilling fluids having high solids content. Other copolymerization techniques for preparing such polymers are also disclosed. Also disclosed are drilling fluids employing such water loss control additives as well as a method of drilling a borehole in the earth using drilling fluids employing such water loss control additives.

摘要翻译： 通过使亲水性乙烯基单体如丙烯酸或甲基丙烯酸与至少一种疏水性乙烯基单体如丙烯酸酯，甲基丙烯酸酯，饱和一元羧酸的乙烯基酯共聚而得到的聚合物，其具有1至3个 碳原子等，在合适的惰性，低链转移的有机液体介质如正戊烷，正己烷，环己烷和氯氟烃中制备，例如1,1,2-三氯-1,2,2 并在惰性低链转移有机液体介质中仍然浆化的无水氨中和，在高温条件下有效地作为钻井液的失水添加剂。 当用于具有高固体含量的钻井液时，这种失水控制添加剂是特别有效的。 还公开了制备这种聚合物的其它共聚技术。 还公开了采用这种失水控制添加剂的钻井液以及使用这种失水控制添加剂的钻井液在地球上钻井的方法。

公开(公告)号：US4997582A

公开(公告)日：1991-03-05

申请号：US335150

申请日：1989-04-07

申请人： Earl Clark, Jr. ,  Billy L. Swanson

发明人： Earl Clark, Jr. ,  Billy L. Swanson

IPC分类号： C09K8/72

CPC分类号： C09K8/74

摘要： Methods and compositions for acid treating subterranean formations penetrated by well bores are provided. The compositions are each comprised of an aqueous acid solution, one or more acrylamide polymers dissolved in the acid solution, a liquid hydrocarbon dispersed in the acid solution, and one or more nonionic surface active agents having at least one reactive hydroxyl group per molecule. The acrylamide polymer or polymers increase the viscosity of the acid solution and the surface active agent or agents interact with the polymer of polymers whereby stabilized high viscosity results. The subterranean formation acid treating methods of the invention are carried out by introducing the high viscosity acid compositions therein, allowing the compositions to react until spent and recovering the compositions.

摘要翻译： 提供了用井眼渗透的地下地层的酸处理方法和组合物。 所述组合物各自包含酸水溶液，溶解在酸性溶液中的一种或多种丙烯酰胺聚合物，分散在酸性溶液中的液体烃，以及每分子具有至少一个反应性羟基的一种或多种非离子表面活性剂。 丙烯酰胺聚合物或聚合物增加酸溶液的粘度，并且表面活性剂或试剂与聚合物的聚合物相互作用，从而导致稳定的高粘度。 本发明的地层酸处理方法是通过在其中引入高粘度酸组合物进行的，使组合物反应直至消耗并回收组合物。

公开(公告)号：US4775010A

公开(公告)日：1988-10-04

申请号：US142484

申请日：1988-01-06

申请人： Earl Clark, Jr. ,  Billy L. Swanson

发明人： Earl Clark, Jr. ,  Billy L. Swanson

IPC分类号： C09K8/72 ,  E21B43/27

CPC分类号： C09K8/74 ,  Y10S507/933

摘要： Methods and compositions for acid treating subterranean formations penetrated by well bores are provided. The compositions are each comprised of an aqueous acid solution, one or more acrylamide polymers dissolved in the acid solution, a liquid hydrocarbon dispersed in the acid solution, and one or more nonionic surface active agents having at least one reactive hydroxyl group per molecule. The acrylamide polymer or polymers increase the viscosity of the acid solution and the surface active agent or agents interact with the polymer or polymers whereby stabilized high viscosity results. The subterranean formation acid treating methods of the invention are carried out by introducing the high viscosity acid compositions therein, allowing the compositions to react until spent and recovering the compositions.

摘要翻译： 提供了用井眼渗透的地下地层的酸处理方法和组合物。 所述组合物各自包含酸水溶液，溶解在酸性溶液中的一种或多种丙烯酰胺聚合物，分散在酸性溶液中的液体烃，以及每分子具有至少一个反应性羟基的一种或多种非离子表面活性剂。 丙烯酰胺聚合物或聚合物增加酸溶液的粘度，并且表面活性剂或试剂与聚合物或聚合物相互作用，从而导致稳定的高粘度。 本发明的地层酸处理方法是通过在其中引入高粘度酸组合物进行的，使组合物反应直至消耗并回收组合物。

公开(公告)号：US4764574A

公开(公告)日：1988-08-16

申请号：US939641

申请日：1986-12-09

申请人： Earl Clark, Jr.

发明人： Earl Clark, Jr.

IPC分类号： C08F2/32

CPC分类号： C08F2/32 ,  Y10S526/911

摘要： In an inverse emulsion polymerization system for producing water-soluble polymers from a monomer system comprising an N-vinyl lactam and/or a vinyl-containing sulfonic acid or salt thereof utilizing a surfactant system having (1) a surfactant with a bulky lipophilic portion and an OH-containing hydrophilic portion and (2) a generally straight-chain nonionic surfactant having a lipophilic hydrocarbon group and an OH-terminated hydrophilic group, i.e. an alcohol. Such a system having both the right HLB and the right chemical combination results in a stable emulsion for the polymerization of these particular water-soluble monomers.

摘要翻译： 在由包含N-乙烯基内酰胺和/或含乙烯基的磺酸或其盐的单体体系制备水溶性聚合物的反相乳液聚合体系中，所述表面活性剂体系具有（1）具有大体积亲油部分的表面活性剂和 含OH的亲水部分和（2）具有亲油性烃基和OH封端的亲水基团（即醇）的通常为直链的非离子表面活性剂。 具有正确的HLB和正确的化学组合的这种体系产生用于这些特定的水溶性单体的聚合的稳定的乳液。

公开(公告)号：US5512261A

公开(公告)日：1996-04-30

申请号：US373828

申请日：1995-01-17

申请人： Earl Clark, Jr. ,  Jimmie J. Straw

发明人： Earl Clark, Jr. ,  Jimmie J. Straw

IPC分类号： B01D19/00 ,  C07B63/00 ,  C07D333/48 ,  C01B17/60 ,  B01D50/00

CPC分类号： C07D333/48

摘要： A process for removing sulfur dioxide in a fluid such as, for example, sulfolene or sulfolane, comprises circulating the fluid in a loop under conditions sufficient to effect the removal of sulfur dioxide from the fluid wherein the loop comprises at least one spraying device such as, for example, a spray nozzle.

摘要翻译： 用于除去流体例如环丁烯砜或环丁砜的二氧化硫的方法包括在足以使流体中除去二氧化硫的条件下在环路中循环流体，其中环路包括至少一种喷射装置，例如 ，例如喷嘴。

公开(公告)号：US5331069A

公开(公告)日：1994-07-19

申请号：US966782

申请日：1992-10-27

申请人： Rex L. Bobsein ,  Earl Clark, Jr.

发明人： Rex L. Bobsein ,  Earl Clark, Jr.

IPC分类号： C08G75/02 ,  C08G75/20 ,  C08G75/14

CPC分类号： C08G75/0236 ,  C08G75/20

摘要： Poly(arylene sulfide sulfone) polymers recovered from a reaction mixture produced by contacting at least one haloaromatic sulfone, at least one sulfur source, and a polar organic compound at polymerization conditions are treated with (1) a haloaromatic sulfone mixture comprising at least one haloaromatic sulfone and a polar organic compound followed by contacting the polymer with (2) a zinc compound. The two-step treatment improves the melt stability and extrudate quality of the polymer.

摘要翻译： 通过在聚合条件下使至少一种卤代芳族砜，至少一种硫源和极性有机化合物接触而制备的反应混合物回收的聚（亚芳基硫醚砜）聚合物用（1）包含至少一种卤代芳族砜 砜和极性有机化合物，然后使聚合物与（2）锌化合物接触。 两步处理改善了聚合物的熔体稳定性和挤出物质量。